Materials Literature
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The positions of the metal ions in the spinel-type structures of compds. of the type MntFe3-tO4 in the region 0.25 <t <1.50 were detd. by the method of Skolnick, et al., (CA 52, 9750h) which employs the diffraction of x-rays of different wavelengths. After a single-phase spinel has been formed by solid-s…
Abstract The rate of isomerization during the polyesterification of maleic acid or maleic anhydride depends on the structure of the glycol used: the longer the chain of the glycol, the lower the isomerization rate. The rate constants differ greatly from one case to another. Thus, the difference in the reaction rate co…
Abstract The degradation of phenol–formaldehyde polycondensates has been investigated by mass spectrometric thermal analysis to 800°C. The thermal oxidative mechanism proposed by Conley and co‐workers has been confirmed. Direct analysis of products at frequent intervals of a temperature‐programmed heating cycle demons…
The influence of cell age, cell size, cell shape, and mode of colony formation on the sinking rates of Bacteriastrum hyalinum Lauder and Chaetoceros lauderi Ralfs was investigated in 18 experiments. The mean sinking rate of B. hyalinum ranged from 0.39 to 1.27 m/day; the absolute minimum and maximum rates were 0.24 an…
Isothermal annealing before or after irradiation is found to have a definite effect upon the thermoluminescent glow curve of LiF (TLD-100). Post-irradiation annealing, by thermally releasing electrons from their traps, reduces the size of each peak in the glow curve. The two main dosimetry peaks each have a simple exp…
X-ray diffraction measurements on anisotropic polycrystalline samples give a set of functions (pole-figures) describing the orientation distribution of individual plane-normals. From the set of these plane-normal distributions it is possible to deduce the orientation distribution of all crystallites in the sample (inv…
Abstract Many rigid PVC compounds show a sharp transition from tough to brittle fracture with decreasing temperature in impact testing, and this temperature becomes a criterion of compound quality in addition to the impact strength observed at specific temperatures. This BT (brittle fracture) has been investigated ind…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRates and Isomer Distributions for the Mercuration of the Monohalobenzenes in Trifluoroacetic Acid. Partial Rate Factors for the Mercuration Reaction1-3Herbert C. Brown and Robert A. WirkkalaCite this: J. Am. Chem. Soc. 1966, 88, 7, 1456–1458Publication Date (Print):April 1,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and Optical Properties of Bis(toluene-3,4-dithiolato)silicon(IV), -germanium(IV), -tin(IV), and -lead(IV)Frank Hall Fink, J. A. Turner, and Dwight A. Payne Jr.Cite this: J. Am. Chem. Soc. 1966, 88, 7, 1571–1572Publication Date (Print):April 1, 1966Publication Histo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolubilities of Disodium Terephthalate in Aqueous Solutions of Sodium Carbonate and Sodium Bicarbonate.J. L. Ellingboe and J. H. RunnelsCite this: J. Chem. Eng. Data 1966, 11, 2, 185–187Publication Date (Print):April 1, 1966Publication History Published online14 June 2008Pub…
The sorption isotherms of several fibres, of different types and structures, have been determined by a gravinietric method. The experiniental results obtained can be used in the confirmation of the equations of Hailwood and Horrobin, which were obtained by considering fibre–water systems as solutions of water in the d…
Abstract The polarized infrared spectra of isotactic polybutene-1 in a hexagonal form will be measured in the region from 4000 to 700 cm−1. The normal vibrations of this polymer, which takes a three-fold helical conformation, will be calculated by the use of the GF-matrix method, with the modified Urey-Bradley force f…
Detailed measurements of electrical conductivity (σ), Hall coefficient (R H ), and Seebeck coefficient (α) were made on seven bismuth telluride samples of composition Bi 2 Te 3+x , with x ranging from −0.06 to +0.48. Above room temperature the slope of R H T 3/2 gave an apparent energy gap about 50% higher than that f…
A general expression of the magnetic anisotropy energy and the magnetoelastic energy in the crystal of magnetic symmetry D 3 d is obtained. It is shown that, in NiO, the easy directions of magnetization will be either turnrightup.eps[1\bar10] or directions very close to turnrightup.eps[11\bar2] when the easy plane is…
The promotion of n ‐type electronic conduction by relatively small concentrations of donors in the presence of a large concentration of calcium, which is an acceptor, is explained by assuming that most of the calcium is present as neutral calcium ion‐oxygen vacancy pairs or clusters. Evaluation of experimental data on…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Molecular and Crystal Structure of Bis(1-phenyl-l,3-butanedionato)copperPing-Kay Hon, C. E. Pfluger, and R. Linn BelfordCite this: Inorg. Chem. 1966, 5, 4, 516–521Publication Date (Print):April 1, 1966Publication History Published online1 May 2002Published inissue 1 Apri…
The structure of post-irradiation annealed UO2 has been examined by transmission electron microscopy to try to understand the behavior and release of fission gas.At a dose of 2.2 × 1019 fissions/cm3, 5 × 1015 small gas bubbles/cm3 are observed in the material. These precipitate at 1100°C and appear to grow from 25 to…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Iron(III)-Catalyzed Oxidation of Cysteine by Molecular Oxygen in the Aqueous Phase. An Example of a Two-Thirds-Order ReactionJay E. Taylor, Johnson F. Yan, and Jin-liang WangCite this: J. Am. Chem. Soc. 1966, 88, 8, 1663–1667Publication Date (Print):April 1, 1966Publicat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Reactions of Metallocenes with Electron Acceptors1aR. L. Brandon, J. H. Osiecki, and A. OttenbergCite this: J. Org. Chem. 1966, 31, 4, 1214–1217Publication Date (Print):April 1, 1966Publication History Published online1 May 2002Published inissue 1 April 1966https://pubs.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMacro Rings. XXXI. Quinone Derived from [2.2]Paracyclophane, an Intramolecular—Molecular Complex1Donald J. Cram and A. Colin DayCite this: J. Org. Chem. 1966, 31, 4, 1227–1232Publication Date (Print):April 1, 1966Publication History Published online1 May 2002Published inissu…