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Novel electronic and magnetic properties in N or B doped silicene nanoribbons

Fu‐bao Zheng、Changwen Zhang、Shishen Yan 等 4 位作者2013-01-01Journal of Materials Chemistry C

Motivated by experimental developments on silicene nanosheets, we performed first-principles calculations to study the geometric, electronic and magnetic properties of pristine, N or B doped, as well as N and B co-doped silicene nanoribbons (SiNRs). It is shown that the substitution of N or B for Si is preferentially…

Graphene research and applicationsTopological Materials and PhenomenaSynthesis and Properties of Aromatic Compounds

Fe3O4–Au@mesoporous SiO2 microspheres: an ideal artificial enzymatic cascade system

Xiaolong He、Longfei Tan、Dong Chen 等 8 位作者2013-01-01Chemical Communications

An artificial enzymatic cascade system with high activity and stability is engineered based on Fe3O4-Au@mesoporous SiO2 (MS) microspheres, which possess both intrinsic glucose oxidase (GOx)- and peroxidase-mimic activities.

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

UV-shielding transparent PMMA/In2O3 nanocomposite films based on In2O3 nanoparticles

Anshu Singhal、K.A. Dubey、Y.K. Bhardwaj 等 6 位作者2013-01-01RSC Advances

Self supporting poly(methyl methacrylate) (PMMA)/In2O3 with varying In2O3 content (1, 2, 5 and 10 wt% In2O3 loading) nanocomposite films have been prepared by solvent-casting and spin casting techniques. The nanocomposite films have been structurally characterized by X-ray diffraction (XRD), and Fourier transform infr…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsPolymer Nanocomposite Synthesis and Irradiation

A tetraphenylethene-based chiral polymer: an AIE luminogen with high and tunable CPL dissymmetry factor

Xunhua Liu、Jiemin Jiao、Xiaoxiang Jiang 等 6 位作者2013-01-01Journal of Materials Chemistry C

A tetraphenylethene (TPE)-based chiral polymer (TPETyr) was synthesized by the polymerization of 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene (M-1) and 3′,5′-diiodo-N-α-tert-butoxycarbonyl-O-octyl-L-tyrosine methyl ester (M-2) via Sonogashira cross-coupling. Interestingly, the generated luminogen emits weak fluorescenc…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Using the Langmuir–Schaefer technique to fabricate large-area dense SERS-active Au nanoprism monolayer films

Yih Hong Lee、Choon Keong Lee、B.H. Tan 等 6 位作者2013-01-01Nanoscale

Interfacial self-assembly of nanoparticles is capable of creating large-area close-packed structures for a variety of applications. However, monolayers of hydrophilic cetyltrimethylammonium bromide (CTAB)-coated Au nanoparticles are challenging to assemble via interfacial self-assembly. This report presents a facile a…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Enhancement of Near Cloaking for the Full Maxwell Equations

Habib Ammari、Hyeonbae Kang、Hyundae Lee 等 5 位作者2013-01-01SIAM Journal on Applied Mathematics

Recently published methods for the quasi-static limit of the Helmholtz equation is extended to consider near cloaking for the full Maxwell equations. Effective near cloaking structures are described for the electromagnetic scattering problem at a fixed frequency. These structures are, prior to using the transformation…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Förster resonance energy transfer and carbon dots enhance light harvesting in a solid-state quantum dot solar cell

Remya Narayanan、Melepurath Deepa、Avanish Kumar Srivastava2013-01-01Journal of Materials Chemistry A

A novel yet inexpensive quantum dot solar cell (QDSC) configuration relying on Förster resonance energy transfer (FRET) from electrode bound excited cadmium sulfide (CdS) quantum dots ensconced in zinc sulfide (ZnS) monolayers to unattached copper phthalocyanine (CuPc) molecules, dissolved in a free standing sulfide i…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Rough contact is not always bad for interfacial energy coupling

Jingchao Zhang、Yongchun Wang、Xinwei Wang2013-01-01Nanoscale

For the first time we report that by introducing sub-nm roughness on a Si surface, the energy coupling between a single layer graphene (SLG) and the Si substrate can be improved substantially. This is contrary to the traditional view that a rough surface contact will weaken the energy coupling, rather than improve it.…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchThermal properties of materials

In situ polydopamine coating-directed synthesis of nitrogen-doped ordered nanoporous carbons with superior performance in supercapacitors

Yeru Liang、Hao Liu、Zhenghui Li 等 5 位作者2013-01-01Journal of Materials Chemistry A

A facile route to fabricate nitrogen-doped ordered nanoporous carbons (NONCs) was developed based on in situ polydopamine coating onto the pore surface of ordered nanoporous silica. The NONC exhibits very attractive capacitive properties, including unusually large capacitances up to 538 F g−1, highly efficient electro…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Thiolate-protected Ag32 clusters: mass spectral studies of composition and insights into the Ag–thiolate structure from NMR

T. Udayabhaskararao、Megalamane S. Bootharaju、Thalappil Pradeep2013-01-01Nanoscale

Clusters composed of a 32 silver atom core, protected with thiolates of glutathione (GSH) and N-(2-mercaptopropionyl)glycine (MPGH), were synthesized by a solid-state route in milligram scale. They do not exhibit surface plasmon resonance unlike their larger sized nanoparticle analogues but show molecule-like features…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

High-strength carbon nanotube buckypaper composites as applied to free-standing electrodes for supercapacitors

Jianfei Che、Peng Chen、Mary B. Chan‐Park2013-01-01Journal of Materials Chemistry A

Buckypaper is an attractive candidate material for free-standing electrodes in supercapacitors due to its high electrochemical performance, light weight, and thin dimensions. At present, however, free-standing buckypapers exhibit severe limitations in terms of product quality, especially mechanical properties, which h…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Bi-functional ZnO–RGO–Au substrate: photocatalysts for degrading pollutants and SERS substrates for real-time monitoring

Chunye Wen、Fan Liao、Shanshan Liu 等 7 位作者2013-01-01Chemical Communications

A ZnO-RGO-Au composite with bi-functional behavior was fabricated: it was employed both as a photocatalyst for degrading pollutants (Rhodamine 6G) and a SERS substrate for real-time monitoring of the degradation quantitatively.

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications

Self-assembly of natural and synthetic drug amphiphiles into discrete supramolecular nanostructures

Lye Lin Lock、Michelle LaComb、Kelly A. Schwarz 等 7 位作者2013-01-01Faraday Discussions

Molecular assembly provides an effective approach to construct discrete supramolecular nanostructures of various sizes and shapes in a simple manner. One important technological application of the resulting nanostructures is their potential use as anticancer drug carriers to facilitate targeted delivery to tumour site…

Supramolecular Chemistry and ComplexesRNA Interference and Gene DeliverySupramolecular Self-Assembly in Materials

Nanofibrous patterns by direct electrospinning of nanofibers onto topographically structured non-conductive substrates

Shifang Zhao、Qihui Zhou、Yun‐Ze Long 等 5 位作者2013-01-01Nanoscale

Patterning of electrospun nanofibers has recently attracted much attention for its usefulness in a wide range of applications. This paper reports on the generation of spatially defined nanofibrous patterns by direct deposition of electrospun nanofibers onto a variety of insulating substrates. It was found that topogra…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Toxicity Assessments of Near-infrared Upconversion Luminescent LaF3:Yb,Er in Early Development of Zebrafish Embryos

Kan Wang、Jiebing Ma、He Meng 等 9 位作者2013-01-01Theranostics

This study reports the effects of upconversion nanoparticles (UCNPs) LaF3:Yb,Er on zebrafish, with the aim of investigating UCNPs toxicity. LaF3:Yb,Er were prepared by an oleic acid/ionic liquid two-phase system, and characterized by transmission electron microscope and X-ray powder diffraction. 140 zebrafish embryos…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsbioluminescence and chemiluminescence research

Quantum dot/liquid crystal composite materials: self-assembly driven by liquid crystal phase transition templating

Andrea L. Rodarte、Ronald Pandolfi、Sayantani Ghosh 等 4 位作者2013-01-01Journal of Materials Chemistry C

The isotropic to nematic liquid crystal (LC) phase transition is used to create organized assemblies of CdSe/ZnS core/shell quantum dots (QDs). Under controlled conditions, well dispersed QDs are expelled from the ordered domains of nematic LC into the remaining isotropic domains. The final LC phase produces three dim…

Liquid Crystal Research AdvancementsQuantum Dots Synthesis And PropertiesPhotonic Crystals and Applications

Fragmentation of Chitosan by Acids

Mohammad Reza Kasaai、Joseph Arul、Gérard Charlet2013-01-01The Scientific World JOURNAL

Fragmentation of chitosan in aqueous solution by hydrochloric acid was investigated. The kinetics of fragmentation, the number of chain scissions, and polydispersity of the fragments were followed by viscometry and size exclusion chromatography. The chemical structure and the degree of N-acetylation (DA) of the origin…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolymer Surface Interaction Studies

Fabrication of superoleophobic surfaces on Al substrates

Jinlong Song、Shuai Huang、Ke Hu 等 6 位作者2013-01-01Journal of Materials Chemistry A

An easy method of fabricating superoleophobic surfaces on Al substrates by constructing reentrant structures is reported. The reentrant micro/nanometer-scale structures comprise micrometer-scale, rectangular-shaped, and step-like Al structures obtained by electrochemical etching and nanometer-scale Ag grains resulting…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Crystal structure and optical properties of white light-emitting Y2WO6:Sm3+ phosphor with excellent color rendering

Haijiao Qian、Junying Zhang、Luqiao Yin2013-01-01RSC Advances

A new single-phased white light-emitting phosphor, Y2WO6:Sm3+, was synthesized via conventional solid-state reaction calcining in air. The Y2WO6:Sm3+ samples were characterized using powder X-ray diffraction and refined with Rietveld methods. The phosphors exhibit a green emission from the host as well as a red emissi…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsPerovskite Materials and Applications