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Laser damage threshold measurements of microstructure-based high reflectors

Douglas S. Hobbs2008-10-08Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

In 2007, the pulsed laser induced damage threshold (LIDT) of anti-reflecting (AR) microstructures built in fused silica and glass was shown to be up to three times greater than the LIDT of single-layer thin-film AR coatings, and at least five times greater than multiple-layer thin-film AR coatings. This result suggest…

Laser Material Processing TechniquesAdvanced Surface Polishing TechniquesOptical Coatings and Gratings

Adsorption Behavior of Dinucleotides on Bare and Ru-Modified Glassy Carbon Electrode Surfaces

Hai–Zhen Wei、Theo G. M. van de Ven、Sasha Omanovic 等 4 位作者2008-10-08Langmuir

The interactive behavior of flavin adenine dinucleotide (FAD) with a bare glassy carbon electrode (GCE) and a Ru-modified GCE was investigated. The reduction of FAD at a GCE/ruthenium-modified GCE surface is a quasi-reversible, surface-controlled process, and our data implied that the attachment of FAD onto the surfac…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Solubility of Bis(benzoxazolyl-2-methyl) Sulfide in Different Pure Solvents and Ethanol + Water Binary Mixtures between (273.25 and 325.25) K

Zu-Shou Yang、Zuoxiang Zeng、Weilan Xue 等 4 位作者2008-10-08Journal of Chemical & Engineering Data

The solubilities of bis(benzoxazolyl-2-methyl) sulfide in ethanol, 1-butanol, 2-propanol, chlorobenzene, toluene, o -xylene, and ethanol + water were measured by a synthetic method. The laser monitoring observation technique was used to determine the disappearance of the solid phase in the solid + liquid mixture. All…

Analytical Chemistry and ChromatographyThermodynamic properties of mixturesCrystallization and Solubility Studies

Synthesis of BaAl 2 S 4 :Eu 2+ Electroluminescent Material by the Polymerizable Complex Method Combined with CS 2 Sulfurization

Valery Petrykin、Masato Kakihana2008-10-08Journal of the American Ceramic Society

Eu‐activated BaAl 2 S 4 (BaAl 2 S 4 :Eu) blue light emission phosphor has attracted considerable attention recently as a prospective material for full color electroluminescent display applications. Although BaAl 2 S 4 :Eu was discovered over 30 years ago, the solid‐state reaction between metal sulfides in sealed quart…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsAmmonia Synthesis and Nitrogen Reduction

Phase-field investigation of effects of surface-tension anisotropy on deterministic sidebranching in solutal dendritic growth

Zhijun Wang、Jincheng Wang、Gencang Yang2008-10-08Physical Review E

Using the phase-field method, effects of the surface-tension anisotropy on sidebranching are investigated during solutal dendritic growth. The results show that without external perturbations the surface tension anisotropy has decisive effects on sidebranching and the nonmonotonic behavior of the solute profile along…

Solidification and crystal growth phenomenaFluid Dynamics and Thin Filmsnanoparticles nucleation surface interactions

Crystal Growth of Ice Ih by Revapor-Deposition and Diffusion Suppression of Monomolecular Water in a Polymer Solid: Spectroscopic Observation of Phase Transition of Water Sorbed into Solid Polystyrene

Makoto Gemmei‐Ide、Hiromi Kitano2008-10-08The Journal of Physical Chemistry B

Monomolecular water in a solid polymer, which has no effective hydrogen bonding sites, was revealed by temperature-variable Fourier transform infrared spectroscopy to be condensable and crystallizable. Ice Ih formed in the polymer matrix was grown by vapor deposition and was reduced by sublimation. Moreover, rapid coo…

Polymer crystallization and propertiesMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Optimization of laser-damage resistance of evaporated hafnia films at 351nm

J. B. Oliver、S. Papernov、Ansgar W. Schmid 等 4 位作者2008-10-08Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A systematic study was undertaken to improve the laser-damage resistance of multilayer high-reflector coatings for use at 351 nm on the OMEGA EP Laser System. A series of hafnium dioxide monolayer films deposited by electron-beam evaporation with varying deposition rates and oxygen backfill pressures were studied usin…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchLaser-induced spectroscopy and plasma

Correlation between conductivity or diffusivity and activation energy in amorphous solids

Manju Sharma、S. Yashonath2008-10-08The Journal of Chemical Physics

There exist many investigations of ionic transport in a variety of glasses. These studies exhibit strong correlation between ionic conductivity and activation energy: Typically, it is found that higher conductivity is associated with lower activation energies and vice versa. Although there are explanations for this at…

Material Dynamics and PropertiesGlass properties and applicationsBuilding materials and conservation

Theoretical Investigation of Water Exchange on the Nanometer-Sized Polyoxocation AlO4Al12(OH)24(H2O)127+ (Keggin-Al13) in Aqueous Solution

Zhaosheng Qian、Hui Feng、Wenjing Yang 等 4 位作者2008-10-08Journal of the American Chemical Society

Reaction pathways, solvent effects and reaction parameters have been investigated for the water exchange on Keggin-Al13 in the aqueous solution by performing supermolecule density functional theory calculations. The calculated results suggest a dissociative (D) mechanism for water exchange on Keggin-Al13 in the aqueou…

Coagulation and Flocculation StudiesIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Hydrothermal Synthesis of Ferroelectric PbHPO4 Nanowires from a Single-Source Precursor

Guangyi Chen、Wengang Qu、Feng Ye 等 5 位作者2008-10-08The Journal of Physical Chemistry C

Ferroelectric PbHPO 4 nanowires have been successfully prepared from a Pb(II)−IP 6 (IP 6, inositol hexakisphosphate acid) complex, a novel single-source precursor, by a hydrothermal method at 180 °C for 24 h. The structure and morphology of the as-prepared PbHPO 4 nanowires and the Pb(II)−IP 6 complex were systematica…

Perovskite Materials and ApplicationsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Alternate Deposition of Oriented Calcite and Amino Acid Layer On Calcite Substrates

Li Qiao、Qingling Feng、Zhuo Li 等 4 位作者2008-10-08The Journal of Physical Chemistry B

Material synthesis inspired by novel nacre architecture and mechanism is popular and has attracted more and more attention. In this paper, iso-oriented calcite tablets/layers and amino acid layers were formed alternately on calcite wafers. It is interesting that the neonatal calcite tablets/layers have the same crysta…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Large scale 3D vertical assembly of single-wall carbon nanotubes at ambient temperatures

Evin Gultepe、Dattatri Nagesha、B. D. F. Casse 等 6 位作者2008-10-08Nanotechnology

We demonstrate three-dimensional directed assembly of single-wall carbon nanotubes (SWNT) into porous alumina nanotemplates on silicon substrates by means of electrophoresis and dielectrophoresis at ambient temperatures. Assembled SWNT provided an interconnection between the surface and base of the nanotemplate. I-V m…

Carbon Nanotubes in CompositesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

COMPARATIVE STUDY OF Ag2O/CO3O4CATALYSTS PREPARED BY THE SOL-GEL AND CO-PRECIPITATION TECHNIQUES: CHARACTERIZATION AND CO ACTIVITY STUDIES

Filiz Balikçi、Saba Buket Yüceer、Çiğdem Güldür2008-10-08Chemical Engineering Communications

In this study effects of the preparation method on the characteristic properties and CO oxidation activities of Ag2O/Co3O4 catalysts were investigated. Catalysts were prepared by two different methods: sol gel and co-precipitation. N2 physisorption measurements, X-ray diffraction, and scanning electron microscopy meas…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Synthesis of Nano‐sized BaTiO 3 Powders by the Rotary‐Hydrothermal Process

Takashi Kubo、Masayuki Hogiri、Hiroshi Kagata 等 4 位作者2008-10-08Journal of the American Ceramic Society

Nano‐sized BaTiO 3 powders with narrow size distribution and high tetragonality were attempted to be synthesized by the rotary‐hydrothermal process in a water system as a novel technique, using a mixture of anatase‐type TiO 2 and Ba(OH) 2 as starting material. The rotary‐hydrothermal syntheses were performed under con…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesElectrophoretic Deposition in Materials Science

Anisotropy of Antiferromagnetic 180° Domains inLiCoPO4andLiNiPO4

Bas B. Van Aken、J.‐P. Rivera、Heinz Schmid 等 4 位作者2008-10-08Physical Review Letters

Unexpected three-dimensional distributions of antiferromagnetic 180 degrees domains are observed in LiCoPO4 and LiNiPO4 by optical second harmonic generation. Domains in LiCoPO4 are isotropic in spite of the quasi-two-dimensional magnetic structure whereas domains in LiNiPO4 are distinctly anisotropic, but in contrast…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

DEVELOPMENT OF SYNERGISTIC HEAT STABILIZERS FOR PVC FROM ZINC BORATE-ZINC PHOSPHATE

Cem Aykut Erdoğdu、Sevdiye Atakul、Devri̇m Balköse 等 4 位作者2008-10-08Chemical Engineering Communications

The importance of flame-retardant and smoke-suppressed poly(vinyl chloride) (PVC) compositions is increasing gradually in the polymer industry since PVC releases smoke and toxic gases (hydrogen chloride, HCl) during heating at temperatures above 140°C with the result of dehydrochlorination reaction. In this study, the…

Polymer Nanocomposites and PropertiesPolymer Science and PVCEnvironmental and Industrial Safety

Fragmentation of an Infinite ZnO2 Square Plane into Discrete [ZnO2]2− Linear Units in the Oxyselenide Ba2ZnO2Ag2Se2

Sebastian J. C. Herkelrath、Ian Saratovsky、Joke Hadermann 等 4 位作者2008-10-08Journal of the American Chemical Society

Analysis of single crystal X-ray diffraction, neutron powder diffraction, electron diffraction and Zn-K-edge EXAFS data show that Ba2ZnO2Ag2Se2 contains unusual isolated [ZnO2]2- moieties resulting from fragmentation of a ZnO2 infinite plane placed under tension.

Advanced Condensed Matter PhysicsIron-based superconductors researchElectronic and Structural Properties of Oxides

Rapid Free Energy Calculation of Peptide Self-Assembly by REMD Umbrella Sampling

Maarten G. Wolf、Jaap A. Jongejan、Jon D. Laman 等 4 位作者2008-10-08The Journal of Physical Chemistry B

We extend umbrella sampling with replica exchange steps to calculate free energies that are important in the self-assembly of peptides. This leads to a more than 10-fold speed up over conventional umbrella sampling, thereby providing a practical method to calculate these free-energy differences. This approach can also…

Protein Structure and DynamicsChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

ORDERING TRANSITIONS IN LIQUID CRYSTALS PERMIT IMAGING OF SPATIAL AND TEMPORAL PATTERNS FORMED BY PROTEINS PENETRATING INTO LIPID-LADEN INTERFACES

Maren Daschner de Tercero、Nicholas L. Abbott2008-10-08Chemical Engineering Communications

Recent studies have reported that full monolayers of L-α-dilaurylphosphatidylcholine (L-DLPC) and D-α-dipalmitoylphosphatidylcholine (D-DPPC) formed at interfaces between thermotropic liquid crystals (LCs) and aqueous phases lead to homeotropic (perpendicular) orientations of nematic LCs and that specific binding of p…

Liquid Crystal Research AdvancementsLipid Membrane Structure and BehaviorMolecular spectroscopy and chirality

Generation and Assembly of Spheroid-like Particles

Tao Deng、James R. Cournoyer、James H. Schermerhorn 等 6 位作者2008-10-08Journal of the American Chemical Society

This paper reports a straightforward approach in generating spheroid-like particles and also the orientational orders observed in the self-assembly of these particles. Nonspherical particles, such as spheroid-like particles, are useful in both fundamental studies and industrial applications due to the geometry impact…

Photonic Crystals and ApplicationsNanomaterials and Printing TechnologiesPickering emulsions and particle stabilization