Materials Literature
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A theoretical analysis is made of crystal stability and of low-temperature deviations from the Cauchy relations between elastic constants of ionic crystals with $\mathrm{AX}$ composition and with cubic or hexagonal structure. The Born-Mayer model is used as a basis, extended to take into account short-range three-ion…
A general expression for the electric field gradient (EFG) at the positive ion nucleus in an ionic crystal with polyatomic negative ions has been derived in the frameworks of the LCAO–MO approximation and the multipole expansion theorem of the electrostatic potential. The contribution to the field gradient in the pres…
Cadmium pyrophosphate forms crystals having triclinic symmetry with the unit cell parameters a = 6.672(8) Å, b = 6.623(8) Å, c = 6.858(7) Å, α = 95.80(10)°, β = 115.38(8)°, and γ = 82.38(8)°. The space group is [Formula: see text] and there are two molecules per unit cell. The structure was refined by least squares me…
Measurements of acoustic attenuation in SrTi${\mathrm{O}}_{3}$ reveal critical scattering behavior near the structural phase transition at ${T}_{a}\ensuremath{\cong}105$ K. Power laws for the frequency and temperature dependences have been found. By these measurements the behavior of the soft mode frequencies could be…
The hydrostatic-pressure dependence of the electronic properties of V${\mathrm{O}}_{2}$ near the semiconductor-metal transition to a pressure of 40 kbar is described. The temperature dependence of the V${\mathrm{O}}_{2}$ resistivity from 0\ifmmode^\circ\else\textdegree\fi{}C through the semiconductor-metal transition…
The absorption spectrum of Pr3+ in LaF3, LaCl3, CaF2, Pr(Y)Cl3·6H2O, and Pr2(SO4)3·8H2O was investigated. Evidence for the S01 level in Pr3+:LaF3 at 46 986 cm−1 is presented; this level was not observed directly in absorption in any of the other matrices studied. An analysis of the 13 observed levels in Pr3+:LaF3, bas…
The specific heats of $n$-type bismuth telluride with carrier concentrations ranging between 2.2\ifmmode\times\else\texttimes\fi{}${10}^{18}$ and 8.3\ifmmode\times\else\texttimes\fi{}${10}^{20}$ ${\mathrm{cm}}^{\ensuremath{-}3}$, $p$-type ${\mathrm{Bi}}_{2}$${\mathrm{Te}}_{3}$ with a carrier concentration of 1.3\ifmmo…
Intramolecular energy transfer in lanthanide chelates can occur through different paths depending on the nature of the chelate. Contrary to prevailing notions, it is shown that energy transfer does not require the participation of the lowest triplet level of the chelate. The experimental results from a study of soluti…
Optical, thermal, magnetic, and transport properties of V${\mathrm{O}}_{2}$ in the vicinity of the semiconductor-metal transition temperature of 68\ifmmode^\circ\else\textdegree\fi{}C are discussed in terms of a simple one-electron band picture. Particular emphasis is placed on the variation in these properties from s…
Luminescent transitions at divalent copper impurities in ZnO give rise to a close-spaced, no-phonon doublet at \ensuremath{\sim}2.8590 eV, as well as a broad multiphonon side band. The transition is found to be an optical charge transfer between a highly shielded localized level of the copper impurity and a level whic…
Hydrocalcite (CaCO(3) * H(2)O) with exactly one molecule of hydrate water is the main component of carbonate scales deposited from cold water in contact with air. When the magnesium content of the water is high, the hydrocalcite occurs together with MgCO(3) * 3H(2)O (nesquehonite). From the conditions under which hydr…
Abstract Solid–liquid interfacial free energy is shown to be highly anisotropic in alloys of some h. c. p. metals and of two metalloids. This anisotropy is evaluated from a study of the equilibrium shapes of small droplets of alloy liquid entrained within solid grains. Factors affecting the attainment of equilibrium i…
Kin-ichi Sakurai, Hisanobu Wakita, Akira Kato, Kozo Nagashima; Chemical Studies of Minerals Containing Rarer Elements from the Far East. LXIII. Bastnaesite
Abstract The reactions of peroxides with polymers have been studied for some time. They form an extensive part of vulcanization technology. Two types of reactions are generally recognized, those leading to crosslinking between polymer chains and those leading to scission of the chains. Natural rubber, polybutadiene an…
Mechanical properties of single crystals of niobium have been measured in the strain-rate range 103-104 see−1 where flow is thermally activated and is probably controlled by the Peierls stress. Dislocation configurations and densities have been measured as a function of strain at strain rates of 6·5 × 103 sec−1 and 2·…
Phase equilibria were determined by standard quench methods in binary systems NIO‐B 2 O 3 , the binary join Li 2 O.B 2 O 3 ‐NiO, and three other sections through the Li 2 O.B 2 O 3 ‐B 2 O 3 ‐NiO system. The only new compound observed was 2NiO.B 2 O 3 , which is stable from 1303° to 1480°C.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymeric Schiff BasesJ. H. Hodgkin and J. HellerCite this: Macromolecules 1969, 2, 5, 556–558Publication Date (Print):September 1, 1969Publication History Published online1 May 2002Published inissue 1 September 1969https://pubs.acs.org/doi/10.1021/ma60011a023https://doi.org…
The ac magnetostriction of transformer sheet has been measured with longitudinal compression up to 2000 lbf/in2(13 800 kN.m-2). Longitudinal stress causes a sudden increase in magnetostriction, while normal stress smooths out the steplike change. Si-Fe sheet from three different manufacturers is shown to have widely v…
Following the suggestion of Scaife that the complex polarizability data ought to be used for comparing dielectric dispersion data, we constructed the mechanical analogue of the complex polarizability. The parameters used to represent the relaxation data of poly( n -hexyl methacrylate) in the two forms were determined.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular structure of diazulenetetrairon decacarbonyl in crystalline (C10H8)2Fe4(CO)10.C2H4Cl2Melvyn R. Churchill and Peter H. BirdCite this: Inorg. Chem. 1969, 8, 9, 1941–1949Publication Date (Print):September 1, 1969Publication History Published online1 May 2002Published…