Materials Literature
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Abstract Three novel hexanuclear core‐based hydroxidolanthanide coordination polymers [Ln 3 (BDC) 3.5 (OH) 2 (H 2 O) 2 ] · H 2 O [Ln = Y ( 1 ), Yb ( 2 ) and Er ( 3 ); BDC = 1,4‐benzenedicarboxylate] were prepared by the hydrothermal method. The controlled hydrolysis of lanthanide ions led to an open hexanuclear cluste…
“Nano-onions” with multifold alternating CdS/CdSe or CdSe/CdS structure have been synthesized via a two-phase approach. The influences of shell on photoluminescence (PL) quantum yields (QYs) and PL lifetimes are investigated and discussed. It is found that the outmost shell plays an important role in the PL QYs and PL…
This paper deals with the degradation processes occurring during polymer processing. Some general aspects of polymer processing are first recalled. Then, oxidation mechanisms and kinetics are evoked and the main processing methods are compared from this point of view. Temperature–molar mass maps allow to define a proc…
A novel nanoparticle−hydrogel assembly was made with a specially designed bile acid-derived thiol to stabilize Au nanoparticles. These particles have been found to stay dispersed in a polar medium in the presence of a bile acid-derived gelator.
A computational study of the electronic structure and magnetic properties of Gd pnictides is reported. The calculations were performed using a full-potential linear muffin-tin orbital method within the so-called $\mathrm{LSDA}+\mathrm{U}$ approach, which adds Hubbard-$U$ correlation effects to specified narrow bands i…
The charge-disordered three-dimensional uniaxial relaxor ferroelectric Sr0.61Ba0.39Nb2O6 splits up into metastable polar nanoregions and paraelectric interfaces upon cooling from above Tc. The frozen polar nanoregions are verified by piezoresponse force microscopy, respond domainlike to dynamic light scattering and di…
Effects of interactions with electrons on optical phonons are studied in an effective-mass approximation. The longitudinal mode with displacement in the axis direction is lowered in its frequency, while the transverse mode with displacement in the circumference direction is raised, in metallic nanotubes. The shifts ar…
Single-walled carbon nanotubes (SWNTs) have high surface area, high adsorption ability, and nanoscale interactions. In this study, capillary columns including SWNTs, ionic liquid (IL), and IL + SWNTs for GC were prepared. The separation results showed that SWNTs possessed a wide selectivity toward alkanes, alcohols, a…
The cold crystallization kinetics in ultrathin polymer films were analyzed by using spectroscopic techniques. The Dielectric spectroscopy (DS) used to monitor in real time the crystallization of ultrathin polymer films of PHB resulted that the thickness of the sample does not influence the change occurring in the amor…
We report the results of an experimental and theoretical study of hydrogen storage in sodium alanate (NaAlH(4)). Reversible hydrogen storage in this material is dependent on the presence of 2-4% Ti dopant. Our combined study shows that the role of Ti may be linked entirely to Ti-containing active catalytic sites in th…
Organic materials with large third-order nonlinearities in the near-infrared spectral regime are critical in the development of photonic devices to be utilized in all-optical signal processing. We have developed polymethine materials, specifically bisdioxaborine-terminated polymethine dyes, which possess large ultrafa…
We study the resistively detected nuclear magnetic resonance (NMR) in an AlGaAs/GaAs quantum Hall device with a side gate. The strength of the hyperfine interaction between electron and nuclear spins is modulated by tuning a position of the two-dimensional electron systems with respect to the polarized nuclear spins u…
Spin-orbit coupling is studied using the quantum interference corrections to conductance in AlGaN/AlN/GaN two-dimensional electron systems where the carrier density is controlled by the persistent photoconductivity effect. All the samples studied exhibit a weak antilocalization feature with a spin-orbit field of aroun…
The plastic deformation of dilute alloys is often accompanied by plastic instabilities due to dynamic strain aging and dislocation interaction. The repeated breakaway of dislocations from and their recapture by solute atoms leads to stress serrations and localized strain in the strain controlled tensile tests, known a…
Abstract The structural and thermodynamical properties of weak polyelectrolytes end‐tethered to surfaces of arbitrary geometry are studied using a molecular theory. The theory is based on writing down the free energy functional of the system including all the basic interactions and the explicit acid–base equilibrium f…
We report on a study of the dynamics of a magnetic antivortex in a submicron, asteroid shaped, permalloy ferromagnet using micromagnetic simulations. As with vortex states in disk and square geometries, a gyrotropic mode was found in which a shifted antivortex core orbits about the center of the asteroid. Pulsed magne…
The local atomic structure of Ni-Mn-Ga alloys was explored using Mn and Ga K-edge extended X-ray fine structure (EXAFS) measurement. The changes occuring in the L1$_0$ sub-cell of the martensitic unit cell and the bond lengths obtained from the analysis enables us to propose a scheme for the structural distortions res…
Interactions between O(2) and CeO(2) are examined experimentally using in situ Raman spectroscopy and theoretically using density-functional slab-model calculations. Two distinct oxygen bands appear at 825 and 1131 cm(-1), corresponding to peroxo- and superoxo-like species, respectively, when partially reduced CeO(2)…
Intelligent textiles and clothing - a part of our intelligent ambience Methods and models for intelligent garment design. Part 1 Phase change material: Introduction to phase change materials Intelligent textiles with PCMs The use of phase change materials in outdoor clothing. Part 2 Shape memory materials: Introductio…
We study the nucleation of a new thermodynamic phase in pores and find that the nucleation often proceeds via two steps: nucleation of pore filling, and nucleation out of the pore. These two rates have opposing dependencies on pore size, resulting in a pore size at which the nucleation rate of the new phase is maximal…