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Ti 5 Al 2 C 3 : A New Ternary Carbide Belonging to MAX Phases in the Ti – Al – C System

Xiaohui Wang、Hui Zhang、Liya Zheng 等 7 位作者2012-03-20Journal of the American Ceramic Society

A new compound, Ti 5 Al 2 C 3 , is identified in the bulk sample prepared by reactive hot pressing a mixture of Ti , Al and graphite powders with a nominal molar ratio of Ti : Al : C = 5:2.15:2.78 at 1580°C for 1 h. This compound follows the crystal structure of other MAX phases. The lattice parameters are a = 0.3038…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Integration Technologies for Silicon Carbide‐Based Ceramics for Micro‐Electro‐Mechanical Systems‐Lean Direct Injector Fuel Injector Applications

Michael C. Halbig、Mrityunjay Singh、Hiroshi Tsuda2012-03-20International Journal of Applied Ceramic Technology

Advanced joining approaches are critically needed for the fabrication and integration of silicon carbide‐based micro‐electro‐mechanical systems lean direct fuel injectors for jet engines. Diffusion bonding of silicon carbide with titanium interlayers offers advantages such as uniform application/surface coverage and n…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Electron scattering by methanol and ethanol: A joint theoretical-experimental investigation

M.-T. Lee、Gabriel L. C. de Souza、Marcos Antônio Machado 等 10 位作者2012-03-20The Journal of Chemical Physics

We present a joint theoretical-experimental study on electron scattering by methanol (CH(3)OH) and ethanol (C(2)H(5)OH) in a wide energy range. Experimental differential, integral and momentum-transfer cross sections for elastic electron scattering by ethanol are reported in the 100-1000 eV energy range. The experimen…

Advanced Chemical Physics StudiesAtomic and Molecular PhysicsElectron and X-Ray Spectroscopy Techniques

Self-Consistent Field Theory of Gaussian Ring Polymers

Jaeup U. Kim、Yongbiao Yang、Won Bo Lee2012-03-20Macromolecules

We present a self-consistent field theory (SCFT) formalism of topologically unconstrained ring polymers for the first time. The resulting static properties of homogeneous and inhomogeneous ring polymers are compared with the random phase approximation (RPA) results. For ring homopolymer mixture, as χ N increases, the…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Integral equation analysis of a low‐profile receiving planar microstrip antenna with a cloaking superstrate

Constantinos Valagiannopoulos、Nikolaos L. Tsitsas2012-03-20Radio Science

Eliminating the electromagnetic interaction of a device with its background is a topic which attracts considerable attention both from a theoretical as well as from an experimental point of view. In this work, we analyze an infinite two‐dimensional planar microstrip antenna, excited by an incident plane wave, and prop…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Controlled Synthesis of Linear Polymers with Highly Branched Side Chains by “Hypergrafting”: Poly(4-hydroxy styrene)-graft-hyperbranched Polyglycerol

Christoph Schüll、Holger Frey2012-03-20ACS Macro Letters

Linear polymers with hyperbranched side chains are unusual macromolecular structures due to their high number of functional groups in the side chains as well as their potential cylindrical conformation in bulk or solution. In a three-step synthesis combining anionic and oxy-anionic polymerization, hyperbranched polygl…

Fuel Cells and Related MaterialsRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Towards a deeper understanding of the formation of friction-induced hillocks on monocrystalline silicon

Bingjun Yu、Xiaoying Li、Hanshan Dong 等 6 位作者2012-03-20Journal of Physics D Applied Physics

Abstract Friction-induced hillocks can be produced on monocrystalline silicon by scratching under given conditions. Results show that the height of these hillocks increases with the applied normal load or number of scratching cycles, but decreases with the sliding velocity. Transmission electron microscope (TEM) and e…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdvanced Surface Polishing Techniques

Phototunable Response in Caged Polymer Brushes

Jiaxi Cui、Thi‐Huong Nguyen、Marcelo Ceolı́n 等 6 位作者2012-03-20Macromolecules

A light-responsive brush was obtained by surface-initiated ATRP of a methacrylate monomer containing ionizable −COOH side groups caged with the photoremovable group 4,5-dimethoxy-2-nitrobenzyl (NVOC). In the caged form, the polymer brush (PNVOCMA) is neutral and hydrophobic due to the presence of the aromatic chromoph…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsNanofabrication and Lithography Techniques

A Hybrid Silk/RADA-Based Fibrous Scaffold with Triple Hierarchy for Ligament Regeneration

Kelei Chen、Sambit Sahoo、Pengfei He 等 6 位作者2012-03-20Tissue Engineering Part A

While silk-based microfibrous scaffolds possess excellent mechanical properties and have been used for ligament tissue-engineering applications, the microenvironment in these scaffolds is not biomimetic. We hypothesized that coating a hybrid silk scaffold with an extracellular matrix (ECM)-like network of self-assembl…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Hydrogen-fuel-powered bell segments of biomimetic jellyfish

Yonas Tadesse、Alex Villanueva、Carter S. Haines 等 6 位作者2012-03-20Smart Materials and Structures

Artificial muscles powered by a renewable energy source are desired for joint articulation in bio-inspired autonomous systems. In this study, a robotic underwater vehicle, inspired by jellyfish, was designed to be actuated by a chemical fuel source. The fuel-powered muscles presented in this work comprise nano-platinu…

Shape Memory Alloy TransformationsSoft Robotics and ApplicationsMicro and Nano Robotics

Biological synthesis of silver nanoparticles by Aspergillus flavus, isolated from soil of Ahar copper mine

Saeed Moharrer2012-03-20Indian Journal of Science and Technology

In this study, silver nanoparticles were synthesized using the fungus, Aspergillus flavus at high yield with an aqueous solution of AgNo3. The formation of silver nanoparticles was confirmed using UV-visible spectrophotometer and their presence was displayed by XRD studies. The size and place formation of silver nanop…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsNanotechnology research and applications

Use of eco‐friendly epoxy resins from renewable resources as potential substitutes of petrochemical epoxy resins for ambient cured composites with flax reinforcements

David Bertomeu、D. García‐Sanoguera、O. Fenollar 等 5 位作者2012-03-20Polymer Composites

Abstract In the last years, some high renewable content epoxy resins, derived from vegetable oils, have been developed at industrial level and are now commercially available; these can compete with petroleum‐based resins as thermoset matrices for composite materials. Nevertheless, due to the relatively high cost in co…

Natural Fiber Reinforced CompositesPolymer composites and self-healingEpoxy Resin Curing Processes

Magnetic and electric coupling effects of dielectric metamaterial

Fuli Zhang、Lei Kang、Qian Zhao 等 5 位作者2012-03-20New Journal of Physics

The coupling effects of subwavelength high-permittivity ( ε r > 100) arrayed ceramics which exhibit magnetic and electric Mie resonances are investigated by electromagnetic full-wave analysis. Special attention was paid to the symmetry properties of both magnetic- and electric-induced dipoles by varying independently…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Interactions of NO2 with Amine-Functionalized SBA-15: Effects of Synthesis Route

Benoît Levasseur、Amani M. Ebrahim、Teresa J. Bandosz2012-03-20Langmuir

SBA-15 mesoporous silica was modified using (3-aminopropyl)trimethoxysilane (APTMS) following co-condensation or grafting methods and then used as a NO(2) adsorbent at room temperature. The samples were characterized before and after exposure to NO(2) by SEM-EDX, N(2) adsorption at 77 K, potentiometric titration, ther…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

The influence of the solid thermal conductivity on active magnetic regenerators

K. Nielsen、Kurt Engelbrecht2012-03-20Journal of Physics D Applied Physics

Abstract The influence of the thermal conductivity of the regenerator solid on the performance of a flat plate active magnetic regenerator (AMR) is investigated using an established numerical AMR model. The cooling power at different (fixed) temperature spans is used as a measure of the performance for a range of ther…

Magnetic and transport properties of perovskites and related materialsMagnetic Properties of AlloysMagnetic Field Sensors Techniques

A Two-Step Valence Tautomeric Transition in a Dinuclear Cobalt Complex

Kerwyn G. Alley、Giordano Poneti、Jade B. Aitken 等 10 位作者2012-03-20Inorganic Chemistry

A dinuclear cobalt complex with cobalt centers bridged by a bis(dioxolene) ligand exhibits a rare two-step valence tautomeric transition.

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Self-accommodation of B19′ martensite in Ti–Ni shape memory alloys. Part III. Analysis of habit plane variant clusters by the geometrically nonlinear theory

Tomonari Inamura、Tomohiro Nishiura、H. Kawano 等 5 位作者2012-03-20The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Competition between the invariant plane (IP) condition at the habit plane, the twin orientation relation (OR) and the kinematic compatibility (KC) at the junction plane (JP) of self-accommodated B19′ martensite in Ti–Ni was investigated via the geometrically nonlinear theory to understand the habit plane variant (HPV)…

Shape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Elastic and electronic properties of tI26-type Mg 12 RE (RE = Ce, Pr and Nd) phases

Meng-Xue Zeng、Ren-Nian Wang、Bi‐Yu Tang 等 5 位作者2012-03-20Modelling and Simulation in Materials Science and Engineering

A detailed theoretical study of structural, elastic and electronic properties of tI26-type Mg12RE (RE = Ce, Pr and Nd) phases has been carried out by means of first-principles calculations based on density functional theory. The optimized lattice parameters at T = 0 K are in excellent agreement with the available expe…

Magnesium Alloys: Properties and ApplicationsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Design and Synthesis of FRET-Mediated Multicolor and Photoswitchable Fluorescent Polymer Nanoparticles with Tunable Emission Properties

Jian Chen、Peisheng Zhang、Gang Fang 等 6 位作者2012-03-20The Journal of Physical Chemistry B

Novel multicolor and photoswitchcable fluorescent polymer nanoparticles were prepared by one-step miniemulsion via methyl methacrylate (MMA) copolymerization with 4-ethoxy-9-allyl-1,8-naphthalimide (EANI), allyl-(7-nitro-benzo[1,2,5]oxadiazol-4-yl)-amine (NBDAA) and spiropyran-linked methacrylate (SPMA). Under visible…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

In vivo assessment of the host reactions to the biodegradation of the two novel magnesium alloys ZEK100 and AX30 in an animal model

Tim Andreas Huehnerschulte、Janin Reifenrath、Brigitte von Rechenberg 等 8 位作者2012-03-20BioMedical Engineering OnLine

BACKGROUND: Most studies on biodegradable magnesium implants published recently use magnesium-calcium-alloys or magnesium-aluminum-rare earth-alloys.However, since rare earths are a mixture of elements and their toxicity is unclear, a reduced content of rare earths is favorable. The present study assesses the in vivo…

Bone Tissue Engineering MaterialsMagnesium Alloys: Properties and ApplicationsMagnesium in Health and Disease