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Crystal Structures for the Electron Donor Dibenzotetrathiafulavalene, DBTTF, and Its Mixed-stack Charge-transfer Salts with the Electron Acceptors 7,7,8,8-tetracyano-p-quinodimethane, TCNQ, and 2,5-difluoro-7,7,8,8-tetracyano-p-quinodimethane, 2,5-TCNQF2

Thomas J. Emge、F. Mitchell Wiygul、J.S. Chappell 等 7 位作者1982-01-01Molecular crystals and liquid crystals

Crystal structures for the electron donor DBTTF and its charge-transfer salts with the acceptors TCNQ and 2,5-TCNQF2 are reported. Crystal data for the three systems are as follows: (a) neutral DBTTF; monoclinic, space group P21/c, a=12.082(2) Å, b=3.955(1) Å, c=14.553(2) Å, β=114.36(1)0, V=633.6 Å3; (b) DBTTF-TCNQ; t…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Temporary anion states of phosphabenzene, arsabenzene, and stibabenzene. Trends in the .pi. and .pi.* orbital energies

P. D. Burrow、Arthur J. Ashe、Dennis J. Bellville 等 4 位作者1982-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemporary anion states of phosphabenzene, arsabenzene, and stibabenzene. Trends in the .pi. and .pi.* orbital energiesP. D. Burrow, A. J. Ashe III, D. J. Bellville, and K. D. JordanCite this: J. Am. Chem. Soc. 1982, 104, 2, 425–429Publication Date (Print):January 1, 1982Publ…

Advanced Chemical Physics StudiesSolid-state spectroscopy and crystallographyVarious Chemistry Research Topics

Properties of low molecular weight block copolymers. 1. Differential scanning calorimetry of styrene-dimethylsiloxane diblock copolymers

Sonja Krause、Magdy Iskandar、Mohammad Anwar Mohamed Iqbal1982-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of low molecular weight block copolymers. 1. Differential scanning calorimetry of styrene-dimethylsiloxane diblock copolymersSonja Krause, Magdy Iskandar, and Mohammad IqbalCite this: Macromolecules 1982, 15, 1, 105–111Publication Date (Print):January 1, 1982Publi…

Advanced Polymer Synthesis and CharacterizationSynthesis and properties of polymersSilicone and Siloxane Chemistry

Mechanisms for the photooxidation of protoporphyrin IX in solution

Graham Cox、David G. Whitten1982-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanisms for the photooxidation of protoporphyrin IX in solutionG. Sidney Cox and David G. WhittenCite this: J. Am. Chem. Soc. 1982, 104, 2, 516–521Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1 January 1982https:/…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Dimeric copper( II ) compounds with a tripodal imidazole-containing ligand and bridged by imidazolate, benzimidazolate, and benzotriazolate ions. Crystal and molecular structure of µ-(benzotriazolato-N 1 ,N 3 )bis{[tris(N 1 -methylbenzimidazol-2-ylmethyl)amine-N,N 3 ,N 3 ′,N 3 ″]copper( II )} trinitrate

H. M. J. Hendriks、P. J. M. W. L. BIRKER、G. C. Verschoor 等 4 位作者1982-01-01Journal of the Chemical Society Dalton Transactions

A series of dimeric copper(II) co-ordination compounds with general formula [Cu2(tmbma)2(azolate)]X3 has been prepared and characterized, where tmbma is the tripodal benzimidazole-containing ligand tris(N-methylbenzimidazol-2-ylmethyl)amine, azolate is the anion of imidazole, benzimidazole, or benzotriazole, and X = N…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Tobelite, a new ammonium dioctahedral mica.

Shoji Higashi1982-01-01Mineralogical Journal

Mineralogical properties of tobelite, a new ammonium-dominant dioctahedral mica, found in the Ohgidani pottery stone deposit at Tobe, Ehime Prefecture, Japan, are described.This mineral, accompanied by quartz, occurs as a hydrothermal alteration product of a biotite andesite dyke. Wet chemical analysis gives a structu…

Glass properties and applicationsCrystal Structures and PropertiesClay minerals and soil interactions

Phase Transitions and Ferroelectricity in {N(CH3)4}2XBr4 (X: Zn, Co, Cu)

K. Gesi1982-01-01Journal of the Physical Society of Japan

The phase transitions in {N(CH 3 ) 4 } 2 XBr 4 (X: Zn, Co, Cu) were stuided by dielectric measurements. A phase transition which accompanied with a break on the dielectric constant vs temperature curve was found at 13.5°C and 13.8°C for {N(CH 3 ) 4 } 2 ZnBr 4 and {N(CH 3 ) 4 } 2 CoBr 4 , respectively. In {N(CH 3 ) 4 }…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Trois phénomènes rentrants dans un produit pur mésogène

Nguyen Huu Tinh、F. Hardouin、C. Destrade1982-01-01Journal de physique

Nous présentons une nouvelle et remarquable séquence mésomorphe dans un produit pur : le 4-nitrobenzoyloxybenzoate de 4-nonyloxyphényle à la pression atmosphérique : K(SC2)S ?SA1NreSAd reNreSAd NI. Cette séquence comporte deux phases nématiques rentrantes (phénomène jamais observé à ce jour) et une phase smectique SAd…

Liquid Crystal Research AdvancementsThermodynamic properties of mixturesNonlinear Dynamics and Pattern Formation

Titanium and titanium alloys : scientific and technological aspects

J. C. Williams、A. F. Belov1982-01-01Plenum Press eBooks

Decomposition of the Martensite in Two-Phase Titanium Alloys.- The Investigation of the Titanium Structure after Shock Wave Loading.- Embrittlement and Spontaneous Cracking of a Hardened (?+?) Titanium Alloy during Aging.- Transformation in Unstable Beta-Titanium Alloys.- Internal Friction Studies in Stable and Metast…

Intermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and PropertiesMetal Alloys Wear and Properties

Electrical conductivity of synthetic and natural quartz crystals

Himanshu Jain、A. S. Nowick1982-01-01Journal of Applied Physics

Electrical conductivity of α quartz is ionic, the current being carried by alkali ions (M+) moving in channels parallel to the c axis. A study was made of conductivity σ of one natural and three synthetic crystals in order to better understand these ionic defects. ac measurements were made over a wide range of frequen…

Glass properties and applicationsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Dynamics of highly entangled rod-like molecules

S. F. Edwards、K. E. Evans1982-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

The diffusion of rod-like molecules is studied in the case of high density. It is argued that when one goes to densities higher than those permitting rotational freedom for the rods, the diffusion of one rod will depend critically upon the cooperation of the others. A calculation of this effect using mean-field theory…

Material Dynamics and PropertiesQuantum Mechanics and ApplicationsAdvanced Thermodynamics and Statistical Mechanics

Isotactic polymerization of .alpha.-olefins: stereoregulation for different reactive chain ends

Adolfo Zambelli、Maria Carmela Sacchi、Paolo Locatelli 等 4 位作者1982-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIsotactic polymerization of .alpha.-olefins: stereoregulation for different reactive chain endsA. Zambelli, M. C. Sacchi, P. Locatelli, and G. ZannoniCite this: Macromolecules 1982, 15, 1, 211–212Publication Date (Print):January 1, 1982Publication History Published online1 M…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Étude des propriétés cristallochimiques, morphologiques, superficielles de kaolinites désordonnées

Jean‐Maurice Cases、Olivier Liétard、Jacques Yvon 等 4 位作者1982-01-01Bulletin de Minéralogie

Trente échantillons d'argiles kaoliniques provenant de Cornouailles anglaise et française, de Géorgie, des Charentes, ont été étudiés par analyses chimique, cristallographique, spectroscopique (I.R.), granulométrique, thermique différentielle et mesures des surfaces spécifiques. Le fer, sous forme d'oxydes ou hydroxyd…

Clay minerals and soil interactionsIron oxide chemistry and applicationsGeochemistry and Geologic Mapping

L-Aspartate oxidase, a newly discovered enzyme of Escherichia coli, is the B protein of quinolinate synthetase.

Satoshi Nasu、Frank D. Wicks、R.K. Gholson1982-01-01Journal of Biological Chemistry

In Escherichia coli, quinolinic acid, a precursor of NAD+, is synthesized from L-aspartate and dihydroxyacetone phosphate. This synthesis requires two enzymes, a FAD-containing "B protein" and an "A protein." The B protein has been purified 500-fold from E. coli cells. The enzyme behaves as an L-aspartate oxidase. In…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Infrared study of hydrogen adsorption on MgO, CaO and SrO. Possible mechanism in promoting O–2 formation

Salvatore Coluccia、F. Boccuzzi、G. Ghiotti 等 4 位作者1982-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Hydrogen adsorption on high-surface-area alkaline-earth oxides has been studied by i.r. spectroscopy at 300 and 78 K. In the former case heterolytic dissociation of H2 molecules produces hydride and hydroxy groups which are partially reversible upon evacuation. Low-temperature hydrogen adsorption appears to be undisso…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsQuantum, superfluid, helium dynamics

Analytical selection of ideal epitaxial configurations and some speculations on the occurrence of epitaxy I. Epitaxy with rectangular interfacial atomic meshes

Jan H. van der Merwe1982-01-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

This investigation has been aimed at a better understanding of epitaxy; particularly, but not exclusively, in monolayers. The description has been facilitated by the introduction of a configuration space γ, spanned by the parameters relevant to epitaxy, namely, lattice parameters, misorientation, bonding, etc. The rig…

Microstructure and mechanical propertiesSurface and Thin Film PhenomenaMetallurgical and Alloy Processes

Composite Materials: Testing and Design (6th Conference)

IM Daniel1982-01-01OpenAlex

Description This publication presents the latest developments in composites testing and design, including applications to the aircraft, automotive, and other industries. 31 papers comprise the contents and address subjects including test methods for mechanical and damage characterization; new types of composites, such…

Material Properties and Applications

Neutron diffraction studies of Nd2(CoxFe1−x)17 alloys: Preferential site occupation and magnetic structure

J. F. Herbst、J. J. Croat、R. W. Lee 等 4 位作者1982-01-01Journal of Applied Physics

Rietveld analyses of room-temperature neutron powder diffraction data for seven Nd2(CoxFe1−x)17 alloys (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) are reported. In the ternary systems we find that the c-type transition metal sites are preferentially occupied by Fe ions; concomitantly, the d and h sites have Co occupations lar…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

X-Ray Diffuse Scattering Study of Some (TMTSF)2X and (TMTTF)2X Salts

Jean‐Paul Pouget、R. Moret、R. Comès 等 6 位作者1982-01-01Molecular crystals and liquid crystals

X-ray diffuse scattering experiments on the superconducting salts (TMTSF)2X with X = PF6, AsF6 and ClO4 reveal no charge density wave instability, in contrast with the poorly conducting (TMTTF)2PF6 salt. New structural phase transitions coinciding with conductivity anomalies are found in (TMTSF)2NO3, (TMTSF)2ReO4, and…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Observation of a magnetic state in the organic superconductor (TMTSF) 2ClO4 : influence of the cooling rate

Tomoya Takahashi、D. Jérôme、K. Bechgaard1982-01-01Journal de Physique Lettres

A magnetic state is observed below ∼ 3.5 K in the organic superconductor (TMTSF)2ClO4 just above the superconducting transition (Tc ∼ 1 K). This state is obtained by fast cooling with a rate of ∼ 25 K/min. and evidenced by 77Se and 1H-NMR intensity and relaxation measurements. The onset temperature is nearly field-ind…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research