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Matrix elements of general configuration of nonorthogonalized orbitals in state with definite spin

Ilya G. Kaplan、О. Б. Родимова1973-11-01International Journal of Quantum Chemistry

Abstract The expressions for matrix elements of spin‐independent operators F and G with the use of Young operators are obtained in the case of arbitrary nonorthogonalized orbital configuration, including both singly and doubly filled orbitals and corresponding to the definite value of total spin. The formulas obtained…

Advanced Chemical Physics StudiesCrystal Structures and PropertiesNonlinear Optical Materials Research

Immunosuppression Produced by Lead, Cadmium, and Mercury

Loren D. Koller1973-11-01American Journal of Veterinary Research

SUMMARY Rabbits given lead acetate, cadmium chloride, or mercuric chloride in their drinking water for 70 days and then inoculated with pseudorabies virus (3 doses, 7 days between doses) as antigen had significantly lower neutralizing antibody titers than did the controls. The titers were determined by the plaque assa…

Nanoparticles: synthesis and applicationsAdvanced biosensing and bioanalysis techniquesAdvanced Nanomaterials in Catalysis

Twinning in Cr-doped VO2

M. Marezio、P. D. Dernier、A. Santoro1973-11-01Acta Crystallographica Section A

Twinning has been studied in several samples of VO2 containing in substitution solid solution 0.5 and 2.5 at.% Cr. The twinning is by reticular pseudo-merohedry and it is controlled by the tetragonal pseudo-symmetry of a superlattice obtained from the original monoclinic cell (a ≃ 9.1, b ≃ 5.8, c ≃ 4.5 Å, β ≃ 90°) by…

Transition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation Reactions

Formation of a glass‐ionomer cement based on an lon‐leachable glass and polyacrylic acid

Stephen Crisp、Alan D. Wilson1973-11-01Journal of Applied Chemistry and Biotechnology

Abstract The chemistry of the cement‐forming reaction between a fluorine‐containing calcium aluminosilicate glass and aqueous solutions of poly(acrylic acid) has been studied using infrared spectroscopy and classical chemical procedures. It was concluded that calcium, aluminium and fluoride ions were leached from the…

Concrete and Cement Materials ResearchGlass properties and applicationsBuilding materials and conservation

Spin translation groups and neutron diffraction analysis

Д. Б. Литвин1973-11-01Acta Crystallographica Section A

Groups that are a generalization of magnetic groups, and called 'spin groups', are defined. Among the spin groups those called 'spin translation groups' are tabulated and described in some detail. The possible magnetic reflexions of unpolarized neutrons elastically scattered from a single crystal whose spin arrangemen…

Solid-state spectroscopy and crystallographyNuclear Physics and ApplicationsInorganic Fluorides and Related Compounds

Experiments and void correlation for PWR small-break LOCA conditions

J.P. Cunningham、Hsu‐Chieh Yeh1973-11-01Transactions of the American Nuclear Society

S>From joint meeting of the American Nuclear Society and the Atomic Industrial Forum and Nuclear Energy Exhibition; San Francisco, California, USA (11 Nov 1973). See CONF-731101-.

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

Hydroformylation of methyl oleate with a recycled rhodium catalyst and estimated costs for a batch process

J. P. Friedrich、G. R. List、V. E. Sohns1973-11-01Journal of the American Oil Chemists Society

Abstract Methyl oleate was hydroformylated to methyl formylstearate at 120 C and 850–900 psig with a 1:1 mol mixture of hydrogen and carbon monoxide. In the presence of triphenylphosphite, an activated rhodium‐on‐alumina catalyst produced an essentially quantitative conversion in about 40 min. Filtration followed by d…

biodegradable polymer synthesis and properties

Über Erdalkalimetalloxogallate. V. Die Kristallstruktur von monoklinem CaGa2O4

H. J. Deiseroth、H. K. Müller‐Buschbaum1973-11-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Von der monoklinen Modifikation der Verbindung CaGa 2 O 4 wurden Einkristalle dargestellt und ihre Kristallstruktur mit Diffraktometer‐Röntgendaten bestimmt; a = 7,992, b = 8,830, c = 10,585 Å, β = 94,72°, Raumgruppe C —P2 1 /C. Ebenso wie die orthorhombische stellt auch die monokline Modifikation einen weite…

Layered Double Hydroxides Synthesis and ApplicationsMicrowave Dielectric Ceramics SynthesisInorganic Chemistry and Materials

The Pathway of Exogenous and Endogenous Carbohydrate Utilization in Escherichia coli: A Dual Function for the Enzymes of the Maltose Operon

T. Norman Palmer、Günter Wöber、William J. Whelan1973-11-01European Journal of Biochemistry

The components of the maltose‐utilizing system in Escherichia coli ML, i.e. maltose permease, amylomaltase and maltodextrin phosphorylase, were re‐investigated, with the following findings: The concentrating mechanism (permease) is the rate‐limiting step in the maltose‐utilizing system. Maltose and higher maltodextrin…

Probiotics and Fermented FoodsEnzyme Structure and FunctionEnzyme Production and Characterization

Stress Corrosion Cracking of Iron and Nickel Base Alloys in Sulfate Solutions at 289 C

David A. Vermilyea1973-11-01CORROSION

Stress corrosion cracking (SCC) of iron and nickel base alloys in aqueous solutions at 289 C (552 F) has been studied using a straining electrode apparatus. Cracking susceptibility decreases in the order sensitized stainless steel, cold worked stainless steel containing martensite, sensitized Inconel 600, annealed sta…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

The short-range structure of Ti and Zr b.c.c. solid solutions containing the ω phase. I. General diffraction theory and development of computational techniques

B. Borie、S.L. Sass、A. Andreassen1973-11-01Acta Crystallographica Section A

Certain Ti and Zr solid solutions containing the ω phase exhibit intensity distributions in reciprocal space which are partly diffuse. In an effort to understand the structural meaning of these diffraction patterns, we have developed new methods for the evaluation of the kinematic intensity sum for certain kinds of at…

Titanium Alloys Microstructure and PropertiesX-ray Diffraction in CrystallographyThermodynamic and Structural Properties of Metals and Alloys

Nature mineralogique et origine des glauconies du plateau continental du Gabon et du Congo

Pierre Giressè、G.S. Odin1973-11-01Sedimentology

RÉSUMÉ Sur le plateau continental du Congo et du Gabon, on constate la formation de goethite, de berthiérine et de glauconies (smectite et glauconite). La berthiérine caractérise un milieu deltaïque a sedimentation active; les glauconies se forment sur le plateau continental à plus grande profondeur (—50à—300m). Dans…

Clay minerals and soil interactionsIron oxide chemistry and applicationsGeological and Geophysical Studies Worldwide

Effect of Iron Oxide on the Sintering Kinetics of Al 2 O 3

Weidong Rao、IVAN B. CUTLER1973-11-01Journal of the American Ceramic Society

Alumina powders with varying iron oxide contents were prepared by coprecipitation. The powders were spheroidized by passing them through an oxygen‐acetylene flame. The spheres were sized, annealed, and sintered in air and in N 2 with 132 ppm O 2 . Isothermal studies were combined with constant‐rate‐of‐heating studies…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesRecycling and utilization of industrial and municipal waste in materials production

Determination of atomic stress distribution in stressed polymers by infrared spectroscopy

V. I. Vettegren、Igor Novák1973-11-01Journal of Polymer Science Polymer Physics Edition

Abstract An attempt was made to evaluate stresses on chemical bonds in axially stressed polymers from the shift of skeletal vibration frequencies in chain molecules. The maximum stress on chemical bonds was found to be at least ten times the average stress on the specimen.

Thermal and Kinetic AnalysisMaterial Properties and ApplicationsPolymer Science and Applications

Ferroelectric Domain Structure of Tri-Glycine Sulfate Observed Using a Scanning Electron Microscope

N. Nakatani1973-11-01Japanese Journal of Applied Physics

Domain structures in the (010) plane are investigated in the secondary electron mode of S.E.M. The long axis of typical lenticular domains in crystals as grown is along the direction nearly perpendicular to the crystallographic c -axis. Fine lamellar structures appearing in annealed crystals are also along the same di…

Nonlinear Optical Materials ResearchAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Laser action from Ho<sup>3+</sup>, Er<sup>3+</sup>, and Tm<sup>3+</sup>in YAlO<inf>3</inf>

William J. Weber、Michael Bass、T. E. Varitimos 等 4 位作者1973-11-01IEEE Journal of Quantum Electronics

Laser action has been observed for the following rare-earth ions in YAlO3:Ho3+(sensitized with Er3+and Tm3+), Er3+, and Tm3+(sensitized with Er3+) at wavelengths of 2.123, 0.851, and 1.861 μm, respectively. Measurements of spectroscopic properties, fluorescence kinetics, and laser performance of these ions in YAlO3are…

Luminescence Properties of Advanced MaterialsSpectroscopy and Laser ApplicationsSolid State Laser Technologies

Transient behavior of the electrically controlled birefringence in a nematic liquid crystal

G. Labrunie、J. Robert1973-11-01Journal of Applied Physics

An homeotropic cell is built with a thin layer (5–25 μm) of nematic liquid crystal such as MBBA sandwiched between two indium oxide coated glass plates. The transient behavior of the cooperative angular variation of molecules submitted to an electric field step is studied theoretically. Experimental results are obtain…

Liquid Crystal Research AdvancementsSpectroscopy and Quantum Chemical StudiesMolecular spectroscopy and chirality

Aging and degradation of polyolefins. I. Peroxide‐initiated oxidations of atactic polypropylene

Etsuo Niki、Christian Decker、Frank R. Mayo1973-11-01Journal of Polymer Science Polymer Chemistry Edition

Abstract Efficiencies of polymer radical production by thermal decomposition of di‐ tert ‐butylperoxy oxalate (DBPO) have been measured in bulk atactic polypropylene (PP) at 25–55°C; they range from 1 to 26%, depending on [DBPO], temperature, and presence of oxygen. Most of the polymer radicals thus produced dispropor…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Auger electron spectroscopy

J C Rivière1973-11-01Contemporary Physics

Auger spectroscopy has progressed from its initial use as a purely research tool to that of an analytical technique of general application wherever information about the composition of non-volatile surfaces is important. This, article describes the underlying physics of the Auger process and the instrumentation involv…

Corrosion Behavior and InhibitionForce Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Cambridge Crystallographic Data Centre. IV. Preparation of "Interatomic Distances 1960-65"

Frank H. Allen、Neil W. Isaacs、Olga Kennard 等 7 位作者1973-11-01Journal of Chemical Documentation

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCambridge Crystallographic Data Centre. IV. Preparation of "Interatomic Distances 1960-65"F. H. Allen, N. W. Isaacs, Olga. Kennard, W. D. S. Motherwell, R. C. Petterson, W. G. Town, and D. G. WatsonCite this: J. Chem. Doc. 1973, 13, 4, 211–218Publication Date (Print):Novembe…

Crystallization and Solubility StudiesMolecular spectroscopy and chiralityHistory and advancements in chemistry