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An investigation into the fabrication and combustion performance of porous silicon nanoenergetic array chips

Shouxu Wang、Ruiqi Shen、Yinghua Ye 等 4 位作者2012-10-11Nanotechnology

An investigation into the ignitions and combustions of porous silicon (PS) nanoenergetic material array chips (nECs) at different ignition voltages was performed. The PS nECs were fabricated by integrating PS nanoenergetic material (nEMs) matrices and Cr-microbridges (microigniters) on the surface of silicon substrate…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchSilicon Nanostructures and Photoluminescence

Effect of Li-deficiency impurities on the electron-overdoped LiFeAs superconductor

Meng Wang、Miaoyin Wang、Hu Miao 等 14 位作者2012-10-11Physical Review B

We use transport, inelastic neutron scattering, and angle-resolved photoemission experiments to demonstrate that the stoichiometric LiFeAs is an intrinsically electron-overdoped superconductor similar to those of the electron-overdoped NaFe${}_{1\ensuremath{-}x}{T}_{x}$As and BaFe${}_{2\ensuremath{-}x}{T}_{x}$As${}_{2…

Corporate Taxation and AvoidanceIron-based superconductors research

Relationship between Dispersion and Conductivity of Polymer Nanocomposites: A Molecular Dynamics Study

Yancong Feng、Hua Zou、Nanying Ning 等 5 位作者2012-10-11The Journal of Physical Chemistry B

The dispersive and conductive properties of polymer nanocomposites are investigated simultaneously using the molecular dynamics simulation method. Four factors influencing the dispersion and conductivity are concerned, including polymer-nanoparticle interaction, nanoparticles with grafted chains, cross-linking of poly…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Optimization of Reductive Debenzylation of Hexabenzylhexaazaisowurtzitane (the Key Step for Synthesis of HNIW) Using Response Surface Methodology

Yadollah Bayat、Heshmat Ebrahimi、Farshad Fotouhi‐Far2012-10-11Organic Process Research & Development

Reductive debenzylation of hexabenzylhexaazaisowurtzitane (HBIW) was carried out using palladium hydroxide deposited on activated carbon catalyst. The catalyst has been characterized using a nitrogen adsorption/desorption isotherm, a hydrogen isotherm, scanning electron microscopy (SEM), and transmission electron micr…

Inorganic and Organometallic ChemistrySynthesis and properties of polymersThermal and Kinetic Analysis

Conductive Photoswitchable Vanadium Oxide Nanopaper based on Bacterial Cellulose

Junkal Gutierrez、Susana C. M. Fernandes、Iñaki Mondragòn 等 4 位作者2012-10-11ChemSusChem

A bacterial cellulose mat was used as a template for the fabrication of conductive photoswitchable hybrid nanopaper by the incorporation of sol-gel synthesized vanadium nanoparticles. The resulting nanopaper, prepared through a green pathway, was able to photoinduce a reversible color change. Conductive properties at…

TiO2 Photocatalysis and Solar CellsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Conversion of rod-shaped gold nanoparticles to spherical forms and their effect on biodistribution in tumor-bearing mice

Yasuyuki Akiyama、Takeshi Mori、Yoshiki Katayama 等 4 位作者2012-10-11Nanoscale Research Letters

Gold nanorods that have an absorption band in the near-infrared region and a photothermal effect have been used as nanodevices for near-infrared imaging and thermal therapy. Choice of the optimal shape of gold nanorods which relates optical properties and in vivo biodistribution is important for their applications. In…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

Advantages of paramagnetic chemical exchange saturation transfer (CEST) complexes having slow to intermediate water exchange properties as responsive MRI agents

Todd C. Soesbe、Yunkou Wu、A. Dean Sherry2012-10-11NMR in Biomedicine

Paramagnetic chemical exchange saturation transfer (PARACEST) complexes are exogenous contrast agents that have great potential to further extend the functional and molecular imaging capabilities of magnetic resonance. As a result of the presence of a central paramagnetic lanthanide ion (Ln(3+) ≠ La(3+) , Gd(3+) , Lu(…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Discrete Equilibrium Data from Dynamic Column Breakthrough Experiments

Reza Haghpanah、Arvind Rajendran、Shamsuzzaman Farooq 等 5 位作者2012-10-11Industrial & Engineering Chemistry Research

A new method for extracting discrete equilibrium data from a set of dynamic column breakthrough experiments is described. Instead of the classical approach where an isotherm model, i.e., a function, is used to describe the equilibrium, this approach represents the isotherm as a set of discrete points. For a given set…

Process Optimization and IntegrationProtein purification and stabilityCrystallization and Solubility Studies

Boosting the Emission Quantum Yield of Urea Cross‐Linked Tripodal Poly(oxypropylene)/Siloxane Hybrids Through the Variation of Catalyst Concentration

Vânia T. Freitas、Patrícia P. Lima、V. de Zea Bermudez 等 5 位作者2012-10-11European Journal of Inorganic Chemistry

Abstract Transparent monoliths of urea cross‐linked tripodal siloxane‐based hybrids, named tri‐ureasils, were prepared by the sol–gel process, using a wide concentration range of hydrochloric acid catalyst (1.0 × 10 –3 ≤ [HCl] ≤ 2.0 M ). The gelation time of the monoliths was controlled by varying the amount of water…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Computer simulation of dendronized polymers: organization and characterization at the atomistic level

Oscar Bertrán、Baozhong Zhang、A. Dieter Schlüter 等 6 位作者2012-10-11RSC Advances

Atomistic molecular dynamics simulations in chloroform and solvent-free environments are used to build and study a homologous series of neutral dendronized linear polymers (DPs), whose repeat units are regularly branched dendrons of generations g = 1–7, excluding g = 5. We find that a DP with g ≤ 4 displays an elongat…

Advanced Polymer Synthesis and CharacterizationChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

THE EFFECTS OF RATTAN FILLER LOADINGS ON PROPERTIES OF RATTAN POWDER-FILLED POLYPROPYLENE COMPOSITES

Shaari Balakrishna Nurshamila、Hanafi Ismail、Nadras Othman2012-10-11BioResources

This study investigates the effects of filler loading on the properties of rattan powder-filled polypropylene composites. The composites were prepared by incorporating rattan powder of average size 180 m into polypropylene matrix using a Polydrive Thermo Haake internal mixer. Filler loadings of the rattan powders rang…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

β-sheet propensity controls the kinetic pathways and morphologies of seeded peptide aggregation

Alex Morriss-Andrews、Giovanni Bellesia、Joan‐Emma Shea2012-10-11The Journal of Chemical Physics

The effect of seeds in templating the morphology of peptide aggregates is examined using molecular dynamics simulations and a coarse-grained peptide representation. Varying the nature of the aggregate seed between β-sheet, amorphous, and β-barrel seeds leads to different aggregation pathways and to morphologically dif…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsProtein Hydrolysis and Bioactive Peptides

Tuning the Adhesion of Silica Microparticles to a Poly(2-vinyl pyridine) Brush: An AFM Force Measurement Study

Astrid Drechsler、Alla Synytska、Petra Uhlmann 等 5 位作者2012-10-11Langmuir

AFM force measurements have been performed to study the influence of the pH value and salt concentration on the interactions between poly(2-vinyl pyridine) brushes and microsized silica spheres, focusing on attractive and adhesion forces. It was found that the interaction was composed of a repulsive component reflecti…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana

Aleksandra Mitrović、Miodrag Zdujić2012-10-11Journal of the Serbian Chemical Society

Mechanochemical treatment of Serbian kaolin clay was carried out in a planetary ball mill using two different milling media, hardened steel or zirconia vials and balls. The samples obtained with various milling times were characterized by the particle size laser diffraction (PSLD), X-ray diffraction (XRD), differentia…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Frustrated Crystallization in the Coupled Viscoelastic Phase Separation

Weichao Shi、Xu‐Ming Xie、Charles C. Han2012-10-11Macromolecules

The interplay between crystallization and phase separation has been intensively studied recently. In this study, we extended the research into a dynamically asymmetric blend composed of amorphous poly(methyl methacrylate) (PMMA) and crystalline poly(ethylene oxide) (PEO). The large dynamic asymmetry induces network st…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Epitaxy of Nanocrystalline Silicon Carbide on Si(111) at Room Temperature

Roberto Verucchi、Lucrezia Aversa、Marco Vittorio Nardi 等 10 位作者2012-10-11Journal of the American Chemical Society

Silicon carbide (SiC) has unique chemical, physical, and mechanical properties. A factor strongly limiting SiC-based technologies is the high-temperature synthesis. In this work, we provide unprecedented experimental and theoretical evidence of 3C-SiC epitaxy on silicon at room temperature by using a buckminsterfuller…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchFullerene Chemistry and Applications

CROSSOVER BETWEEN MAGNETIC REVERSAL MODES IN ORDERED Ni AND Co NANOTUBE ARRAYS

Mariana P. Proença、C. T. Sousa、J. Ventura 等 6 位作者2012-10-11SPIN

Ordered arrays of Ni and Co nanowires and nanotubes, with diameters between 30 nm and 60 nm, were prepared by electrodeposition into nanoporous alumina templates. The study of the corresponding magnetization reversal processes was performed by analyzing the angular dependence of coercivity (H c ) and using a simple an…

Magnetic properties of thin filmsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Facile synthesis and magnetic phase transformation of Nd–Fe–B nanoclusters by oxygen bridging

Chang Woo Kim、Young Hwan Kim、Umapada Pal 等 4 位作者2012-10-11Journal of Materials Chemistry C

We demonstrate a facile chemical approach for fabricating Nd–Fe–B nanoclusters through oxygen bridging. The Nd–Fe–B nanoclusters comprised of small aggregated particles (∼2 nm diameter) could be successfully synthesized using sodium borohydride, a conventional reducing agent. The three-step process consists of the for…

Metallic Glasses and Amorphous AlloysRare-earth and actinide compoundsMagnetic Properties of Alloys

Dielectric breakdown properties of SF6–N2 mixtures in the temperature range 300–3000 K

Xingwen Li、Hu Zhao、Shenli Jia2012-10-11Journal of Physics D Applied Physics

Abstract Reduced critical electric field strength ( E / N ) cr is an important indicator for the evaluation of dielectric breakdown of SF 6 and its mixtures. This paper aims to analytically investigate the dielectric breakdown properties of SF 6 –N 2 mixtures. First, ( α − η )/ N and ( E / N ) cr of SF 6 –N 2 mixtures…

Semiconductor materials and devicesHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Surface plasmon polaritons in VO_2 thin films for tunable low-loss plasmonic applications

L. Wang、Elizabeth Radue、S. Kittiwatanakul 等 8 位作者2012-10-11Optics Letters

We report on the first observation of optically excited surface plasmon polaritons (SPPs) in the conducting phase of vanadium dioxide (VO(2)) thin films. VO(2) is low-loss optical material that undergoes an insulator-metal transition (IMT) under suitable thermal, optical, or electrical stimulation, thus enabling tunab…

Gas Sensing Nanomaterials and SensorsOptical Wireless Communication TechnologiesTransition Metal Oxide Nanomaterials