Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRelaxation of Disulfide and Tetrasulfide PolymersA. V. Tobolsky, W. J. MacKnight, and M. TakahashiCite this: J. Phys. Chem. 1964, 68, 4, 787–790Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 1964https://pubs.acs.…
The thermal dilatation of VO 2 has been measured on ceramic samples from room temperature to 95°C, in connection with Mott's consideration which interpretes the non-metal to metal transition observed in some transition metal oxides as an effect of contraction of lattice spacings. A discontinuous volume expansion was u…
The oxidation‐reduction equilibrium between ferrous and ferric iron in Na 2 O · 2Si0 2 glass melts was studied by equilibrating melts with various oxygen partial pressures. Exceedingly long equilibration times were required to obtain meaningful results. The reaction appears to be diffusion‐controlled and may be expres…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTransition Metal-Hydrogen Compounds. II. The Crystal and Molecular Structure of Potassium Rhenium Hydride, K2ReH9S. C. Abrahams, A. P. Ginsberg, and K. KnoxCite this: Inorg. Chem. 1964, 3, 4, 558–567Publication Date (Print):April 1, 1964Publication History Published online1…
Pit origin and formation in stainless steels are discussed according to results of investigations from the following points of view: Conditions for the Existence of Pitting Corrosion.Pitting potential range and pitting potentials. Functions dependent on the potential which are important for pitting corrosion, effect o…
The influence of impurity segregation on the kinetics of spherulitic crystallization is examined. Radial growth rates over a range of temperatures are reported for a number of polymers containing various proportions of impurity species of widely varying molecular weight. Variations of growth rate with molecular weight…
On the basis of present investigations, copper(II) compounds with subnormal magnetic moments can be roughly divided into two types. Those with direct copper-to-copper interaction have short copper-to-copper distances. In these compounds, of which copper(II) acetate monohydrate is an example, the bonding is postulated…
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A systematic study of impurity segregation in spherulitic crystallization is described. The experiments deal principally with high polymers, in which the role of ``impurities'' is fulfilled by stereoirregular molecules or by molecules of low molecular weight. It is shown that these species are rejected preferentially…
The theory of the work-hardening curve of a pure single crystal is discussed. An outline is given of the experimental methods available for the study of the mechanism of plastic deformation and work hardening. An attempt is made to correlate existing theories of work hardening. The theory is illustrated by discussions…
Abstract Combined X-ray topographic and phase-contrast micrographic studies of natural diamond octahedral faces show that pyramidal trigons are always associated with dislocation outcrops. No dislocations outcrop at flat-bottomed trigons. On the other hand, absence of trigons does not necessarily imply absence of outc…
Fission fragment angular distributions have been measured with gold surface barrier detectors for proton-induced fission of ${\mathrm{U}}^{233}$, ${\mathrm{U}}^{234}$, ${\mathrm{U}}^{235}$, ${\mathrm{U}}^{236}$, ${\mathrm{U}}^{238}$, ${\mathrm{Np}}^{237}$, and ${\mathrm{Pu}}^{239}$. Absolute fission cross sections wer…
The spectrum of the recombination radiation from diamond has been measured over the photon energy range 4.9-5.5 eV at 90, 160, 207, and 320\ifmmode^\circ\else\textdegree\fi{}K. At 90\ifmmode^\circ\else\textdegree\fi{}K, recombination emission has been detected from ten samples out of a batch of fifteen single crystals…
Received 17 February 1964DOI:https://doi.org/10.1103/PhysRevLett.12.275©1964 American Physical Society
The physical model of two-dimensional p-electron delocalization proposed by Bersohn for crystalline iodine is examined. The principal features of the model are adopted, including the Hückel method for writing one-electron orbitals and the restriction to nearest nonbonded neighbor interactions. Crystal symmetry is expl…
The vaporization behavior of the systems boron—carbon and boron—carbon—silicon has been studied with a mass spectrometer. In addition to the gaseous species characteristic of graphite, silicon carbide and boron, the molecules BC2, B2C, BCSi, BSi2, BC, and BSi were identified and their atomization energies measured. Th…
By classifying particle center positions with a hexagonal grid, evaluation of the two-dimensional rigid sphere partition function is reduced to a special lattice statistics problem, with precisely defined nearest-neighbor effective pair interactions. The hexagonal cell size is chosen to be the maximum consistent with…
A framework for interpreting experiments on Doppler shifts in light scattering from pure liquids and polymer solutions is presented. The spectral density of the light scattered into a given frequency range and angle by a liquid composed of identical, isotropic particles much smaller than the wavelength of the incident…
ONE-DIMENSIONAL DISOI~DER IN SODIUM 2-OXOCAPRYLATE respectively are normal.These contacts are as follows : C(x, y, z)-C(~, ~, z) 4.02 A C(x, y, z)-C(~, 1-y, z) 4.29 C(x, y, z)-C(~, y, z-½) 4-12 C(x,y,z)-C(5, y,z+½) 4.12The structure analysis has been only recently completed, and it has therefore not yet been possible…
The formation of a silver ferrite of empirical formula AgFeO~ by reactions involving iron hydroxides and silver compounds in aqueous suspensions was reported by The initial interest of these authors was in use of the red-colored silver compound in identification of specific iron hydroxide compounds. The products obtai…