Materials Literature
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We report results of 75As nuclear magnetic resonance (NMR) experiments on a self-flux grown high-quality single crystal of SrFe2As2. The NMR spectra clearly show sharp first-order antiferromagnetic (AF) and structural transitions occurring simultaneously. The behavior in the vicinity of the transition is compared with…
Agglomerated amino‐modified silica nanoparticles were prepared from a novel Stöber‐like precursor system consisting of aminopropyltriethoxysilane (APTES), tetraethoxysilane (TEOS), ethanol, and water where the molar ratio APTES/TEOS was 0, 0.1, 1.0, and 2.0, and the molar ratio H 2 O/‐SiOC 2 H 5 was about 20 to 60, or…
This review covers sonochemical fabrication of polymer nanocomposites. In addition to its application to the synthesis of various polymeric systems, due to its powerful efficiency, sonochemistry has been widely used not only as the assistant of dispersion for nanomaterials such as carbon nanotubes (CNT) and organophil…
High-pressure resistivity experiments were performed on FeSe 0.5 Te 0.5 . The onset temperature of T c ( T c onset ) increases rapidly from 13.5 to 26.2 K upon applying pressure up to 2 GPa. Above 2 GPa, T c decreases linearly and the metallic phase was observed at P =14 GPa. The same relationship between normalized T…
We report resistivity measurements performed on KFe$_2$As$_2$ single crystals down to $T$ = 0.3 K and in magnetic fields up to 17.5 T. The in-plane resistivity vs. $T$ curve has a convex shape down to $\sim$50 K and shows a $T^2$ dependence below $\sim$45 K. The ratio of the c-axis to in-plane resistivities is $\sim$1…
The role of the exchange-correlation density functional (PBE, PW91, RevPBE) and of surface relaxation in the determination of the adsorption energies, reaction energy barriers, and reaction rate constants has been analyzed taking water dissociation on Cu(111) surface as a test case. The PBE and PW91 functionals yield…
Dissociation constants and corresponding pK(a) values of five drugs were obtained with the Bates-Schwarzenbach method using a Perkin-Elmer Lambda 35 UV/vis spectrophotometer at temperature 298.15 K in the buffer solutions. Atropine, promethazine hydrochloride, ibuprofen, flurbiprofen, and meclofenamic acid sodium salt…
Abstract The development of an eco‐friendly and reliable process for the synthesis of gold nanomaterials using microorganisms is gaining importance in the field of nanotechnology. In the present study, gold nanoparticles have been synthesized by reduction of aqueous gold ions using the culture supernatant of Aspergill…
Current method to magnetically label cells using ferumoxides (Fe)-protamine (Pro) sulfate (FePro) is based on generating FePro complexes in a serum free media that are then incubated overnight with cells for the efficient labeling. However, this labeling technique requires long (>12-16 hours) incubation time and uses…
Simulations based on the discrete element method (DEM) are used to investigate the relationship between the distribution of particle sizes and the macroscopic sintering behavior of ceramic powders. This is achieved by generalizing the DEM force laws for solid‐state sintering in such a way that sintering of particles w…
Hydroxyapatite (HAp) nanoparticle-coated micrometer-sized poly(l-lactic acid) (PLLA) microspheres were fabricated via a "Pickering-type" emulsion route in the absence of any molecular surfactants. Stable oil-in-water emulsions were prepared using 40 nm HAp nanoparticles as a particulate emulsifier and a dichloromethan…
In the context of revealing interfacial effects on ion conduction, thin films are extremely worthwhile due to defined geometry. Of particular interest are heterostructures as they offer symmetric boundary conditions and a high density of hetero-interfaces. The recent progress in this field is reviewed. Materials class…
Responsive magnetic resonance imaging (MRI) contrast agents can change MR image contrast in response to a molecular biomarker. Quantitative detection of the biomarker requires an accounting of the other effects that may alter MR image contrast, such as a change in the agent's concentration, magnetic field variations,…
Whispering Gallery modes in bulk cylindrical Gallium Arsenide and Gallium Phosphide samples have been examined both in darkness and under white light at 50 K. In both samples we observed change in permittivity under light and dark conditions. This results from a change in the polarization state of the semiconductor, w…
We report fabrication of transistors in a FinFET geometry using isotopically purified silicon-28 -on-insulator (28-SOI) substrates. Donor electron spin coherence in natural silicon is limited by spectral diffusion due to the residual $^{29}$Si nuclear spin bath, making isotopically enriched nuclear spin-free $^{28}$Si…
We present a combined study of the electronic structure of the superconducting skutterudite derivative SrPt4Ge12 by means of X-ray photoelectron spectroscopy and full potential band structure calculations including an analysis of the chemical bonding. We establish that the states at the Fermi level originate predomina…
We report lattice-dynamical measurements, made using neutron inelastic-scattering methods, of the relaxor perovskite ${\text{PbMg}}_{1/3}{\text{Nb}}_{2/3}{\text{O}}_{3}$ (PMN) at momentum transfers near the edge of the Brillouin zone. Unusual ``columns'' of phonon scattering that are localized in momentum, but extende…
An ultrafast quench is applied to binary mixtures of superparamagnetic colloidal particles confined at a two-dimensional water-air interface by a sudden increase of an external magnetic field. This quench realizes a virtually instantaneous cooling which is impossible in molecular systems. Using real-space experiments,…
We discuss the large gap anisotropy found for the ${A}_{1g}$ ($s$ wave) state in random-phase approximation spin fluctuation and functional renormalization-group calculations and show how the simple arguments leading to isotropic sign-switched $s$-wave states in these systems need to be supplemented by a consideration…
Construction of maximally localized Wannier functions (MLWFs) has been implemented within the linear combination of pseudoatomic orbital method. Detailed analysis using MLWFs is applied to three closely related materials, single benzene (Bz) molecule, organometallic vanadium-Bz infinite chain, and ${\text{V}}_{2}{\tex…