Materials Literature
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Abstract The transformations of the polymorphic forms of polybutene‐1 (I,II,III) were studied by infrared spectroscopy. Attenuated total reflectance spectra demonstrate that the II → I transformation occurs initially and most rapidly on the film surfaces. Electron irradiation experiments showed the II → I conversion c…
Transmission electron microscope examinations of silicon single crystals, phosphorus-diffused at low temperatures from anodic oxide films as phosphorus sources, showed the presence of crystallographically oriented precipitate. X-ray and electron diffraction investigations of SiP and SiAs single crystals prepared by a…
Summary This paper presents a quantitative interpretation of results of differential thermal analysis of hydration reactions at 2, 12,23 and 52°C of 3CaO.Al 2 O 3 mixed with 0, 0·25, 2·5, 10 or 20% gypsum, and compares these with length changes obtained from the hydration of compacts of these mixtures. Estimates of th…
Abstract Di- and trioctahedral micas were altered to vermiculite-like minerals by extracting the K with sodium tetraphenylboron. Chemical analysis of original and altered micas shows that loss of K is accompanied by an increased loss on ignition, oxidation of some Fe 2+ to Fe 3+ , loss of divalent octahedral cations,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSubstituted Deuteroporphyrins. II. Substituent Effects on Electronic Spectra, Nitrogen Basicities, and Ligand Affinities*Winslow S. Caughey, Wilfred Y. Fujimoto, and Barbara P. JohnsonCite this: Biochemistry 1966, 5, 12, 3830–3843Publication Date (Print):December 1, 1966Publ…
The stimulation of bacterial respiration by clay minerals was related to certain physicochemical characteristics of clays. Respiration increased with an increase in the cation exchange capacity and surface area of the particles. The importance of surface area, however, could not be unequivocally established, as some o…
The complexes formed by ethylene glycol, HOCH 2 .CH 2 OH, and by glycerol, HOCH 2 .CHOH.CH 2 OH, with smectites (montmorillonite-saponite group), and vermiculites have received more attention than any other group of organo-silicate complexes. This interest arose in the first place from their use for identification pur…
The boundaries of regions of glass‐forming compositions were determined in binary tellurite systems with alkali, alkaline‐earth, and heavy‐metal oxides, and in the ternary systems TeO 2 ‐WO 3 ‐Ta 2 O 5 , TeO 2 ‐WO 3 ‐BaO, TeO 2 ‐WO 3 ‐Bi 2 O 3 , and TeO 2 ‐WO 3 ‐Tl 2 O. On the basis of a structural interpretation of l…
We consider an M×N periodic system of hard squares each of which prohibits the occupation of its nearest-neighbor sites by the other squares. An appropriate unitary transformation factors the matrix required in evaluating the grand canonical partition function into a direct sum of submatrices. Each submatrix belongs t…
Abstract Thin films of phthalocyanine compounds formed on cleaved surfaces of muscovite by the vacuum-condensation method showed well-defined single-directional orientation when their substrates were preheated at 300°C for one hour and then kept at 150°C. Their electron diffraction patterns were fiber diagrams, the fi…
Abstract Polymerization of methyl methacrylate with Grignard reagents in mixed solvent of toluene and dimethyl sulfoxide (DMSO) under ultrasonic irradiation was carried out, and the effects of ultrasonic irradiation in connection with the mixed solvent on the stereoregularity and the properties of the polymers obtaine…
Abstract Decomposition of organic matter within shell fragments appears to result in the formation of localized reducing environments. This has led to the development of pyrite within the shell. This pyrite may indicate relic shell structure and thus show that the aragonite of the shell changed to calcite without a di…
Abstract The glass transitions of an ionic polymer in bulk have been studied as a function of the counterion for various homo‐ and copolymers. It is shown that the glass transition temperature can vary by as much as 530°C., from −10°C. for the nonionic material to +520 for Ca 2+ or Zn 2+ substituted polymer. From simp…
A magnetometric demagnetization tensor is defined for uniformly-magnetized samples of arbitrary geometry. It is shown that this is a real symmetric tensor with non-negative diagonal elements and unit trace. Diagonalization of the magnetometric demagnetization tensor yields the Brown-Morrish equivalent ellipsoid and th…
The decomposition of brucite was studied directly in electron and optical microscopes. A small amount of decomposition caused marked changes in the physical state of the brucite crystal. The decomposition was interpreted as a normal nucleation and growth process in which magnesium oxide nuclei formed coherently with t…
The solid solution limit of titanium dioxide in Al 2 O 3 was investigated using diffuse reflectance and cathodoluminescence measurements on polycrystalline Al 2 O 3 doped with 1.0 mole % or less TiO 2 . The samples had been fired in air at 1300°C. The diffuse reflectance spectra indicated that the solid solubility lim…
The dielectric properties of ice have been studied up to 107 kbar using opposed circular anvils. Ice VII undergoes orientational polarization, and consequently its molecules are orientationally disordered. The volume of activation for the relaxation of the orientational polarization is ∼3 cm3 mole−1, which suggests th…
A new method was developed for determining the dynamic stress-strain relationships of materials subjected to high rate of torsional loading. In addition, an investigation of propagation of torsional plastic waves in a long tube was conducted. Commercially pure copper was used throughout both investigations. In the mat…
Abstract Dye molecules containing two or more polymethine structural units, or at least one polymethine and one polyene structural unit, generally exhibit coupling effects that determine the spectroscopic behavior and other physicochemical properties of the substance. The coupling concept can be used inter alia to fit…
Following a suggestion by Kingery and Francois, the theory of grain growth in porous compacts controlled by the migration of pores with the boundaries is developed for all possible transport processes. Contrary to the assumption of these authors, it is shown that the cubic rate law reported for both UO2 and Al2O3 comp…