Materials Literature
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Abstract Bismaleimide polymers offer a thermostability that fills in the gap between epoxies and high temperature polyimides. Bismaleimides of the new generation overcome traditional problems of brittleness and difficult processing. The property transpositions from these tougher, hot‐melt processable resins to the cor…
Abstract The venting and control strategies of a Magnesium Grignard formation reaction were assessed by theoretical predictions of the exotherm and the reaction rate, by simple laboratory measurements of the self heat rate, and by Leung's simplified equations and SAFIRE evaluations, based on DIERS methods. SAFIRE comp…
Abstract A viscous traction interfacial viscometer was constructed to study a mineral oil‐water‐emulsifier system. The effect on interfacial viscosity of the synthetic emulsifiers Span 80 and Pluronic L42 were investigated, along with the bioemulsifier produced by the yeast Torulopsis petrophilum. In the case of the s…
We report a high-resolution x-ray scattering study of the nematic--smectic-A transition around the tricritical point in mixtures of heptyloxypentylphenylthiobenzoate and octyloxycyanobiphenyl. Unusually large susceptibility and correlation length critical exponents are observed; this is explained as a clear example of…
The chirality-induced biaxiality is measured at the uniaxial-to-biaxial cholesteric phase transition of the lyotropic system including potassium laurate, decanol, ${\mathrm{H}}_{2}$O, and some chiral agent. The measurement of an induced biaxiality in a cholesteric uniaxial liquid crystal is reported. The corresponding…
The aecA and aecB loci map at 250 and 290 degrees, respectively, on the Bacillus subtilis chromosomal genetic map. The aecB locus has been proposed as the structural gene for aspartokinase II. From DNA sequence analyses and comparisons to the sequence of the aspartokinase II gene, it can be concluded that the structur…
Abstract Barbituric acid derivatives with electron donors at 5-position were synthesized and their second order nonlinear optical properties were investigated by electric field induced second harmonic generation (EFISH) method. It was found that barbituric acid units were strong acceptors and contributed to the large…
Abstract The mechanisms of palygorskite and sepiolite alteration to smectite under mild hydrothermal conditions were investigated by solid-state 27 Al and 29 Si magic-angle spinning-nuclear magnetic resonance (MAS-NMR) spectroscopy, X-ray powder diffraction (XRD) and transmission electron microscopy (TEM). Palygorskit…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and x-ray structure of (tetramethyldibenzotetraaza[14]annulene)chromium dimer [(tmtaa)Cr]2. A multiply bonded complex of dichromium(II) without bridging ligandsJilles J. H. Edema, Sandro Gambarotta, Paul Van der Sluis, Wilberth J. J. Smeets, and Anthony L. SpekCi…
Abstract A homopolymer of L ‐lactic acid (LA), which was synthesized by direct polycondensation in the absence of a catalyst at 200°C, is crystalline, in contrast to the homopolymer of D , L ‐mandelic acid (MA) which is amorphous. Poly(LA‐ co ‐MA), obtained under the above conditions, is amorphous over a wide range of…
High-temperature deformation of A1-1 wt.% wg-1 wt. % Mn has been carried out in plane-strain compression at constant strain rate and temperature, and with abrupt changes in Zener-Hollomon parameter. Subgrain sizes and dislocation densities within subgrains have been measured and correlated with the roomtemperature pro…
The relationship between electronic polarizability of oxide(—II), α O 2− , and the electron donor power, expressed as the optical basicity, ∧, indicates that ∧(TiO 2 ) is much greater than ∧(SiO 2 ) and is approximately the same as ∧(CaO). Such a high basicity is supported by the trend in the Racah B parameter for the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPredicting the densest packings of ternary and quaternary mixtures of solid particlesNorio Ouchiyama and Tatsuo TanakaCite this: Ind. Eng. Chem. Res. 1989, 28, 10, 1530–1536Publication Date (Print):October 1, 1989Publication History Published online1 May 2002Published inissu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTechnetium bis(.mu.-oxo) dimers of 1,4,7-triazacyclonane-N,N',N''-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(.mu.-O)2Tc(TCTA)]n- (n = 2, 3) and the crystal structure of Ba2[(TCTA)Tc(.mu.-O)2Tc(TCTA)](ClO4).9H2OKaren E. Linder, John C. Dewan, and Alan Davi…
ABSTRACT In the Deer Lake Basin of western Newfoundland, Canada, analcime has been found within fine‐grained, siliciclastic and carbonate, lake and lake‐margin sediments of the Carboniferous Rocky Brook Formation. Analcime is the only zeolite observed in these unmetamorphosed and non‐volcanogenic rocks. Microscopic an…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and photoactivity of chemically asymmetric polymeric porphyrin films made by interfacial polymerizationCarl C. Wamser, Raymond R. Bard, Velu Senthilathipan, Valerie C. Anderson, James A. Yates, Harold K. Lonsdale, George W. Rayfield, Dwayne T. Friesen, Douglas A. L…
Abstract Poly[ N , N ′‐(sulfo‐phenylene)phthalamid]es and poly[ N , N ′‐(sulfo‐ p ‐phenylene)pyromellitimide] were prepared in water‐soluble form and were found to have unique solution properties, similar in some respects to xanthan. The polymer most investigated, poly[ N , N ′‐(sulfo‐ p ‐phenylene)terephthalamide] (P…
We study the transition between the twisted and untwisted states of a cholesteric liquid crystal bounded between two plates and constrained to have homeotropic anchoring at the plate surfaces. Previous theories predict that the twisted-untwisted transition should be second order, while experiments show that it is firs…
In this work the value methods of deposit caused by reversible movement of domain and interphase boundaries (boundaries between the tetragonal and rhombohedral phases) into piezomoduli is proposed. Ceramics on the basis of (Ba, Ca)TiO3 (TBK) and Pb(Zr, Ti)O3 (ZTS) were estimated. In some materials piezoeffect is cause…
The genus of a three-periodic intersection-free surface in R3 refers to a primitive unit cell of its symmetry group. Two procedures for the calculation of the genus are described: (1) by means of labyrinth graphs; (2) via the Euler characteristic derived from a tiling on the surface. In both cases new formulae based o…