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Physical and chemical properties of singlet molecular oxygen

David R. Kearns1971-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhysical and chemical properties of singlet molecular oxygenDavid R. KearnsCite this: Chem. Rev. 1971, 71, 4, 395–427Publication Date (Print):August 1, 1971Publication History Published online1 May 2002Published inissue 1 August 1971https://pubs.acs.org/doi/10.1021/cr60272a0…

Porphyrin and Phthalocyanine ChemistryInorganic and Organometallic ChemistryOxidative Organic Chemistry Reactions

Nuclear Reactor Theory

E.M. Gelbard1971-08-01OpenAlex

"Nuclear Reactor Theory." Nuclear Science and Engineering, 45(2), pp. 234–235

Nuclear reactor physics and engineeringGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

On the attenuation of 9.4 GHz longitudinal hypersonic waves in some trigonal crystals

W Liekens、L. Michiels、August Böck1971-07-30Journal of Physics C Solid State Physics

The temperature dependence of the attenuation of longitudinal hypersonic waves at 9.4 GHz has been measured in 'perfect' specimens of trigonal crystals: quartz, lithium niobate and corundum. It is found that this attenuation follows a T 6.5 -law in the range 0.1<or= alpha (db/cm)<or=5. The results are in good qualitat…

Numerical methods in engineeringUltrasonics and Acoustic Wave PropagationThermal properties of materials

Normal mode assignments in vitreous silica, germania and beryllium fluoride

R. J. Bell、P. Dean、D C Hibbins-Butler1971-07-30Journal of Physics C Solid State Physics

Detailed assignments are given for normal modes of vibration in vitreous silica, germania and beryllium fluoride. They have been obtained by calculating the atomic displacement eigenvectors for selected modes throughout the spectrum, and separating the kinetic energy of these modes into contributions from cation motio…

Glass properties and applicationsPhotonic Crystals and ApplicationsPhotorefractive and Nonlinear Optics

Microkinetics of lamellar crystallization in a long chain polymer

E. H. Andrews、P. J. Owen、Ajay Singh1971-07-27Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract The growth kinetics of single crystal lamellae grown from polyisoprene melts have been determined by thin film electron microscopy which also reveals the relevant microstructure. The growth rate of a continuous lamellar crystal is independent of the length of the crystal and (in the absence of crosslinks) dep…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Study of the nature of the metal-binding sites and estimate of the distance between the metal-binding sites in transferrin using trivalent lanthanide ions as fluorescent probes

Chun Ka Luk1971-07-20Biochemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of the nature of the metal-binding sites and estimate of the distance between the metal-binding sites in transferrin using trivalent lanthanide ions as fluorescent probesChun Ka LukCite this: Biochemistry 1971, 10, 15, 2838–2843Publication Date (Print):July 20, 1971Pub…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Optical Absorption Edge of SrTiO3Around the 105-K Phase Transition

K. W. Blazey1971-07-19Physical Review Letters

The wavelength-modulated absorption and reflection spectra of SrTi${\mathrm{O}}_{3}$ have been measured as functions of temperature. Over a 60-K temperature range around the structural phase transition the band gaps of both high- and low-temperature phases are observed simultaneously. This effect and an associated ban…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsElectronic and Structural Properties of Oxides

Deformation of Ordered CuAu Alloy

B. P. Adrianovskii、B. A. Greenberg、V. I. Syutkina 等 5 位作者1971-07-16physica status solidi (a)

The mechanism of deformation of the ordered CuAu alloy is investigated using electron microscopy. The alloy deformation is shown to be accomplished by slipping; a larger degree of deformation involves the mechanism of twinning. The interaction between dislocations and the boundaries of 90° -disoriented domains has bee…

Quasicrystal Structures and PropertiesMetallurgical and Alloy ProcessesMetallurgy and Material Science

Intrinsic Coercivity of BaFe12−xCrxO19

K. Haneda、H. Kojima1971-07-16physica status solidi (a)

The influence of the partial substitution of Cr for Fe in BaFe12O19 on the intrinsic coercive force has been investigated. The specimens BaFe12−xCrxO19 (x = 0 to 3.0) were prepared by the ordinary powder method. The intrinsic coercive force iHc, saturation magnetization Is, and anisotropy constant K, at room temperatu…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Dielectric Constant of Mixed Ionic Crystals

Kan-ichi Kamiyoshi、Yutaka Nigara1971-07-16physica status solidi (a)

The dielectric constants of NaClNaBr, KClKBr, RbClRbBr, KClRbCl, and KIRbI mixed ionic crystals were measured by the “immersion method” at 1 MHz as a function of concentration. Their variations with the mole fraction were represented by convex curves. A semi-empirical equation for calculating the dielectric const…

Ionic liquids properties and applicationsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Photoemission Studies of Platinum

Sansan Lin、D. T. Pierce、W. E. Spicer1971-07-15Physical review. B, Solid state

Photoelectron energy-distribution curves of Pt at photon energies $6.8\ensuremath{\le}\ensuremath{\hbar}\ensuremath{\omega}\ensuremath{\le}11.6$ eV exhibit structure originating from initial states 3.6, 2.5, 1.5, and between 0.7 and 0.2 eV below ${E}_{F}$. A strong peak at - 0.2 eV observed for $\ensuremath{\hbar}\ens…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Time-of-Flight Spectroscopy of Metastable Photodissociation Fragments. N2O Dissociation in the Vacuum uv

R. K. Gilpin、K. H. Welge1971-07-15The Journal of Chemical Physics

The photodissociation of N2O involving electronically excited metastable fragments has been investigated at wavelengths ≳ 1050 Å by photofragment translational energy spectroscopy. Irradiation was carried out with light pulses of a few microseconds duration, and fragment energies were measured by means of the time-of-…

Mass Spectrometry Techniques and ApplicationsNuclear Materials and PropertiesIon-surface interactions and analysis

Collisional Deactivation of O2(1Δg)

F. D. Findlay、D. R. Snelling1971-07-15The Journal of Chemical Physics

This paper reports determinations of collisional deactivation rate constants for O2(1Δg) by minor atmospheric constituents and other gases. The benzene–oxygen photochemical system was used to produce O2(1Δg), and relative concentrations were measured by monitoring the intensity of its emission at 1.27 μ. The rate cons…

Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceIndustrial Gas Emission Control

Polarized Vibrational Spectra of Potassium Chlorate

J.B. Bates1971-07-15The Journal of Chemical Physics

The Raman spectra of single crystal KClO3 were measured in the region above 30 cm−1 at 298 and 77°K. Single crystal infrared spectra in the internal mode region were measured by reflection at 298°K. Infrared spectra of the polycrystalline material also were measured at 77°K. Assignments for all of the crystal vibratio…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Cation Diffusion and Conductivity in Solid Electrolytes. I

Hiroshi Sato、Ryoichi Kikuchi1971-07-15The Journal of Chemical Physics

The characteristics of cation diffusion and ionic conductivity in solid electrolytes are discussed using β- and β″-alumina as examples. The problem is characterized by a cation migration by the vacancy mechanism in a “cation-disordered phase,” a system in which the number of available vacant sites is of the same order…

Material Dynamics and PropertiesThermal Expansion and Ionic ConductivityThermodynamic and Structural Properties of Metals and Alloys

Role of Rate Equations in the Theory of Luminescent Energy Transfer

W. J. Grant1971-07-15Physical review. B, Solid state

In this paper we derive from first principles, equations describing the kinetics of luminescent transfer. We apply the Pauli equation to an appropriately defined density matrix to derive, under one formalism but under opposite limiting assumptions, both the usual nonlinear kinetic rate equations and the equations whic…

Luminescence Properties of Advanced MaterialsPhotochemistry and Electron Transfer StudiesQuantum optics and atomic interactions

Electrohydrodynamic and Dielectric Instabilities of Cholesteric Liquid Crystals

W. Helfrich1971-07-15The Journal of Chemical Physics

A model is proposed for electrohydrodynamic alignment effects in cholesteric liquid crystals. We derive and discuss a formula for the threshold voltage of such alignment, starting from the planar texture between two conducting plates. An improved formula for the threshold of the dielectric deformation of this orientat…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationFluid Dynamics and Thin Films

Electronic Core Levels of theIIB−VIACompounds

C. J. Vesely、D. W. Langer1971-07-15Physical review. B, Solid state

X-ray induced electron-emission measurements were used to determine the energy levels of core electrons in ZnO, ZnS, ZnSe, ZnTe, CdO, CdS, CdSe, CdTe, HgS, HgSe, and HgTe. The investigated energy range extends from the bottom of the valence band to about 1200 eV below the Fermi level. Chemical shifts were determined b…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Raman Spectra and Lattice Dynamics of Tellurium

A. S. Pine、G. Dresselhaus1971-07-15OpenAlex

The Raman spectrum of trigonal tellurium has been obtained at 295 and 90 \ifmmode^\circ\else\textdegree\fi{}K. The Raman-active ${A}_{1}$ singlet and two $E$ doublets are identified by the scattering polarization selection rules, and the $E$-mode LO-TO splittings and linear wave-vector shifts are observed. The natural…

High-pressure geophysics and materialsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Nonequilibrium Steady-State Statistics and Associated Effects for Insulators and Semiconductors Containing an Arbitrary Distribution of Traps

J.G. Simmons、G.W. Taylor1971-07-15OpenAlex

The statistics for an arbitrary distribution of traps under nonequilibrium steady-state conditions is derived, and it is seen to be identical in form to the Shockley-Read expression for a single trapping level. The energy dependence of the statistics has been investigated, and several interesting features have been de…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena