Materials Literature
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Single-wall carbon nanotubes (SWNTs) were functionalized with biotin at the ends and sidewalls of the nanotubes in a series of chemical reactions. Streptavidin-coated gold nanoparticles were attached to the biotin-modified SWNTs in solution in a self-assembly process. Gold nanoparticles which connected two SWNTs were…
Abstract Summary: Poly(butylene succinate) (PBS) and PBS‐based ionomers (PBSi's) with 0.3 and 1.2 mol‐% of sodium sulfonated succinate unit were synthesized. The existence of ionic aggregates in the ionomer matrices was indicated by melt viscosity and glass transition data. It seems that the ionic aggregates have two…
As more alternative, lightweight actuators have become available, the conventional fixed-wing configuration seen on modern aircraft is under investigation for efficiency on a broad scale. If an aircraft could be designed with multiple functional equilibria of drastically varying aerodynamic parameters, one craft capab…
A facile, efficient synthesis of 1 --> 3 C-branched polyamide dendrons is described. Treatment of acryloyl chloride with 1 --> 3 C-branched amines, e.g., di-tert-butyl 4-[2-(tert-butoxycarbonyl)ethyl]-4-aminoheptanedioate, gave the corresponding acrylamides in high yields, which upon reaction with nitromethane generat…
The template-directed nucleation of inorganic materials by organic supramolecular frameworks is an overarching principle in biomineralization. In the present work, synthesized latex particles of poly(styrene-ran-methacrylic acid) were used as additives for the crystallization modification of calcium carbonate (CaCO 3…
Low molecular weight peptidomimetics with simple amphiphilic sequences can help to elucidate the structures of cross beta-sheet assemblies, such as amyloid fibrils. The peptidomimetics described herein comprise a dibenzofuran template, two peptide strands made up of alternating hydrophilic and hydrophobic residues, an…
The adsorption of an armchair single-walled carbon nanotube (CNT) on fully and partially hydrogenated Si(001) surfaces are studied from first-principles calculations. Our results indicate that the electronic properties of the adsorbed CNT can be ruled by the H concentration along the CNT–H∕Si(001) contact region. On t…
Diamond has been identified as a very promising material for X and ultraviolet sensing. In this Letter, a photoconductive device based on a freestanding homoepitaxial chemically vapor deposition (CVD) single-crystal diamond 500μm thick has been tested. Photoconductive measurements in coplanar and transverse configurat…
Highly oriented Ba0.7Sr0.3TiO3 thin films were grown on MgO (001) single-crystal substrate using pulsed-laser deposition and the in-plane ferroelectric properties of the film were evaluated. X-ray diffraction characterization revealed a good crystallinity and tensile in-plane stress in the film. A well-defined ferroel…
Separation of single-walled carbon nanotubes (SWNTs), according to their electronic characteristics, is essential to the development of molecular electronics, including field-effect transistors. Recent efforts by many groups have used non-covalent and covalent sidewall chemistry to probe differential reactivity in met…
We characterized single-walled carbon nanotubes before and after HNO3/H2SO4 treatments for different times by scanning electron microscopy, Raman spectroscopy, and N2 adsorption at 77 K. Single-walled carbon nanotube assembly revealed a bimodal pore structure of microporosity (surface area of 476 m2 g(-1)) and mesopor…
We performed direct solvent-free amination of multi-walled carbon nanotubes (MWCNTs) with nonylamine, dodecylamine, octadecylamine, 4-phenylbutylamine and 1,8-ocanediamine at a temperature of 150-170 degrees C and reduced pressure. Thermogravimetric analysis and temperature-programmed desorption-mass spectrometry reve…
Single-crystalline MgxZn1−xO (0≤x≤0.25) nanowires on glass substrates obtained by a hydrothermal method: growth, structure and electrical characteristics, Lee, Chia Ying, Tseng, Tseung Yuen, Li, Seu Yi, Lin, Pang
This paper discusses the implications of the aqueous hydrogen level stress corrosion cracking (SCC) functionality on modeling the temperature dependency (thermal activation energy) of nickel alloy SCC. Prior testing has identified a significant effect of hydrogen level on the SCC of nickel-based alloys in high tempera…
A multi-layered nanocomposite thin film was fabricated to increase the density of PbSe quantum dots. It consisted of low-loss polymer layers and multi-stacked PbSe quantum dot layers in series. The solutions of a UV-curable low-loss polymer and PbSe quantum dots were spin-coated layer-by-layer. An arrayed and multi-st…
We report a simple low-temperature inverse micelle solvothermal route for the synthesis of a large quantity of single-crystalline germanium nanocrystals. X-ray diffraction measurement indicates that the as-prepared nanocrystals are composed of pure Ge with a cubic structure. The morphology, size, chemical composition,…
Abstract The present study compares the properties of five films: one film of low‐density polyethylene (LDPE), two films of linear low density polyethylenes (1‐octene comonomer)—one made by metalllocene catalyst (mLLDPE) and the other by Ziegler–Natta (zLLDPE)—and two blend films, one of mLLDPE/LDPE (film A) and the o…
The alkali-metal iodide double-walled carbon nanotube composites MI@DWNTs (M = K, Cs) have been prepared using a melt-phase filling procedure. The imaging and subsequent structural analysis of the encapsulated metal iodide crystals was performed with a combination of phase restored high-resolution transmission electro…
We report the hierarchical self-assembly of ZnO nanoparticles on single-walled carbon nanotubes (SWCNT–ZnO) and multi-walled carbon nanotubes (MWCNT–ZnO) by utilizing an electrostatic coordination approach. The affinity for Zn atoms to the oxygen of the C = O in the carboxyl groups is utilized to decorate oxidized sin…
Poly(amic ester) (PAE) is a soluble precursor of polyimide that has attracted interest from both the microelectronic and the flat-panel display industries because of its several important advantages, including excellent solubility, high hydrolytic stability, and solvent-free film formation, over the polyimide precurso…