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Electronic absorption spectra of tetragonal and pseudotetragonal cobalt(II). I. Dipotassium tetrafluorocobaltate, dirubidium tetrafluorocobaltate, dipotassium magnesium tetrafluorocobaltate, and dirubidium magnesium tetrafluorocobaltate

J. W. Ferguson、T E Wood、H. J. Guggenheim1975-01-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic absorption spectra of tetragonal and pseudotetragonal cobalt(II). I. Dipotassium tetrafluorocobaltate, dirubidium tetrafluorocobaltate, dipotassium magnesium tetrafluorocobaltate, and dirubidium magnesium tetrafluorocobaltateJ. Ferguson, T. E. Wood, and H. J. Gugg…

Magnetism in coordination complexesElectronic and Structural Properties of OxidesSurface and Thin Film Phenomena

Cyanoporphyrins. Co-ordinating and electrochemical properties

H. J. CALLOT、Alain Giraudeau、Maurice Gross1975-01-01Journal of the Chemical Society Perkin Transactions 2

Successive substitutions in the pyrrole rings of tetraphenylporphyrin by up to four cyano-groups lead to large additive anodic shifts of the redox potentials. These shifts are large than those observed with other electron-withdrawing substituents. The stoicheiometry and stability of the complexes formed from metallote…

Electrochemical sensors and biosensorsPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Cyclization in crosslinking polymerization. I. Chain polymerization of a bis unsaturated monomer (monodisperse case)

Karel Dušek、M. Ilavský1975-01-01Journal of Polymer Science Polymer Symposia

Abstract Cyclization in the chain polymerization of bis unsaturated monomers has been treated by cascade formalism based on primary chains for a kinetically controlled reaction. The primary chains consist of repeat units bearing an unreacted (pendent) double bond and units engaged in effective branchings (crosslinks),…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Hot‐Working of Aluminum Oxide: II, Optical Properties

W. H. Rhodes、David J. Sellers、T. Vasilos1975-01-01Journal of the American Ceramic Society

Polycrystalline Al 2 O 3 fabricated into plates or shapes by hot‐working techniques exhibits high in‐line transmittance from 0.4 to 5.5 μm. Examination of the product by an inverse pole figure technique demonstrated a strong {0001} texture normal to the pressing direction for both equiaxed and textured microstructures…

Advanced ceramic materials synthesisAluminum Alloy Microstructure PropertiesAdvanced Surface Polishing Techniques

The Influence of Structure on Autohesion (Self-Tack) and other forms of Diffusion into Polymers

R. P. Campion1975-01-01The Journal of Adhesion

Autohesion is discussed emphasising in particular the influence of polymer chain structure on apparent rates of diffusion. The full range of autohesive levels which exists amongst rubbery polymers is rationalised by proposing a distinction between inter-chain free volume and “intra-chain” free volume, the latter being…

Asphalt Pavement Performance EvaluationPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Source Theory Viewpoints in Deep Inelastic Scattering

Julian Schwinger1975-01-01Proceedings of the National Academy of Sciences

The phenomena of deep inelastic electron scattering on single nucleons, viewed as virtual photon absorption, are reexamined with the nonspeculative, phenomenological attitude of source theory. The use of a double spectral representation for forward scattering, and of experimental inputs from the low energy resonance r…

High-Energy Particle Collisions ResearchX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Optically active additives in twisted nematic devices

E. P. Raynes1975-01-01Revue de Physique Appliquée

A study has been made of the use of optically active additives in twisted nematic devices to remove areas of reverse twist, the results obtained depending on the chirality of the additives and the director alignment on the two containing surfaces. Under certain conditions degeneracy of the field induced reorientation…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

O− centre formation in YAG crystals doped with rare earth ions

Jiří Kvapil、Josef Kvapil、B. Perner1975-01-01Kristall und Technik

Abstract Colour changes of YAG crystals doped with rare earth ions and annealed in hydrogen, oxygen, vacuum or argon are described. The influence of UV irradiation is also given. Some crystals were further doped with Ca, Sr, Ba, or Cr, respectively. Yellow or brown colouring of the crystals is attributed to the O − ce…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

The deformable relaxation mesh technique for solution of electron optics problems

R.B. True1975-01-01OpenAlex

This paper describes the principles of a method for the solution of electron optics problems which has led to significant design improvements in traveling wave tubes over the past few years. In contrast to Conventional procedures which solve Poisson's equation on square meshes, the space within the problem boundaries…

Particle Accelerators and Free-Electron LasersElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Autoxidation of 5-methyl-5,6,7,8-tetrahydrofolic acid

J. Anthony Blair、Anthony J. Pearson、Anthony J. Robb1975-01-01Journal of the Chemical Society Perkin Transactions 2

The autoxidation of 5-Methyl-5,6,7,8-tetrahydrofolic acid has been studied by kinetic methods and product analysis. The yields of the two major products, 5-methyl-5,6-dihydrofolic acid and 4a-hydroxy-5-methyl-4a,5,6,7-tetrahydrofolic acid, were determined under a variety of conditions. Attempts to observe or isolate p…

Porphyrin and Phthalocyanine ChemistryChemical Synthesis and ReactionsOrganic Chemistry Cycloaddition Reactions

Thermodynamic properties of the calcium + calcium chloride system measured by an electrochemical technique

Vishu Dosaj、C. Aksaranan、David R. Morris1975-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

A galvanic cell study of the Ca + CaCl2 system is reported. By proper allowance for electronic conduction in the electrolyte phase, the thermodynamic properties have been determined. These data are in good agreement with a vapour pressure study and phase diagram determinations. A model is proposed based upon non-stoic…

Ionic liquids properties and applicationsMolten salt chemistry and electrochemical processesThermal Expansion and Ionic Conductivity

Synthese von 2‐Amino‐3‐cyano‐pyrrolen

H. J. Roth、Kurt Eger1975-01-01Archiv der Pharmazie

Abstract Es wird eine einfache Synthese für 2‐Amino‐3‐cyano‐pyrrole beschrieben, die in der Kondensation von α‐Hydroxyketonen, primären Aminen und Malonitril besteht.

Porphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistrySynthesis and Characterization of Pyrroles

Crystal and molecular structure, electron spin resonance, and electronic spectrum of hexakis(imidazole)copper(II) nitrate

Dennis L. McFadden、Andrew T. McPhail、C. David Garner 等 4 位作者1975-01-01Journal of the Chemical Society Dalton Transactions

The structure of the title compound has been established by three-dimensional X-ray crystal-structure analysis from diffractometer data. Crystals are monoclinic, space group P21/c, with a= 8·65(1), b= 17·64(1), c= 8·38(1)Å, β= 93·20(10)°, Z= 2. The structure was solved by the heavy-atom approach and molecular paramete…

Metal complexes synthesis and propertiesCrystal structures of chemical compoundsMagnetism in coordination complexes

A Simple Two-Band Theory of Galvanomagnetic Effects in Graphite in Relation to the Magnetic Field Azimuth

Kiyoshi Noto、Takurō Tsuzuku1975-01-01Japanese Journal of Applied Physics

A simple two-band theory of galvanomagnetic effects in graphite has been developed so as to involve not only the magnetic field intensity ( H ) but its azimuth (θ) with respect to the c-axis, which successfully accounts for the complicated behavior of transverse magnetoresistance (Δρ/ρ 0 ) in an iron-melt graphite pre…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsGraphite, nuclear technology, radiation studies

The Difference Infrared Spectra of Titanium-Containing Vitreous Silica

Carlyle Franklin Smith、R. A. Condrate、W. E. Votava1975-01-01Applied Spectroscopy

Vitreous silicas containing up to 10% titania are of significant commercial importance because of their low thermal expansions. Instrumental techniques are being developed to determine the structure of the titanium groups in these glasses in order to relate their reduced thermal expansitivities with structural propert…

Glass properties and applicationsMineralogy and Gemology Studies

Identification of enantiomorphism in crystals by electron microscopy

Omer Van der Biest、G. Thomas1975-01-01Acta Crystallographica Section A

Simple electron-microscopy techniques are described which allow one to detect the presence of two enantiomorphous forms of a structure within an apparent single crystal. The first method consists of a characterization of the interface between the two enantiomorphs. In the second method advantage is taken of violations…

Crystallization and Solubility StudiesX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds

New adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine and their vibrational, magnetic, and electronic properties. Part I. Reactivity towards oxygen

F. Cariati、Dario Galizzioli、Franca Morazzoni 等 4 位作者1975-01-01Journal of the Chemical Society Dalton Transactions

Different reaction temperatures have allowed the isolation of 1 : 1 and 1 : 2 adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine. Thermal, vibrational, and magnetic-susceptibility analyses have provided useful information about the structural properties of these complexes; e.s.r. and electronic s…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Selenium dioxide oxidation of d-limonene. Reinvestigation

Harbo P. Jensen、K. Barry Sharpless1975-01-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelenium dioxide oxidation of d-limonene. ReinvestigationHarbo P. Jensen and K. Barry SharplessCite this: J. Org. Chem. 1975, 40, 2, 264–265Publication Date (Print):January 1, 1975Publication History Published online1 May 2002Published inissue 1 January 1975https://doi.org/1…

Electrochemical sensors and biosensorsEnzyme Catalysis and ImmobilizationPorphyrin and Phthalocyanine Chemistry