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Vapor-deposited thin films with negative real refractive index in the visible regime

Yi-Jun Jen、Akhlesh Lakhtakia、Ching-Wei Yu 等 4 位作者2009-04-27Optics Express

A thin film comprising parallel tilted nanorods was deposited by directing silver vapor obliquely towards a plane substrate. The reflection and transmission coefficients of the thin film were measured at three wavelengths in the visible regime for normal-illumination conditions, using ellipsometry and walk-off interfe…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

Measurement and Simulation of Thermal Stability of Poly(Lactic Acid) by Thermogravimetric Analysis

Mu-Hoe Yang、Yeuh-Hui Lin2009-04-27Journal of Testing and Evaluation

Abstract The thermal degradation of poly(lactic acid) (PLA) biopolymer was studied as used by the thermogravimetry analyzer in a nitrogen atmosphere in the temperature range of 100–500°C. The reaction was found under these experimental conditions to be of first order with an activation energy of 94.0 and 105.3 kJ/mole…

biodegradable polymer synthesis and propertiesThermal and Kinetic AnalysisPolymer Synthesis and Characterization

Analysis of the structure and mass transport properties of nanocomposite polyurethane

Carola Esposito Corcione、Giuseppe Mensitieri、Alfonso Maffezzoli2009-04-27Polymer Engineering and Science

Abstract In this work, nanocomposite adhesives obtained using an organically modified montmorillonite (OMM) in a polyurethane matrix were studied. The basal distance of OMM before and after mixing with the polyol and after curing was characterized by X‐Ray diffraction. The viscosity of polyols‐OMM systems was studied…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Activity of Nitrogen Containing Carbon Nanotubes in Base Catalyzed Knoevenagel Condensation

S. van Dommele、Krijn P. de Jong、Johannes H. Bitter2009-04-27Topics in Catalysis

The catalytic activity of Nitrogen containing Carbon Nanotubes (NCNT), grown from acetonitrile or pyridine over supported Fe-, Co or Ni catalysts at various conditions, were tested for the base catalyzed Knoevenagel condensation of benzaldehyde and ethylcyanoacetate. All NCNT displayed activity for the reaction with i…

Carbon Nanotubes in CompositesGraphene research and applicationsSynthesis and properties of polymers

Delta-doped LaAlO3/SrTiO3 interfaces

Thomas Fix、Judith L. MacManus‐Driscoll、M. G. Blamire2009-04-27Applied Physics Letters

The quasi-two-dimensional electron gases formed at the interface between insulators such as SrTiO3/LaAlO3 are predicted to arise from an interfacial electronic reconstruction, but the extent to which oxygen vacancies within the substrate contribute to the conduction remains unclear. We show that delta-doping the inter…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Morphology and Mechanical Properties of Bicontinuous Gels of Agarose and Gelatin and the Effect of Added Lipid Phase

Preeti Shrinivas、Stefan Kasapis、Taewee Tongdang2009-04-27Langmuir

This study examines the structural properties of binary and tertiary mixtures made of the cold-setting biopolymers agarose and gelatin and a lipid phase with solid or liquid-like viscoelasticity. The working protocol included the techniques of small-deformation dynamic oscillation on shear, modulated differential scan…

Enzyme Production and CharacterizationCollagen: Extraction and CharacterizationPolysaccharides Composition and Applications

Explosion hardening of Hadfield steel crossing

F. C. Zhang、Bo Lv、T. S. Wang 等 8 位作者2009-04-27Materials Science and Technology

In the present paper the effects of explosion hardening on the microstructure and the mechanical properties as well as the lifetime of Hadfield steel (high manganese steel) crossing have been studied. The optimum explosion hardening technology of the high manganese steel crossing was proposed. That is twice explosion…

Metal and Thin Film MechanicsAdvanced materials and compositesMetal Alloys Wear and Properties

Study of a nitrogen-doped ZnO film with synchrotron radiation

Changwei Zou、Xiaolong Yan、Jie Han 等 6 位作者2009-04-27Applied Physics Letters

X-ray absorption near-edge spectroscopy (XANES) and photoelectron spectroscopy (PES) with synchrotron radiation have been applied to investigate the structure and chemical states of nitrogen atoms in ZnO:N films with different annealing temperatures. The high-resolution XANES and PES spectra of N 1s reveal the chemica…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

On the Adsorption of Tetracycline by Calcined Magnesium‐Aluminum Hydrotalcites

Zhaoyi Xu、Jie Fan、Shourong Zheng 等 5 位作者2009-04-27Journal of Environmental Quality

Exploiting effective sorbents for antibiotic adsorption is highly desirable for the elimination of ecological risks from antibiotic contamination. In this study, MgAl-CO(3)(2-) hydrotalcites with different Mg/Al molar ratios were prepared and tetracycline (TC) adsorption to the hydrotalcites and calcined hydrotalcites…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsNanomaterials for catalytic reactions

Mn–Mn couplings in Mn-doped CdS nanocrystals studied by magnetic circular dichroism spectroscopy

Seiji Taguchi、Atsushi Ishizumi、Takeshi Tayagaki 等 4 位作者2009-04-27Applied Physics Letters

We report on the optical and magnetic properties of Mn-doped CdS nanocrystals coated with a ZnS shell layer (CdS:Mn/ZnS core-shell nanocrystals) by magnetic circular dichroism (MCD) spectroscopy. The magnetic field and temperature dependences of the MCD spectrum show paramagnetic behavior of the CdS:Mn/ZnS core-shell…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Unexpected Alternated Radical Copolymerization of Vinylidene Cyanide with a Fluorinated Vinyl Ether for Superhydrophobic and Highly Oleophobic Films

Ahmed Meskini、Mustapha Raihane、Bruno Améduri2009-04-27Macromolecules

The synthesis and the characterization of original copolymers based on vinylidene cyanide (VCN) and 1 H,1 H,2 H,2 H -perfluorodecyl vinyl ether (FAVE8) are presented. While VCN is known to be very reactive in radical homopolymerization in contrast to the vinyl ether which does not homopolymerize, the radical copolymer…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsPer- and polyfluoroalkyl substances research

Enhanced ferromagnetism and ferroelectricity in multiferroic CuCr1−xNixO2

Shijun Luo、Kefeng Wang、S. Z. Li 等 7 位作者2009-04-27Applied Physics Letters

Polycrystalline CuCr1−xNixO2 is synthesized and its multiferrocity is characterized in order to enhance the ferromagnetism and ferroelectricity of CuCrO2-based multiferroics. At the optimized doping level x=0.05, we observe not only an enhancement of one order of magnitude in magnetization but also a remarkable increa…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Critical Evaluation of Determining Swelling Pressure by Swell-Load Method and Constant Volume Method

H. B. Nagaraj、M. Mohammed Munnas、A. Sridharan2009-04-27Geotechnical Testing Journal

Abstract For any construction activity in expansive soils, determination of swelling pressure/heave is an essential step. Though many attempts have been made to develop laboratory procedures by using the laboratory one-dimensional oedometer to determine swelling pressure of expansive soils, they are reported to yield…

Textile materials and evaluations

Theoretical Characterization of Electronic Transitions in Co2+- and Mn2+-Doped ZnO Nanocrystals

Ekaterina Badaeva、Christine M. Isborn、Yong Feng 等 6 位作者2009-04-27The Journal of Physical Chemistry C

Linear response time-dependent hybrid density functional theory has been applied for the first time to describe optical transitions characteristic of Co 2+ - and Mn 2+ -doped ZnO quantum dots (QDs) with sizes up to 300 atoms (∼1.8 nm diam) and to investigate QD size effects on the absorption spectra. Particular attent…

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Solubility of Butanedioic Acid in Different Solvents at Temperatures between 283 K and 333 K

Qiushuo Yu、Simon Black、Hongyuan Wei2009-04-27Journal of Chemical & Engineering Data

Using a laser monitoring observation technique, the solubilities of butanedioic acid in water, ethanol, 1-propanol, 2-propanol, acetone, and ethanoic acid were determined by the synthetic method at temperatures between 283 K and 333 K. A laser technique is used to determine the disappearance of solute particles. The e…

Phase Equilibria and ThermodynamicsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Preparation of poly(acrylonitrile–butadiene–styrene)/montmorillonite nanocomposites and degradation studies during extrusion reprocessing

E.‐K. Karahaliou、P. A. Tarantili2009-04-27Journal of Applied Polymer Science

Abstract In this study, the preparation of organically modified montmorillonite/poly(acrylonitrile–butadiene–styrene) (ABS) nanocomposites was studied by melt blending in a twin‐screw extruder. The composite material was subjected to a series of five extrusion cycles, and the effect of reprocessing on the material's s…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Influence of multiwall carbon nanotubes on the mechanical properties and unusual crystallization behavior in melt‐mixed co‐continuous blends of polyamide6 and acrylonitrile butadiene styrene

Suryasarathi Bose、Arup R. Bhattacharyya、Liane Häußler 等 4 位作者2009-04-27Polymer Engineering and Science

Abstract The mechanical and the crystallization behavior of melt‐mixed cocontinuous blends of polyamide6 (PA6) and acrylonitrile butadiene styrene were studied in presence of multiwall carbon nanotubes (MWNT). Young's modulus was observed to be significantly improved with increasing concentration of MWNT, while only m…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Resistive switching characteristics in Pr0.7Ca0.3MnO3 thin films on LaNiO3-electrodized Si substrate

Wen-Yuan Chang、Jeng-Hwa Liao、Yun-Shan Lo 等 4 位作者2009-04-27Applied Physics Letters

The resistive switching characteristics of Pr0.7Ca0.3MnO3 (PCMO) thin films deposited on LaNiO3 (LNO)-electrodized Si substrate were investigated. Highly (100)-textured PCMO films were grown on the (100)-oriented LNO electrode. They exhibited reversible and steady bistable resistance switching behavior. The resistive…

Ferroelectric and Piezoelectric MaterialsAdvanced Memory and Neural ComputingMagnetic and transport properties of perovskites and related materials

Hydrogen Production through the Water−Gas Shift Reaction: Thermodynamic Equilibrium versus Experimental Results over Supported Ni Catalysts

Agus Haryanto、Sandun Fernando、S. D. Filip To 等 6 位作者2009-04-27Energy & Fuels

This paper discusses the experimental results of the water−gas shift reaction over supported nickel catalysts in comparison to thermodynamic equilibrium composition at the same reaction conditions. The effects of different supports on the performance of H 2 production over nickel-supported catalysts are also evaluated…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingAmmonia Synthesis and Nitrogen Reduction

Interactive Radical Dimers in Photoconductive Organic Thin Films

Akito Iwasaki、Laigui Hu、Rie Suizu 等 11 位作者2009-04-27Angewandte Chemie International Edition

Fully interactive: Overlap between extended unoccupied molecular orbitals leads to the high photoconductivity of interactive radical dimers. Sandwich-type cells (see picture; ITO = indium tin oxide) comprising highly oriented thin films of a disjoint diradical, 4,4'-bis(1,2,3,5-dithiadiazolyl) (BDTDA) exhibit a photoc…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchOrganic and Molecular Conductors Research