Materials Literature
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A portfolio of crosslinked chitosan:collagen blends was prepared, and their microarchitecture and water binding capacity were studied to investigate their application for adipose tissue engineering. Glutaraldehyde (GA) concentration had little effect on scaffold morphology or water binding capacity. However, the proce…
We present a unified treatment of Zitterbewegung phenomena for a wide class of systems including spintronic, graphene, and superconducting systems. We derive an explicit expression for the time dependence of the position operator of the quasiparticles which can be decomposed into a mean part and an oscillatory term. T…
The depolarization fields set up to due to uncompensated surface charges in a ferroelectric thin film can suppress the ferroelectric phase below a critical size. Recent experiments show that 180 degree domain structures can help to stabilize ferroelectricity in films as thin as 3 unit cells. We study the influence of…
The long disputed issue of the limiting value of quasiparticle density of states $\r(0) = \r (\e \to 0)$ in a \emph{d-}wave superconductor with impurities (\emph{vs} its linear vanishing, $\r_0(\e) \propto |\e|/\D$, near the nodal point $\e = 0$ in a pure system with the gap parameter $\D$) is discussed. Using the tec…
The electrical resistance of magnetic domain walls in ferromagnetic metallic manganites can be enhanced to 10-12 Ohm.m2 by patterning nanoconstrictions [J. Appl. Phys. 89, 6955 (2001)]. We show equally large enhancements in a phase separated La0.60Ca0.40MnO3 manganite film without recourse to nanopatterning. The domai…
Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers.…
With the desire to mass produce any specific n,m type of single wall carbon nanotube (SWNT) from a small sample of the same material, we disclose here the preliminary work directed toward that goal. The ultimate protocol would involve taking a single n,m-type nanotube sample, cutting the nanotubes in that sample into…
New tris(heterocyclic beta-diketonato)europium(III) complexes of the general formula Eu(PBI)3.L [where HPBI = 3-phenyl-4-benzoyl-5-isoxazolone and L = H2O, 2,2'-bipyridine (bpy), 4,4'-dimethoxy-2,2'-bipyridine (dmbpy), 1,10-phenanthroline (phen), or 4,7-diphenyl-1,10-phenanthroline (bath)] were synthesized and charact…
We demonstrate that aptamer-capped near-infrared PbS quantum dots (QDs) can detect a target protein based on selective charge transfer. The water-soluble QDs are synthesized with the thrombin-binding aptamer, which retains the secondary quadruplex structure necessary for binding to thrombin. These QDs have diameters o…
Vanadium oxide (VO2) exhibits a very interesting semiconductor to metal transition as the crystal structure changes from tetragonal or rutile to monoclinic upon cooling close to 68°C. The characteristics of this transition are very interesting scientifically and are of immense technological importance due to a variety…
Quantitative determination of oxide nanoparticle composition and structure by X-ray photoelectron spectroscopy (XPS) has proven difficult for metal oxides because of three factors: some oxide nanoparticles are prone to reduction in the XPS instrument under X-ray illumination in the ultrahigh vacuum (UHV) environment;…
Gadolinium-based contrast agents (CAs) are widely used to enhance the contrast of images in magnetic resonance imaging procedures. Two categories of gadolinium chelates exist: the macrocyclic molecules where Gd3+ is caged in the pre-organized cavity of the ligand and the linear molecules. Gadolinium chelates differ in…
Using quartz crystal microbalance with dissipation and ellipsometry, we show that during adsorption of fibrinogen on evaporated tantalum films the saturation uptake increases with increasing root-mean-square roughness (from 2.0 to 32.9 nm) beyond the accompanying increase in surface area. This increase is attributed t…
Lead-free piezoelectric ceramics, with the nominal composition of 0.948(K0.5Na0.5)NbO3–0.052LiSbO3 (KNN-LS5.2), were synthesized by conventional solid-state sintering, and the piezoelectric and electromechanical properties were characterized as a function of temperature. The Curie temperature of the KNN based perovski…
The Handbook of Fiber Chemistry, Third Edition provides complete coverage of scientific and technological principles for all major natural and synthetic fibers. Incorporating new scientific techniques, instruments, characterization, and processing methods, the book features important technological advances from the pa…
The inhibition of corrosion of mild steel in hydrochloric acid by isatin glycine (ING) and isatin (IN) at 30-60 oC and concentrations of 0.0001 M to 0.0005 M was studied via weight loss method. At the highest inhibitor concentration studied ING exhibited inhibition efficiency of 87% while IN exhibited 84% at 60 oC. A…
Silicon subiodide clusters (Si(n)I(m), n = 1-20) produced by laser ablation of bulk powder silicone tetraiodide have been investigated by time-of-flight mass spectroscopy and ab initio calculations. Both experimental results and theoretical calculations revealed a tendency to form different structures of the clusters…
A double-groove, two-depth dielectric grating structure for high-efficiency light coupling into a light guide is introduced. We show computationally that the optimized gratings can couple a monochromatic TE- or TM-polarized light beam with nearly 100% efficiency. For an unpolarized light beam 90% efficiency can be rea…
An electron-phonon interaction model is proposed and applied to thermal transport in semiconductors at micro/nanoscales. The high electron energy induced by the electric field in a transistor is transferred to the phonon system through electron-phonon interaction in the high field region of the transistor. Due to this…
The crystal structure of the low-temperature form of barium metagermanate (BaGeO3) has been determined from laboratory X-ray powder diffraction data collected at 298.5 (5) K. The structure was found to consist of alternating layers of Ba cations and [GeO3]3 rings, and is closely related to pseudo-wollastonite. The rin…