Materials Literature
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The dispersion interaction between two point-like particles confined in a dielectric slab between two plates of another dielectric medium is studied within a continuum (Lifshitz) theory. The retarded (Casimir-Polder) interaction at large inter-particle distances is found to be strongly enhanced as the mismatch between…
Surface-bound modes in metamaterials forged by drilling periodic hole arrays in perfect-conductor surfaces are investigated by means of both analytical techniques and rigorous numerical solution of Maxwell's equations. It is shown that these metamaterials cannot be described in general by local, frequency-dependent pe…
Using density functional theory, we demonstrate that superconductivity in ${\mathrm{C}}_{6}\mathrm{Ca}$ is phonon mediated with $\ensuremath{\lambda}=0.83$ and phonon frequency $⟨\ensuremath{\omega}{⟩}_{\mathrm{log}}=24.7\text{ }\text{ }\mathrm{meV}$. The calculated isotope exponents are $\ensuremath{\alpha}(\mathrm{…
The energy-level alignment at interfaces between three electroactive conjugated organic materials and Au was systematically varied by adjusting the precoverage of the metal substrate with the electron acceptor tetrafluoro-tetracyanoquinodimethane (F4-TCNQ). Photoelectron spectroscopy revealed that electron transfer fr…
We demonstrate the key role of phonon occupation in limiting the high-field ballistic transport in metallic carbon nanotubes. In particular, we provide a simple analytic formula for the electron transport scattering length, which we validate by accurate first principles calculations on (6, 6) and (11, 11) nanotubes. T…
The energies of point defects in graphite have been calculated from first principles. The various interplane interstitial configurations are found to have a wider range of energies than in some earlier calculations, implying a larger interstitial migration energy than previously expected $(>1.5\phantom{\rule{0.3em}…
Glasses have a large excess of low-frequency vibrational modes in comparison with most crystalline solids. We show that such a feature is a necessary consequence of the weak connectivity of the solid, and that the frequency of modes in excess is very sensitive to the pressure. We analyze, in particular, two systems wh…
To understand the formation mechanism of magnetic moments at the edges of graphitic fragments, we carry out first-principles density-functional calculations for the electronic and magnetic structures of graphitic fragments with various spin and geometric configurations. We find that interedge and interlayer interactio…
In this work a simple concept was used for a systematic search for materials with high spin polarization. It is based on two semiempirical models. First, the Slater-Pauling rule was used for estimation of the magnetic moment. This model is well supported by electronic structure calculations. The second model was found…
The synthesis of TlGa 1− x Yb x S 2 single crystals with the partial substitution of ytterbium for gallium is described. Variations in the electric conductivity of grown crystals irradiated with X-rays of various intensities are measured.
Around the year 1500, Leonardo da Vinci designed the first mechanical calculator connecting a number of toothed wheels for simple adding operations. Since then, mechanical systems have become a major part of the later industrial revolutions with an abundance of machines in our everyday lives. Only with the advent of s…
A new sucrose ester, acretoside, has been isolated from the roots of the Greek endemic species Aristolochia cretica and identified as 6-O-p-coumaroyl-beta-D-fructofuranosyl-(2 --> 1)-alpha-D-glucopyranoside (1). In addition, a known sucrose ester, identified as arillatose B, two phenylpropanoid glucose esters, and fiv…
Abstract We have prepared nanocomposites of intercalated and exfoliated organosilicates in butadiene rubber (BR) by using a two‐stage melt blending process. We used X‐ray diffraction and transmission electron microscopy to examine, respectively, the intergallery spacing of the organosilicates and their dispersion in t…
This work aimed at studying the electrochemical reduction of the hexavalent chromium Cr(VI) by means of a tubular reactor operating under both continuous and batch regimes. It is shown that chromium (VI) reduction to chromium (III) was exerted not only by the oxidation of iron to Fe(II) released from the steel sacrifi…
Abstract Facile antimony(V/III) transition has been found to occur in phthalocyanine complexes via oxidative addition/reductive elimination process.
An antiparallel orientational transition is reported for an intermetallic compound, i.e., ${\mathrm{Cd}}_{6}\mathrm{Ca}$ crystal, which is a $1∕1\ensuremath{-}1∕1\ensuremath{-}1∕1$ crystalline approximant to the icosahedral quasicrystal ${\mathrm{Cd}}_{5.7}\mathrm{Ca}$. A group theoretical analysis based on the Landau…
The stability of crystalline acetylsalicylic acid (ASA) powder in binary mixtures with cellulose powders was investigated to reveal information about the influence of the cellulose structural properties on the moisture-induced ASA degradation. Different cellulose powder samples were manufactured and characterized by X…
Polymer nanocomposites with carbon nanotubes (CNT) are becoming important structural materials because of their superior mechanical properties and easy processability. The objective of the work is to investigate the influence of small amounts of single walled carbon nanotubes (SWCNT), as well as multi-walled carbon na…
Transport in suspended metallic single-wall carbon nanotubes in the presence of strong electron–electron interaction is investigated. We consider a tube of finite length and discuss the effects of the coupling of the electrons to the deformation potential associated to the acoustic stretching and breathing modes. Trea…
Spatially resolved electron field emission experiments on oxidized highly phosphorus-doped homoepitaxial diamond (111) were applied at room temperature. The diamond layer shows hopping conductivity. Field emission properties have three distinct regions. We attribute the variation in emission currents to: (a) Electron…