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Methyltrioxorhenium als Katalysator für die Olefin‐Oxidation

Wolfgang A. Herrmann、Richard W. Fischer、Dieter W. Marz1991-12-01Angewandte Chemie

Ausgeprägte Lewis‐Acidität ist die Erklärung für die außergewöhnliche Aktivität der Titelverbindung in der katalytischen Olefin‐Epoxidierung mit Wasserstoffperoxid. Das System MTO/ t ‐C 4 H 9 OH/H 2 O 2 epoxidiert selektiv und effizient Olefine unter sehr schonenden Bedingungen (‐ 30 bis + 60°C, in der Regel Raumtempe…

Organometallic Complex Synthesis and CatalysisPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Experimental evidence for the Si-Si bond model of the 7.6-eV band inSiO2glass

Hideo Hosono、Yoshihiro Abe、Hiroshi Imagawa 等 5 位作者1991-12-01Physical review. B, Condensed matter

We have found a decrease in the intensity of the 7.6-eV band and the appearance of the Si-H band upon heating ${\mathrm{SiO}}_{2}$ glasses, which were prepared by a method involving processes of dehydration with ${\mathrm{Cl}}_{2}$ gas, in ${\mathrm{H}}_{2}$ gas. The absorption cross section of the 7.6-eV band evaluat…

Glass properties and applicationsThin-Film Transistor TechnologiesPhotonic Crystals and Applications

Molecular cloning of a second form of rac protein kinase.

Pamela F. Jones、Teresa Jakubowicz、Brian A. Hemmings1991-12-01Cell Regulation

A novel serine/threonine protein kinase (termed rac-PK) has recently been identified and cloned from cDNA libraries derived from the human cell lines MCF-7 and WI38. A second form of this protein kinase, termed rac protein kinase beta, has been identified from cDNAs derived from the same cell lines. These two closely…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Molecular structure of chromyl nitrate (CrO2(NO3)2) in the gas phase: a novel form of coordination for chromium?

Colin J. Marsden、Kenneth Hedberg、M. Ludwig 等 4 位作者1991-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular structure of chromyl nitrate (CrO2(NO3)2) in the gas phase: a novel form of coordination for chromium?Colin J. Marsden, Kenneth Hedberg, M. M. Ludwig, and Gary L. GardCite this: Inorg. Chem. 1991, 30, 25, 4761–4766Publication Date (Print):December 1, 1991Publicatio…

Thermal and Kinetic AnalysisChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

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S. F. Rastopov、Anatoly T. Sukhodolsky1991-12-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Experiments investigating thermocavitation in binary solutions induced by continuous laser radiation are described. The cavitation consists in periodic rise and collapse of vapor-gas bubbles, accompanied by hydraulic shocks. The necessary condition for obtaining periodic pressure pulses by thermocavitation are investi…

Ultrasound and Cavitation PhenomenaLaser Design and ApplicationsChemical and Physical Studies

Azomesogens: (I) 4-(4′ −n-Alkoxy-2′ −Methylphenylazo)—Benzoic acids: (II) Ethyl 4-(4′ −n-Alkoxyphenylazo)—Benzoates

N. H. Shah、R. A. Vora、N. D. Jadav1991-12-01Molecular crystals and liquid crystals

Two mesongenic homologous series containing azo group are synthesized. The esters of Series II, III and IV exhibit only the smectic phase. The smectic phase exhibits focal conic or fan-shaped textures. Members of Series I exhibit nematic phases, whereas the members of Series II and IV exhibit enantiotropic smectic pha…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPhotochromic and Fluorescence Chemistry

Corrosion Behavior of Alumina Ceramics in Caustic Alkaline Solutions at High Temperatures

Tsugio Sato、Shigeki Sato、Akitsugu Okuwaki 等 4 位作者1991-12-01Journal of the American Ceramic Society

The corrosion rate and changes in the microstructure and fracture strength of alumina ceramics (93.0% Al 2 O 3 and 99.5% Al 2 O 3 ) were studied in 0.1 m to 25 m NaOH solutions at 150°C to 200°C, where m = mol/(kg of H 2 O). The attack of the caustic alkaline solution started at the grain boundaries. Consequently, the…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisMagnesium Oxide Properties and Applications

Initial Stages of the Anodic Oxidation of Iron in Chloride Solutions

Gary W. Ashley、G.T. Burstein1991-12-01CORROSION

Data have been obtained for the rate of reaction of freshly generated iron surfaces at low potentials with aqueous solutions containing chloride ions. The presence of chloride ions accelerates the formation of the first monolayer of oxidized iron, but with no significant increase in the charge required to form it. The…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsElectrochemical Analysis and Applications

Analytical Characterization of Two-Step Braided Composites

Joon‐Hyung Byun、Thomas J. Whitney、Guang-Wu Du 等 4 位作者1991-12-01Journal of Composite Materials

The fabric geometric models based on lamination analogy and stiffness averaging method are utilized to numerically characterize a 2-step braided composite. The model predictions were found to be in good agreement with results of mechanical tests performed in this study. The architecture of this material is investigate…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Reaction and Diffusion Kinetics During the Initial Stages of Isothermal Chemical Vapor Infiltration

Brian W. Sheldon、Theodore M. Besmann1991-12-01Journal of the American Ceramic Society

Individual bundles of ceramic fibers were infiltrated with SiC to study the reaction and diffusion kinetics during isothermal chemical vapor infiltration (CVI). More uniform infiltration was observed in samples where baffles were placed in the reactor and when HCl was added to the inlet gases. The evolution of the mic…

Advanced ceramic materials synthesisAdvancements in Solid Oxide Fuel CellsThermal properties of materials

The crystal structure of fedotovite, K2Cu3O(SO4)3

Галина Л. Старова、С. К. Филатов、V.S. Fundamensky 等 4 位作者1991-12-01Mineralogical Magazine

Abstract The crystal structure of fedotovite, K 2 Cu 3 O(SO 4 ) 3 has been determined, space group C 2/ c , a 19.037(6), b 9.479(2), c 14.231(5) Å, β 111.04(3)°, Z = 8, D x = 3.09 g/cm 3 . The main units of the fedotovite structure are formed around two additional oxygen atoms and consist of edge-sharing [OCu 4 ] tetr…

Crystal Structures and PropertiesPolyoxometalates: Synthesis and ApplicationsInorganic Fluorides and Related Compounds

Assembly and structure of calcium-induced thick vimentin filaments.

Ilse Hofmann、Harald Herrmann、Werner W. Franke1991-12-01PubMed

Using a viscometric assay and various electron microscopic procedures (negative staining, rotary shadowing, ultrathin sectioning) we have determined the influences of different kinds of ions and of ionic strength on the structures formed by assembly of soluble subunits of vimentin from bovine lens tissue or from Esche…

RNA Interference and Gene DeliverySkin and Cellular Biology ResearchSilk-based biomaterials and applications

Structural decline of soils, assessment and prevention

W. W. Emerson1991-12-01Soil Research

Two extreme textural types of cultivated surface soils are mainly considered here, non-shrinking red-brown earths and highly shrinking cracking clays. Total porosity is used to assess the structural status of the former. Values are compared with the highest and lowest values found in the field. For the latter, the cri…

Soil and Unsaturated FlowClay minerals and soil interactionsSoil Management and Crop Yield

On the relative propensities of ether and methylene linkages for liquid crystal formation in calamitics

Andrew Emerson、G. R. Luckhurst1991-12-01Liquid Crystals

The nematic-isotropic transition temperatures for aromatic calamitic compounds with terminal alkyl chains attached via a methylene group are usually found to be lower than those with an ether link. This difference is generally attributed to the higher anisotropy of the molecular polarizability expected for an ether li…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

Optical Properties of a Liquid Crystal Microlens with a Symmetric Electrode Structure

Toshiaki Nose、Shin Masuda、Susumu Sato1991-12-01Japanese Journal of Applied Physics

A disclination line or a shifting effect of the lens center had been observed in a homogeneously aligned or a hybrid-aligned liquid crystal microlens with an asymmetric electrode structure of a hole-patterned electrode and a plane electrode. These deteriorating factors of lens properties can be eliminated by a homogen…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced optical system design

Towards a model for soil structural behavior

JP Quirk、RS Murray1991-12-01Soil Research

Clay particle interaction as mediated by water is considered within the context of attractive and repulsive inter-particle forces-van der Waals forces, ion correlation forces responsible for the potential minimum between Ca-clay particles, cation hydration, ion induced structural forces and diffuse double layer forces…

Soil and Unsaturated FlowClay minerals and soil interactionsGeotechnical and construction materials studies

On the shape of small sessile and pendant drops by singular perturbation techniques

S. O’Brien1991-12-01Journal of Fluid Mechanics

The problem of obtaining asymptotic expressions describing the shape of small sessile and pendant drops is revisited. Both cases display boundary-layer behaviour and the method of matched asymptotic expansions is used to obtain solutions. These give good agreement when compared with numerical results. The sessile solu…

Rheology and Fluid Dynamics StudiesTextile materials and evaluationsVibration and Dynamic Analysis

The determination of crystal size and disorder from the X-ray diffraction photograph of polymer fibres. 2. Modelling intensity profiles

I. H. Hall、R. Somashekar1991-12-01Journal of Applied Crystallography

The intensity profile of the X-ray reflection from a crystalline material is related to the lattice disorder and the distribution of crystal sizes through its Fourier cosine coefficients. However, existing methods of obtaining these structural parameters from the coefficients require more than one order of reflection…

Advanced X-ray Imaging TechniquesCultural Heritage Materials AnalysisX-ray Diffraction in Crystallography