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Synthesis, computational and electrochemical characterization of a family of functionalized dimercaptothiophenes for potential use as high-energy cathode materials for lithium/lithium-ion batteries

Yasuyuki Kiya、Jay C. Henderson、Geoffrey Hutchison 等 4 位作者2007-01-01Journal of Materials Chemistry

We present a family of a novel class of organosulfur compounds based on dimercaptothiophene and its derivatives, with a variety of functional groups (electron-donating or electron-withdrawing groups) and regiochemistries, designed as potential high-energy cathode materials with sufficient charge/discharge cyclability…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Direct NO decomposition over stepped transition-metal surfaces

Hanne Falsig、Thomas Bligaard、Claus H. Christensen 等 4 位作者2007-01-01Pure and Applied Chemistry

Abstract We establish the full potential energy diagram for the direct NO decomposition reaction over stepped transition-metal surfaces by combining a database of adsorption energies on stepped metal surfaces with known Brønsted-Evans-Polanyi (BEP) relations for the activation barriers of dissociation of diatomic mole…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsAmmonia Synthesis and Nitrogen Reduction

Thermoelectric power factor of nanoporous semiconductors

Natalio Mingo、David Broido2007-01-01Journal of Applied Physics

We compute the thermoelectric power factor of a nanoporous matrix material. Although the porous material is a connected, extended system, where perfect confinement cannot take place, we show that “quasi-confinement” can occur, thus increasing the matrix’s optimized power factor above bulk values. For parabolic band ma…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Reducing fouling during UHT treatment of goat's milk

Sangeeta Prakash、Nivedita Datta、M.J. Lewis 等 4 位作者2007-01-01Victoria University Research Repository (Victoria University)

Whole fresh goat's milk was heat treated at 135 degrees C for 4 s using a miniature UHT plant. The temperature of the milk in the preheating and sterilizer sections, and the milk flow rate were monitored to evaluate the overall heat transfer coefficient (OHTC). The decrease in OHTC was used to estimate the extent of f…

Calcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic EffectsFreezing and Crystallization Processes

Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfide nanorods: improved miscibility and enhanced photoconductivity

Haipeng Xu、Bo-Yu Xie、Wang Zhang Yuan 等 10 位作者2007-01-01Chemical Communications

Molecules of a thiol-functionalized phenylacetylene derivative were assembled on the CdS nanorod surface and copolymerized with phenylacetylene, affording an inorganic semiconductor-conjugated polymer hybrid with excellent solubility and high photoconductivity.

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Four copper(ii) pyrazolido complexes derived from reactions of 3{5}-substituted pyrazoles with CuF2 or Cu(OH)2

Q.F. Mokuolu、Dolos Foguet‐Albiol、Leigh F. Jones 等 9 位作者2007-01-01Dalton Transactions

Treatment of CuF(2) with 2 equiv of 3{5}-[pyrid-2-yl]pyrazole (Hpz(Py)), 3{5}-phenylpyrazole (Hpz(Ph)) or 3{5}-[4-fluorophenyl]pyrazole (Hpz(PhF)) in MeOH, followed by evaporation to dryness and recrystallisation of the solid residues, allows solvated crystals of [{Cu(micro-pz(Py))(pz(Py))}(2)] (1), [{Cu(micro-pz(Ph))…

Metal complexes synthesis and propertiesMagnetism in coordination complexesFerrocene Chemistry and Applications

Low-loss single-layer metamaterial with negative index of refraction at visible wavelengths

Carlos García‐Meca、R. Ortuño、R. Salvador 等 5 位作者2007-01-01Optics Express

We present a structure exhibiting a negative index of refraction at visible or near infrared frequencies using a single metal layer. This contrasts with recently developed structures based on metal-dielectric-metal composites. The proposed metamaterial consists of periodically arranged thick stripes interacting with e…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Metal complexes formed by metal-assisted solvolysis of di-pyridylketone azine: structures and magnetic properties

Dayu Wu、Wei Huang、Weijie Hua 等 7 位作者2007-01-01Dalton Transactions

A series of metal complexes were achieved from the metal-assisted solvolysis reaction of di-pyridylketone azine (dpka). The tetranuclear nickel cluster , [Ni(2)[dpk(O)(OH)][dpk(O)(OCH(3))](N(3))(2)](2), is centrosymmetric with a central core described as an edge-shared triangle core. Neighboring Ni(II) ions are altern…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Liquid Phase Patterning of Ceramics(Review)

Yoshitake Masuda2007-01-01Journal of the Ceramic Society of Japan

We suggested liquid phase patterning (LPP) of ceramics and fabricated nano/micropatterns of ceramic thin films in the solutions. Molecular recognitions of functional groups of self-assembled monolayer (SAM) were utilized for site-selective deposition (SSD) of oxides based on crystallography, interfacial chemistry and…

Catalytic Processes in Materials ScienceQuantum Dots Synthesis And PropertiesElectronic and Structural Properties of Oxides

Synthesis of 3,4-alkoxythieno[2,3-b]thiophene derivatives. The first block copolymer associating the 3,4-ethylenedioxythieno[2,3-b]thiophene (EDOThT) unit with 3,4-ethylenedioxythiophene (EDOT) moieties

Noémie Hergué、Pierre Frère2007-01-01Organic & Biomolecular Chemistry

The synthesis of 3,4-alkoxythieno[2,3-b]thiophene derivatives has been developed from the readily accessible dimethyl or diethyl 3,4-dihydroxythieno[2,3-b]thiophenedicarboxylates. The yields for the dialkoxy derivatives were strongly dependent both on the base and the alkylating agent used for the nucleophilic substit…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsPhotochromic and Fluorescence Chemistry

CHARACTERISTICS OF ELECTROMAGNETIC WAVE PROPAGATION IN BIAXIAL ANISOTROPIC LEFT-HANDED MATERIALS

Wei Ding、Liang Chen、Chang-Hong Liang2007-01-01Electromagnetic waves

This paper investigates the characteristics of electromagnetic wave propagation in biaxially anisotropic left-handed materials (BA-LHMs) theoretically and numerically.We discuss under what conditions the anomalous refraction or reflection will occur at the interface when a plane wave passes from one isotropic right-ha…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisElectromagnetic wave absorption materials

Effect of Carbon Nanofiber Heat Treatment on Physical Properties of Polymeric Nanocomposites—Part I

Khalid Lafdi、William Fox、Matthew Matzek 等 4 位作者2007-01-01Journal of Nanomaterials

The definition of a nanocomposite material has broadened significantly to encompass a large variety of systems made of dissimilar components and mixed at the nanometer scale. The properties of nanocomposite materials also depend on the morphology, crystallinity, and interfacial characteristics of the individual consti…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Physical properties of soft repulsive particle fluids

D. M. Heyes、A. C. Brańka2007-01-01Physical Chemistry Chemical Physics

Molecular dynamics computer simulation has been applied to inverse power or soft-sphere fluids, in which the particles interact through the soft-sphere pair potential, phi(r) = epsilon(sigma/r)(n), where n measures the steepness or stiffness of the potential, and epsilon and sigma are a characteristic energy and dista…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesNMR spectroscopy and applications

Influence of chemical treatments on the interfacial adhesion between sisal fibre and different biodegradable polymers

Vera A. Álvarez、Iñaki Mondragòn、A. Vázquez2007-01-01Composite Interfaces

The influence of chemical treatments on the interfacial adhesion of sisal fibres and biodegradable matrices were studied in the present work. For that purpose, four different polymers were used: polycaprolactone (PCL), cellulose acetate, MaterBi Z (a commercial starch/polycaprolactone blend) and MaterBi Y (a commercia…

Natural Fiber Reinforced CompositesFiber-reinforced polymer compositesTribology and Wear Analysis

Growth and multiferroic properties of hexagonal HoMnO3 films

J.-W. Kim、L. Schultz、K. Dörr 等 5 位作者2007-01-01Applied Physics Letters

Hexagonal, twin-free HoMnO3 (0001) films of 25–240nm thickness were grown epitaxially on Y2O3:ZrO2(111) substrates using pulsed laser deposition. Ferroelectric polar order and Mn3+ antiferromagnetism were observed by optical second harmonic generation. Magnetization data reveal Ho3+ ordering which is, with subtle devi…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Some β-Amino Alcohols Compounds As Green Volatile Corrosion Inhibitors for Brass

Guo Gao、Chenghao Liang2007-01-01Journal of The Electrochemical Society

Some β-amino alcohols compounds in the series of 1,3-bis-dialkyl aminopropan-2-ols referred to as -apo- , where , 3 and 4, were tested as volatile corrosion inhibitors for brass in simulated atmospheric water using potentiodynamic, potentiostatic current transient, electrochemical impedance spectroscopy, gravimetric,…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisAnodic Oxide Films and Nanostructures

Kinetics of Hexagonal-Body-Centered Cubic Transition in a Triblock Copolymer in a Selective Solvent: Time-Resolved Small-Angle X-ray Scattering Measurements and Model Calculations

Minghai Li、Yongsheng Liu、Huifen Nie 等 5 位作者2007-01-01OpenAlex

ABSTRACT: Time-resolved small-angle X-ray scattering (SAXS) was used to examine the kinetics of the transition from hexagonal (hex) cylinders to body-centered cubic (bcc) spheres at various temperatures in poly(styrene-bethylene-co-butylene-b-styrene) (SEBS) in mineral oil, a selective solvent for the middle ethylene-…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesBlock Copolymer Self-Assembly

Fluorescence Spectra of Colored Diamonds Using A Rapid, Mobile Spectrometer

Sally Eaton‐Magaña、Jeffrey E. Post、Peter J. Heaney 等 6 位作者2007-01-01Gems & Gemology

While a large number of peaks and defect centers have been chronicled in natural diamonds using UV-Vis absorption, cathodoluminescence, and photoluminescence spectroscopy (see, e.g., However, visual assessment of fluorescence and phosphorescence tells only part of the story. The color discerned by the unaided eye may…

High-pressure geophysics and materialsGas Sensing Nanomaterials and SensorsDiamond and Carbon-based Materials Research

Phosphate of Aluminum as Corrosion Inhibitor for Steel in H3PO4

L. Malki Alaoui、S. Kertit、A. Bellaouchou 等 6 位作者2007-01-01Portugaliae electrochimica acta

The influence of phosphate of aluminum (PA) on the corrosion inhibition of mild steel in phosphoric acid solution was studied using the weight-loss method. The electrochemical performance of the inhibitors was also investigated through potentiodynamic polarisation and EIS measurements. The inhibition efficiency of inh…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability