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ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTThermal AnalysisSergey VyazovkinView Author Information Department of Chemistry, University of Alabama at Birmingham, 901 South 14th Street, Birmingham, Alabama 35294 Cite this: Anal. Chem. 2002, 74, 12, 2749–2762Publication Date (Web):April 19, 2002Publication History Publis…
Reaction of cobalt(II) salts with the thiosalicylate dianion under hydrothermal conditions yields green lamellar Co((O2C)(S)C6H4) which displays canted antiferromagnetism.
The volume dependent electronic structure of the spinel-type lithium manganese oxides ${\mathrm{Li}}_{x}{\mathrm{Mn}}_{2}{\mathrm{O}}_{4},$ $x=0,0.5,1,$ is studied ab initio by employing a full-potential electronic structure method. The electronic structure, total energies, open-circuit voltage, and magnetic moments w…
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.
A recent analytic expression for the $\ensuremath{\sigma}$ bond order of $\mathrm{sp}$-valent systems with open structures is generalized to close-packed structures. This requires the retention of both the four-member ring contribution and the second-order embedding-type terms which arise naturally within the tight-bi…
The structure of 2H CuScO 2 has been refined from single-crystal X-ray diffraction data obtained at room temperature and from neutron powder diffraction data obtained from 11 to 1206 K. Strong negative thermal expansion (−4.0 × 10 - 6 /K) has been found for the apparent Cu−O bond length below 300 K. This is the first…
Telechelic high molecular weight polystyrene (PS-A) and poly(methyl methacrylate) (PMMA-A) containing anthracene end groups undergo end-coupling reaction in THF solution to form [4 + 4] anthracene photodimers upon exposure to UV irradiation at wavelengths greater than 300 nm. A mixture of products is obtained that inc…
The present paper explores the possibility of orienting columnar discotic liquid-crystalline (LC) materials and causing a uniaxial “in-plane” orientation of the columns along the orientation direction. The discotic LCs employed were based on 2-hydroxy-3,6,7,10,11-penta(1-butoxy)triphenylene, which was derivatized with…
A series of gold nanoclusters stabilized by ligands containing short ethylene oxide oligomers of fixed length were prepared and characterized. The thiols CH 3 (OCH 2 CH 2 ) n SH (where n = 2, 3, and 4) were substituted onto the surface of 1.8-nm hexanethiol-capped gold clusters by a thiol-exchange reaction, and the re…
p-Quinone units incorporated into the central portion of rigid pi-systems linking either two porphyrin macrocycles or a porphyrin and a phenanthroline group have the potential to function as a chemically and electrochemically controllable switch, thus acting as a means of modulating electronic communication between th…
We present the first treatment of the refraction of physical electromagnetic waves in newly developed negative index media (NIM), also known as left-handed media (LHM). The NIM dispersion relation implies that group fronts refract positively even when phase fronts refract negatively. This difference results in rapidly…
The local structure of a solid-on-solid (SOS) interface in a two-dimensional kinetic Ising ferromagnet with single-spin-flip Glauber dynamics, which is driven far from equilibrium by an applied field, is studied by an analytic mean-field, nonlinear-response theory [P.A. Rikvold and M. Kolesik, J. Stat. Phys. 100, 377…
The spin-dependence of the interface resistance between ferromagnetic Fe and InAs is calculated from first-principles for specular and disordered (001) interfaces. Because of the symmetry mismatch in the minority-spin channel, the specular interface acts as an efficient spin filter with a transmitted current polarisat…
Various physical quantities were measured and analyzed for the Cu-substituted thermoelectric oxide ${\mathrm{NaCo}}_{2\ensuremath{-}x}{\mathrm{Cu}}_{x}{\mathrm{O}}_{4}.$ As was previously known, the substituted Cu enhances the thermoelectric power, while it does not increase the resistivity significantly. The suscepti…
The transition metal ions doped with TiO2 films are of magnetic properties at room temperatures and have stimulated many scientists to study other properties. The Co-TiO2 sandwich composite films have been recently grown on glass and silicon substrates by using alternately radio frequency reactive and direct current m…
We analyze the reflection and transmission coefficients calculated from transfer matrix simulations on finite lengths of electromagnetic metamaterials, to determine the effective permittivity (\ensuremath{\varepsilon}) and permeability (\ensuremath{\mu}). We perform this analysis on structures composed of periodic arr…
Polycrystalline BaTiO 3 /SrTiO 3 (BT/ST) multilayer thin films were fabricated via pulsed-laser deposition onto Pt/Ti/SiO 2 /Si substrates. The dielectric constant of the multilayer films was obviously enhanced and the dielectric loss was almost the same as that of the pure BaTiO 3 and SrTiO 3 thin films. A dielectric…
Boltron H30 is a polyester polyol with a dendritic structure, developed by Perstop Corp. Complete methacrylated H30 oligomers were obtained by using three different reaction routes, i.e., treatment of H30 with methacrylic anhydride, methacryloyl chloride and 2-isocyanatoethyl methacrylate (IEM). The viscosities of the…
Results of local spin-density approximation (LSDA) and LSDA + U calculations of the electronic structure and magnetic configurations of the 50% hole-doped pseudocubic perovskite La 0.5 Sr 0.5 MnO 3 and double-layered LaSr 2 Mn 2 O 7 are presented. We demonstrate that the on-site Coulomb correlation ( U ) of Mn d elect…
The synthesis, photophysical, and photochemical properties of a series of stable bacteriochlorins containing a fused six-member anhydride or an imide ring are discussed. The Q y band (a 1u → e gx transition) in the near-infrared region (NIR) lies between 788 and 831 nm depending upon the macrocycle substituents. Compo…