Materials Literature
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Self-assembled nanotapes of a few tailor-made oligo(p-phenylenevinylene)s (OPVs) have been prepared and used as supramolecular donor scaffold to study the fluorescence resonance energy transfer (FRET) to a suitable acceptor. In nonpolar solvents, FRET occurs with nearly 63-81% efficiency, exclusively from the self-ass…
Microporous solid K3PW12O40 is prepared by precipitation of phosphotungstic acid and potassium ion, followed by calcination. Using this material as photocatalyst, a series of dye pollutants, such as rhodamine B, malachite green, rhodamine 6G, fuchsin basic, and methyl violet, were efficiently degraded in the presence…
The exploitation of biological macromolecules, such as nucleic acids, for the fabrication of advanced materials is a promising area of research. Although a greater variety of structural and functional uses can be envisioned for protein-based materials, systematic approaches for their construction have yet to emerge. C…
Indium tin oxide nanoparticles with tin oxide contents varying from 2 to 30 wt % have been synthesized via a nonaqueous sol−gel procedure involving the solvothermal treatment of indium acetylacetonate and tin tert -butoxide in benzyl alcohol. According to powder X-ray diffraction analysis combined with Rietveld refine…
We report the observation of exchange bias phenomena in the hole-doped perovskite cobaltites ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{CoO}}_{3}$ ($x=0.12$, 0.15, 0.18, and 0.30) in which a spontaneous phase separation occurs. When the ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{CoO}}_{…
A nanoparticle magnetic resonance imaging (MRI) contrast agent was developed by conjugation of more than 500 gadolinium chelate groups onto a viral capsid. The high density of paramagnetic centers and slow tumbling rate of modified MS2 capsids provided enhanced T1 relaxivities up to 7200 mM-1s-1 per particle. A bimoda…
We present a novel NMR technique that provides a non-invasive, direct measurement of gas exchange in a three-dimensional gas-fluidized bed of solid particles. The NMR spectrum of hyperpolarized 129Xe gas in an Al2O3 particle bed displays three resolved peaks corresponding to xenon in bubbles, the interstitial spaces (…
In order to propose a ferromagnet exhibiting highly spin-polarized transport, we theoretically analyzed the spin polarization ratio of the conductivity of the bulk ${\mathrm{Fe}}_{4}\mathrm{N}$ with a perovskite-type structure, in which N is located at the body center position of the fcc-Fe. The spin polarization rati…
This Account presents recent advances in understanding how and why dilute solutions/sols of low-molecular-mass organic gelators (LMOGs) undergo microscopic phase separation to form self-assembled fibrillar networks in molecular organogels. Concepts are illustrated structurally at the subnanometer (molecular) to severa…
Abstract Previously, bi‐axial self‐reinforcement of high‐density polyethylene (HDPE) was achieved through a uni‐axial shear stress field introduced by dynamic packing injection molding technology. Here, further improvement of tensile strength along the flow direction (MD) was achieved by blending a small amount of hig…
Abstract The backscattering coefficient of low–medium energy electron beams (from 250 to 10 000 eV) impinging on C/Al double layered thin films was investigated by a Monte Carlo simulation. The aim of the research was to study the behaviour of the backscattering coefficient as a function of the beam primary energy and…
X-ray crystallography has revealed two similar alpha/beta domains of the aspartate racemase from the hyperthermophilic archaeon, Pyrococcus horikoshii OT3. The active site is located in the cleft between the two domains where two cysteine residues face each other. This arrangement allows the substrate to enter the cle…
Within an Onsager-like density functional theory we explore the thermodynamic and structural properties of an isotropic and nematic fluid of hard needle-like colloids in contact with a hard substrate coated with a soft short-ranged attractive or repulsive layer. As a function of the range and the strength of the soft…
We investigate the effect of annealing on the Ge nanocrystal formation in multilayered germanosilicate–oxide films grown on Si substrates by plasma enhanced chemical vapour deposition (PECVD). The multilayered samples were annealed at temperatures ranging from 750 to 900 °C for 5 min under nitrogen atmosphere. The ons…
Filling effect of silica on dielectric and mechanical properties of ethylene propylene diene/acrylonitrile butadiene rubber EPDM/NBR blends with different compositions was studied. To solve the problem of phase separation polyvinyl chloride (PVC) with concentration 10 phr was added. The dielectric data for the investi…
Immanuel Kant describes his approach as a ‘Copernican Revolution’ in philosophy. Copernicus put forward the theory that the earth moves round the sun rather than vice versa. Kant’s revolutionary idea is that the world that we inhabit and perceive depends on qualities of the perceiver’s mind, rather than simply existin…
A series of water-resistant cellulose films was prepared by coating castor oil based polyurethane (PU)/benzyl starch (BS) semi-interpenetrating polymer networks (semi-IPN). All of the coated films, with a very thin coating layer of about 0.4 μm, exhibited much better optical transmittance, water resistance, and mechan…
The pore shape and size of MCM-41 were studied analytically by comparing the observed powder X-ray diffraction intensities with that derived from the MCM-41 crystal structure models, with two different pore shapes, a hexagon and a circle. The powder diffraction patterns from the as-synthesized and the calcined MCM-41…
This paper reports the results of an investigation on the effect of shear deformations on wave propagation in carbon nanotubes embedded in an elastic matrix. A multi-walled carbon nanotube is considered as a multiple shell coupled together through van der Waals forces between two adjacent tubes. The surrounding matrix…
Fully coordinated ultrathin silica nanotubes are derived by performing first-principles calculations. The nanotubes are well ordered and are of three magic configurations, quite different from the conventional amorphous thick silica nanotubes. They possess low intrinsic strain energy, tunable band gaps, and high stiff…