Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic properties of the complex di-.mu.-hydroxo-bis[2-(2-ethylaminoethyl)pyridine]dicopper(II) perchlorateDavid Y. Jeter, David L. Lewis, Judith C. Hempel, Derek J. Hodgson, and William E. HatfieldCite this: Inorg. Chem. 1972, 11, 8, 1958–1960Publication Date (Print):Augu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic spectrum of trinuclear chromium(III) acetateL. Dubicki and P. DayCite this: Inorg. Chem. 1972, 11, 8, 1868–1875Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 August 1972https://pubs.acs.org/doi/10.1021/ic50…
Abstract The formation of silver crystallites in silver-form zeolites was investigated, mainly by means of X-ray diffraction analysis. Silver ions were reduced to the zero-valent state; they aggregated to metals in three cases in this study—first, when silver-form zeolites were heated in a helium flow at above 600°C;…
The majority of theoretical work on the scattering of radiation from plasma is restricted to the low temperature regime where v/c<<1. Nevertheless it is common practice to apply the results of these theories to plasmas for which v/c/ approximately 0.05. (T e > approximately 600 eV). The theory of incoherent scattering…
The crazing behaviour of a grade of polystyrene which crazes profusely when tested in tension has been studied at 293°K using quantitative optical, electron and electron scanning microscopy. Tensile tests on this material showed that a high density of crazes was produced at room temperature. The crazes formed in a zon…
The kinetics of the initial‐stage sintering of a UO 2 powder in H, were investigated over the range 600° to 1200°C by dilatometry. Decreasing green density below #40% of theoretical leads to progressively reduced rates of sintering. Initiation of the effect is related to a critical value of the ratio of pore size to p…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron spectroscopy for chemical analysis (ESCA) studies on catalysts. Rhodium on charcoalJ. S. Brinen and A. MeleraCite this: J. Phys. Chem. 1972, 76, 18, 2525–2526Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 Aug…
The polarized laser-Raman scattering of oriented single crystals of β-AgI has been investigated at 300°, 80°, and 4.2°K. The fundamental optic lattice modes predicted by group theory were observed and assigned on the basis of scattering tensors. Further support for the present assignments of the β-AgI optic lattice mo…
In a copper crystallite containing many hundreds of atoms the static and dynamic behavior of point defects is simulated by means of an electronic computer. This follows the lines of an earlier work by Gibson et al. We have extended their investigation to collisions with subthreshold energies using a new computer progr…
The compound Bi2WO6 has been prepared as a ceramic and in single crystal form. Growth of Bi2WO6 single crystals from the melt by the Czochralski method produced boules as large as 20 mm in diameter by 60 mm long. On cooling to room temperature these boules invariably cracked, yielding for experimental investigations s…
Abstract On the example of transition metal hydrides, the role of interaction between interstitial atoms in the formation of ordered solid solutions and interstitial compound structures has been examined.
After revision, the molecular weight of the subunit of Escherichia coli K12 aspartokinase I‐homoserine dehydrogenase I is 86000 ± 4000 instead of 60000 as previously published. The enzyme is a tetramer, not an hexamer. The electrophoretic homogeneity of the subunits, the number of unique sequences around cysteinyl and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIndication of the magnitude of orientation factors in esterificationDan R. Storm and D. E. Koshland Jr.Cite this: J. Am. Chem. Soc. 1972, 94, 16, 5805–5814Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 August 1972http…
ADVERTISEMENT RETURN TO ISSUEPREVArticle1,3-Dioxolan-2-ylium and related heterocyclic cationsCharles U. Pittman, Samuel P. McManus, and John W. LarsenCite this: Chem. Rev. 1972, 72, 4, 357–438Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 August 1972https://doi…
The intensity ratio of the 004 to the 002 diffraction line, I(004)/I(002), was measured for graphitizing C atoms, non-graphitizing C atoms, carbon blacks and a neutron-irradiated carbon. The values of I(004)/I(002) are different for different C atoms even when they have the same interlayer spacing d002. For example, a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface charge development of porous silica in aqueous solutionR. P. AbendrothCite this: J. Phys. Chem. 1972, 76, 18, 2547–2549Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 August 1972https://pubs.acs.org/doi/10.1021…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron paramagnetic resonance studies of the electronic structure of bis(cyclopentadienyl)vanadium dichloride and a comparison with simple molecular orbital calculationsDennis P. Bakalik and Robert G. HayesCite this: Inorg. Chem. 1972, 11, 8, 1734–1738Publication Date (Pri…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMass spectrometric study of the vaporization of cuprous iodideT. E. Joyce and E. J. RolinskiCite this: J. Phys. Chem. 1972, 76, 16, 2310–2316Publication Date (Print):August 1, 1972Publication History Published online1 May 2002Published inissue 1 August 1972https://doi.org/10…
Contact angles have been measured using water drops of specified sizes, and in equilibrium with their vapor only, at their boiling point when residing on a copper surface at pressures ranging from 50–760 Torr.No appreciable change of contact angle with drop diameter was evident for sizes of 0.5 cm or more, but below t…
Certain samples of essential oils from Myoporum deserti , M. betcheanum , M. acuminatum , Eremophila maculata, and E. latrobei have been shown to contain myoporone and/or 10,ll-dehydromyoporone. The ambiguity regarding the stereochemistry of myoporone (previously known from M, bontioides) has been resolved,(-)-myoporo…