Materials Literature
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Abstract Benzene and aniline clathrates of metal-complex host lattices with a general formula of M(II)(NH3)2Ni(CN)4·2G, in which M(II) was nickel, copper, or cadmium, and G, benzene or aniline as the guest molecule, were prepared. The stoichiometry was established through the analytical data and the structural informa…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Model and Experimental Results for Drainage of Solution between Foam BubblesP. A. Haas and H. F. JohnsonCite this: Ind. Eng. Chem. Fundamen. 1967, 6, 2, 225–233Publication Date (Print):May 1, 1967Publication History Published online1 May 2002Published inissue 1 May 1967htt…
The influence of a distribution of relaxation times is studied in annealing experiments. A two-relaxation time model is proposed, which permits the calculation of the distribution of relaxation times from the crossover data of Spinner and Napolitano as well as that of Ritland. This model also characterizes the structu…
The system Zr‐O was studied in the composition range 50 to 66.7 at.% O by metallographic analysis, high‐temperature X‐ray analysis, and lattice parameter determinations at room temperature. The solubility of zirconium in zirconia was determined from 1200° to 2000°C, and the cubic‐tetragonal inversion temperature of Zr…
The dynamic Young's moduli E of molded films of a polyethylene and a polypropylene were found to decrease with increasing thickness t. An upper limit of E appears to exist when the film thickness is reduced to less than 1 mil. For thicker films, E is inversely proportional to t. Finally, the modulus approaches a lower…
Thin foils were prepared from slices taken in selected orientations from crystals deformed in compression by single glide on (101) or (211) or by double glide on (211) and (211). At room temperature the structures observed after single glide were quite similar to those which have been reported for copper. In stage I,…
Abstract Growth rates of ammonium‐ and potassium‐dihydrogen phosphate crystal faces have been measured in a simple laboratory apparatus under carefully controlled conditions of temperature, supersaturation and solution velocity. The growth process, which was found to be second‐order with respect to the supersaturation…
General procedures for preparation of lactic dehydrogenases of only the H4 and M4 types are presented. These purified enzymes have only one enzyme band on starch gel electrophoresis. The molecular weights of these enzymes are 140,000 to 150,000 g and the sedimentation constants of all the enzymes are in the same range…
Abstract Electron microscopic examination of stretched thin films of black loaded vulcanizates of SBR and polybutadiene blends shows that vacuole formation is prevalent when the polybutadiene content drops below one-third. The vacuoles that formed on stretching these stocks did so at small coherent carbon black agglom…
Mossbauer spectra were measured on Ca2Fe2O5, Ca2Fe1.5Al0.5O5, Ca2FeAlO5, and Ca2Fe0.67Al1.33O5 at temperatures from 95°K to above the Neel points. The Mossbauer spectrum of Ca2Fe2O5 below its Neel point shows lines which were assigned to tetrahedral and octahedral site ferric ions on the basis of the observed isomer s…
Single crystals of AgI in the form of hexagonal prisms up to 20 mm in length and 2 mm in diameter can be grown by slow diffusive dilution of a solution of AgI in concentrated aqueous KI solution. The crystals are of good quality and have very small concentrations of potassium impurity.
The initial steady-state electrode potential of mild steel in a vigorously aerated salt solution is believed to be a type of potential not previously described in that, for a given type of surface preparation of metal, it is wholly controlled by the nature and concentration of the anions in solution. It is a function…
The structural change of the jersey loop upon yarn swelling is related to the amount of expected laundering shrinkage in cotton jersey fabric by introducing a three-dimen sional loop model. The lengthwise shrinking is explained by the geometry of loop migration and curvature changes upon wetting and drying of the fabr…
Diffuse-reflectance spectra are reported for 11 rare-earth oxides of various structural types over the spectral range of 225–2700 mμ. These spectra, particularly in the near infrared, permit the use of diffuse-reflectance spectroscopy to identify rare-earth ions in solid materials.
Abstract To sum up our findings on the requirements for rubber blends with vulcanizate properties arithmetically interpolated between those of the constituent rubbers one needs: (a) Rubbers which have similar values of solubility parameter and which also yield blends whose vulcanizates exhibit a single glass transitio…
A model of concentric circular dislocation loops is used to examine the Hall-Petch relation. For a given critical stress concentration at the grain boundary, the Hall-Petch slope produced by this model is higher than that from either single or double-ended pile-ups of infinite straight dislocations. The minimum stress…
Abstract A new electron microscope technique permits study of the heterogeneity of elastomer blends and filler distribution therein. Vulcanizates are embedded with a specific monomer system which is subsequently polymerized. Specimens are then sectioned with an ultramicrotome and examined in the electron microscope. E…
Abstract An x‐ray investigation of the products formed by the action of caustic soda on different samples of cellulose and those formed on the decomposition of these products by aqueous reagents and alchols shows that the fundamental reacting unit is a sheet of cellulose chains, and not individual cellulose chains. Al…
In principle, the refinement of a pseudosymmetric structure starting from an idealized high-symmetry structure is impossible by routine methods of analysis, such as least-squares, even when the atomic displacements are very small. A much more helpful approach is by a method of successive approximations. This uses firs…
Measurements of resistivities of dilute iron based alloys show strong deviations from. Matthiessen's rule. These deviations can be explained by a model in which spin ↑ and spin ↓ electrons conduct in parallel. The results are consistent with the theory of impurity shielding in these alloys.