Materials Literature
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Syntheses of two series of new styryl dyes incorporating thiacrown ether moieties (CSDs 3a − e, 4a − e ) are described. 1 H NMR and UV−vis measurements show that these compounds exhibit a strong preference for formation of complexes with heavy metal ions. Polarographic measurements allow conversion of relative complex…
Measures to counteract proteolysis during sample preparation are widely used; among them, protein extraction at a basic pH (Tris pH 11.0), sample boiling in sodium dodecyl sulfate (SDS), extraction in denaturing lysis solutions and the use of proteinase inhibitors combined with some of these approaches. Here, we teste…
[structure: see text] A novel TTF-based donor with a uracil moiety, TTF-(1-n-butyluracil-5-yl) (TnbU), was synthesized. Crystal structures of both TnbU and the charge-transfer complex of TnbU-hydrogen cyananilate possess complementary double hydrogen bonds through uracil moieties and pi-stacking dimer structures betwe…
The formation of glycerol-3-phosphate (G3P) in cells growing on TB causes catabolite repression, as shown by the reduction in malT expression. For this repression to occur, the general proteins of the phosphoenolpyruvate-dependent phosphotransferase system (PTS), in particular EIIA(Glc), as well as the adenylate cycla…
Abstract The method for prediction of Gibbs free energies of formation, based on the parameter Δ G O= M z + (clay) characterizing the oxygen affinity of the cation M z + , on the smectites, considered as hydrated clay minerals, has been used for micas and brittle micas, and yielded underestimated values. This method o…
Summary The soils and sediments of the uplands in the Manaus region are described and analysed along a representative cross‐section. There are two broad types of features, lateritic and redoximorphic. Their formation is linked to two main processes acting under contrasted hydrological regimes. The first process, actin…
The main purposes of wastewater treatment systems are to remove organic pollutants, but it would be very attractive if there were a way to recover the organic pollutants as valuable organic materials. One of the possible ways to recover organic pollutants in wastewater is to convert them into polyhydroxyalkanoates (PH…
A series of formulations with varying enzyme and chelator components is tested for flax fiber yield and properties using a recently developed enzyme retting system on Ariane flax grown as a winter crop in southeastern South Carolina. The levels of Viscozyme L, a commercial pectinase-rich enzyme mixture, and Mayoquest…
A stable colloidal form of novel π-conjugated polydithiafulvene (PDF)-protected PbS nanoparticles was first prepared in a nonaqueous solution at room temperature. The results of X-ray diffraction (XRD) and transmission electron microscopy (TEM) images demonstrated that the synthesized PbS nanoparticles of stable collo…
Well-aligned carbon nanotubes (CNTs) were grown on mesoporous silica films by chemical vapor deposition (CVD). Ethylene was used as the carbon source and CVD was performed at 1023 K and atmospheric pressure. The films were doped with Fe during sol−gel synthesis, and three different structure directing agents were used…
The molecular configuration and long-range order at the surface of spin-cast poly(ethylene terephthalate) (PET) thin films spin-cast onto an etched Si(001) surface during crystallisation from the amorphous state has been investigated for a range of annealing temperatures. The structural ordering at the surface of the…
Well-ordered 2-D polyaniline (PAni) honeycomb films were produced by electropolymerization of aniline within the interstitial voids in assemblies of polystyrene (PS) nanospheres precoated with poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) (PDADMAC/PSS) thin shells, followed by the extracti…
The mechanism for NO 2 storage in barium oxide supported on magnesium oxide (BaO/MgO) was investigated. In situ Raman spectroscopy was used to follow temporal changes in the composition of the catalyst that occurred during the reaction with NO 2 . Up to catalyst temperatures of 400 °C, the formation of an intermediate…
Thin films of wide-gap p-type (LaO)CuS were prepared by rf sputtering followed by postannealing. Undoped (LaO)CuS films are electrically insulating and emit ultraviolet (UV) light arising from excitons at room temperature upon photoexcitation. The hole carrier concentration in the film was controlled in the range ∼101…
We have prepared Pt/SrBi2Ta2O9 (SBT)/Si metal-ferroelectric-semiconductor (MFS) and Pt/SBT/Y2O3/Si metal-ferroelectric-insulator-semiconductor (MFIS) ferroelectric gate structures and investigated the changes in memory window with different thickness of SBT and Y2O3 in the MFS and MFIS. As a result, it is found that t…
Abstract The barrier and mechanical properties of biodegradable melt‐mixed polyesteramide/octadecylamine‐treated montmorillonite clay (filler) have been studied. Extruded films containing 5 and 13 wt% filler were prepared by melt‐mixing. Samples compression molded after extrusion was also studied. Oxygen and water tra…
Well-aligned carbon nitride nanotubes are fabricated by microwave plasma assisted chemical vapor deposition using iron as the catalyst. These nanotubes are linearly polymerized by carbon nitride nanobells with catalyst particles in the root, as revealed by high-resolution transmission electron microscopy. Carbon nitri…
Porous Y 2 O 3 ‐stabilized ZrO 2 (YSZ) samples were synthesized by preparing NiO/YSZ composites by tape casting and calcining at 1800 K, reducing the NiO to nickel in H 2 at 973 K, and finally leaching the nickel out of the structure with 2.2 M HNO 3 at 353 K. Porous YSZ was prepared from NiO/YSZ composites containing…
The purpose of this report is to describe the appropriate use of indices relating to crystallinity, such as the ‘crystallinity index’, the ‘Hinckley index’, the ‘Kübler index’, and the ‘Árkai index’. A ‘crystalline’ solid is defined as a solid consisting of atoms, ions or molecules packed together in a periodic arrang…
Abstract X‐ray diffraction methods and DSC thermal analysis have been used to investigate the structural change of nylon 6/clay nanocomposites. Nylon 6/clay has prepared by the intercalation of ε‐caprolactam and then exfoliaton of the layered saponite or montmorillonite by subsequent polymerization. Both X‐ray diffrac…