Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew approach to the preparation of tetrathiafulvalenium saltsF. WudlCite this: J. Am. Chem. Soc. 1975, 97, 7, 1962–1963Publication Date (Print):April 1, 1975Publication History Published online1 May 2002Published inissue 1 April 1975https://pubs.acs.org/doi/10.1021/ja00840a0…
1 The cellulolytic enzyme (β-1,4-glucan cellobiohydrolase) isolated from culture filtrates of the fungus Trichoderma viride as described previously by us was further characterized as regards chemical, physico-chemical and enzymatic properties. 2 The amino-acid composition revealed a high content of acidic amino acids…
Abstract Molecular core binding energies have been measured by ESCA for series of surface‐fluorinated high‐density polyethylene films. Detailed analysis of the results shows that the technique can be used to establish a comprehensive picture of the early stages of the surface fluorination process. Both the depth of fl…
Abstract A study has been carried out of the changes in the x‐ray diffraction patterns which occur when oriented fibers or tapes of poly(trimethylene terephthalate) (3GT) and poly‐(tetramethylene terephthalate) (4GT) are subjected to mechanical tensile stress. Although the polymers show very different behavior in deta…
ADVERTISEMENT RETURN TO ISSUEPREVArticleGeometrical isomerism arising from partial substitution of metal atoms in isopoly and heteropoly complexes. Possibilities for the Keggin structureMichael T. Pope and Thomas F. ScullyCite this: Inorg. Chem. 1975, 14, 4, 953–954Publication Date (Print):April 1, 1975Publication His…
It has been demonstrated that the natural atmospheric corrosion behavior of low-alloy steels in industrial environments can be accurately described by an equation of the form: ΔW = K tN. Thus, reliable predictions of long-term behavior become possible, and a vehicle is provided for accurately assessing the effect on a…
Abstract The kinetics of formation of the 1:1 and 2:1 adducts of (in terms of equivalents of epoxide) 2,3‐epoxypropyloxybenzene ( 2 ) and 2,2‐bis[ p ‐(2,3‐epoxypropyloxy)phenyl]‐propane ( 1 ) with 2‐ethyl‐4‐methylimidazole ( 3 ) have been investigated by differential scanning calorimetry (DSC). A comparison of isother…
The transient nonlinear oscillations of a spherical gas bubble in an incompressible, viscous liquid subject to the action of a sound field are investigated by means of an asymptotic method. Approximate analytical solutions are presented for the frequency regions of the fundamental resonance, the first and second subha…
Abstract Amorphous silk fibroin with random coil conformation shows endothermic and exothermic peaks and endothermic shift on the DSC (differential scanning calorimetry) curve. The endothermic shift observed at 175°C was due to the glass transition. The exothermic peak at 212°C is recognized to be the crystallization,…
The Bragg condition λ = 2d sin θ is presented as a necessary condition for perfect (100%) blazing of infinite, perfectly conducting diffraction gratings that produce only a single diffracted order, n = −1. As an illustration, the rectangular-profile grating is analyzed. Design blaze curves, showing the required depth…
A model for the conduction mechanism in polymer insulating materials based on a classical concept is described; the application may possibly be extended beyond polymers. By means of this model, a formula expressing the field dependence of conductivity is derived. The values given by this formula have been checked agai…
Abstract XPS techniques were used to clarify the state of supported cobalt catalysts. In order to characterize Co2+ and Co3+, the spin-orbit splitting of the 2p level, which is considered to be affected by the exchange interaction between the unpaired 3d electrons and 2p electrons, was found to be very useful. The int…
Reflection behavior is examined for an interface having periodic height variation. Upon employing the Bloch theorem, in conjunction with the extended boundary condition, exact matrix equations are obtained for surface fields, as well as transmitted and reflected wave amplitudes. Tunneling considerations then lead to n…
The program comprises a main program for inspection and correction of the intensity data, and a number of subroutines covering specific operations. These subroutines can be called upon in any desired sequence.
Abstract The synthesis of six unsymmetrically substituted tetraarylporphyrins is reported. The compounds prepared are 5‐(R),10,15,20‐tritolylporphyrins, where R = 2‐pyridyl, 3‐pyridyl, 4‐acet‐amido, and 2,3 or 4‐hydroxyphenyl. Four new tetrasubstituted tetraarylporphyrins (5,10,15,20‐tetra‐(R)‐porphyrin) are also repo…
The internal friction and dynamic modulus of W single crystals were measured after neutron irradiation near liquid-helium temperature. The results on dislocation pinning and the associated relaxation peaks suggest that in W the $〈110〉$ split interstitials perform a free migration at \ensuremath{\sim} 15 K (substage ${…
Abstract The infrared and photoelectron spectra of some substituted acetylacetones have been measured, and interpreted in terms of enolic and ketonic structures. Ionization potentials from specific orbitals have been assigned. With different substituents, the proportion of the two forms varies considerably. From measu…
X-ray photoemission spectra of W core levels in metallic sodium tungsten bronzes, ${\mathrm{Na}}_{x}\mathrm{W}{\mathrm{O}}_{3}$, clearly show asymmetries due to many-body effects. Na and O core levels show only the expected plasmon satellite, demonstrating the importance of the local density of states in the screening…
Neutron-scattering studies of $2H$-Nb${\mathrm{Se}}_{2}$ and $2H$-Ta${\mathrm{Se}}_{2}$ reveal the strong Kohn anomalies and incommensurate superlattice characteristic of charge-density-wave instabilities. Whereas the Nb${\mathrm{Se}}_{2}$ superlattice (${T}_{0}=33.5$ K) remains incommensurate to 5 K, Ta${\mathrm{Se}}…
Normal modes of vibration in vitreous SiO 2 , GeO 2 and BeF 2 are discussed from the point of view of the relative phase of motion of neighbouring atoms in the system. The notion of a phase quotient is introduced, as a criterion for determining the extent to which modes are acoustic or optical in character. Use of the…