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An electron spin-lattice relaxation mechanism involving tunneling modes for trapped radicals in glassy matrixes. Theoretical development and application to trapped electrons in .gamma.-irradiated ethanol glasses

Michael K. Bowman、Larry Kevan1977-03-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn electron spin-lattice relaxation mechanism involving tunneling modes for trapped radicals in glassy matrixes. Theoretical development and application to trapped electrons in .gamma.-irradiated ethanol glassesMichael K. Bowman and Larry KevanCite this: J. Phys. Chem. 1977,…

Glass properties and applicationsPhotochemistry and Electron Transfer StudiesPhase-change materials and chalcogenides

Verfeinerung der Struktur von Malachit, Cu2(OH)2CO3, durch Neutronenbeugung

作者信息未提供1977-03-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The crystal structure of malachite is refined ( R = 0.021) with the intensity values of 635 independent neutron reflexions from a single crystal, rather free from absorption and extinction. Concerning the structural geometry, no essential deviations occur from the known results of x-ray diffraction. The therm…

Cultural Heritage Materials AnalysisChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Metal-metal bond cleavage reactions. The crystallization and solid state structural characterization of cadmium tetracarbonyliron, CdFe(CO)4

Richard D. Ernst、Tobin J. Marks、James A. Ibers1977-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal-metal bond cleavage reactions. The crystallization and solid state structural characterization of cadmium tetracarbonyliron, CdFe(CO)4Richard D. Ernst, Tobin J. Marks, and James A. IbersCite this: J. Am. Chem. Soc. 1977, 99, 7, 2090–2098Publication Date (Print):March 1…

Catalytic Processes in Materials ScienceIonic liquids properties and applicationsCatalysis and Oxidation Reactions

Fatigue crack propagation in poly(methyl methacrylate): Effect of molecular weight and internal plasticization

S. L. Kim、M. D. Skibo、J. A. Manson 等 4 位作者1977-03-01Polymer Engineering and Science

Abstract In spite of the importance of fatigue behavior in engineering plastics, relatively few fundamental studies have been made of the effects of polymer structure, molecular weight, composition, and morphology on fatigue crack propagation (FCP). As, part of a broad program for the study of such effects, the role o…

Polymer crystallization and propertiesFatigue and fracture mechanicsOrthopaedic implants and arthroplasty

Decomposition and ordering in Fe1−xO

Bengt Andersson、J. O. Sletnes1977-03-01Acta Crystallographica Section A

Samples in the composition range Fe0.95O-Fe0.88O quenched from about 1000°C, have been studied by electron diffraction/microscopy with special emphasis on the dark-field technique. The set of morphologies obtained by quenching and annealing confirms a spinodal-like decomposition in an oxygen-rich and an almost stoichi…

Microstructure and mechanical propertiesMagnetic Properties and ApplicationsIron oxide chemistry and applications

Unified Landau theory for the nematic, smecticA, and smecticCphases of liquid crystals

Kuo‐Chung Chu、W. L. McMillan1977-03-01Physical Review A

A unified Landau theory is introduced for the nematic, smectic $A$, and smectic $C$ phases using the director $\stackrel{\ensuremath{\rightarrow}}{\mathrm{n}}$ for the nematic order parameter, the complex order parameter $\ensuremath{\psi}$ for the smectic planes, and the vector $\stackrel{\ensuremath{\rightarrow}}{\e…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

(Acetylacetonato)[(-)-N-alkylephedrinato]dioxomolybdenum, a new class of chiral chelate complexes which catalyze asymmetric epoxidation of allylic alcohol

Shunichi Yamada、T. Mashiko、Shiro Terashima1977-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT(Acetylacetonato)[(-)-N-alkylephedrinato]dioxomolybdenum, a new class of chiral chelate complexes which catalyze asymmetric epoxidation of allylic alcoholShunichi Yamada, Toshio Mashiko, and Shiro TerashimaCite this: J. Am. Chem. Soc. 1977, 99, 6, 1988–1990Publication Date (…

Metal complexes synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsMetal-Catalyzed Oxygenation Mechanisms

Sulphonated polystyrene as an optimal substratum for the adhesion and spreading of mesenchymal cells in monovalent and divalent saline solutions

N.G. Maroudas1977-03-01Journal of Cellular Physiology

Cell adhesion and spreading were studied on sulphonated polystyrene dishes in serum-free saline (Mn, Na, Cl, buffer) i.e., without an intervening protein layer. Spreading as a function of surface charge density, SCD, peaked around 2-10 negative charges per square nanometer, corresponding to a monomolecular layer of su…

Cellular Mechanics and InteractionsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Historical Developments in Soil Chemistry: Ion Exchange

G. W. Thomas1977-03-01Soil Science Society of America Journal

Abstract The early development of ideas on cation exchange from 1850 to 1900 is described. From 1900 to the present, the coverage has been divided as the work has concentrated on soil acidity, alkali soils, and classical cation exchange studies. The discovery of crystallinity in soil clays and the rediscovery of the i…

Soil and Unsaturated FlowSpectroscopy and Quantum Chemical StudiesClay minerals and soil interactions

Study of oxygen isotopic exchange over ultraviolet irradiated anatase samples and comparison with the photooxidation of isobutane into acetone

Henri Courbon、M. Formenti、Pierre Pichat1977-03-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of oxygen isotopic exchange over ultraviolet irradiated anatase samples and comparison with the photooxidation of isobutane into acetoneHenri Courbon, Marc Formenti, and Pierre PichatCite this: J. Phys. Chem. 1977, 81, 6, 550–554Publication Date (Print):March 1, 1977Pu…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceArsenic contamination and mitigation

Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Solutions. 2. Quantitative Estimation of the Interfacial Thickness of Lamellar Microphase Systems

Takeji Hashimoto、Akira Todo、Hideyuki Itoi 等 4 位作者1977-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDomain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Solutions. 2. Quantitative Estimation of the Interfacial Thickness of Lamellar Microphase SystemsTakeji Hashimoto, Akira Todo, Hideyuki Itoi, and Hiromichi KawaiCite this: Macromolecules 1977, 10,…

Advanced Polymer Synthesis and CharacterizationModel Reduction and Neural NetworksBlock Copolymer Self-Assembly

Temperature Dependence of Hydrogen Bonding in Toluene Diisocyanate Based Polyurethanes

C. S. P. Sung、N. S. Schneider1977-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemperature Dependence of Hydrogen Bonding in Toluene Diisocyanate Based PolyurethanesC.S. Paik Sung and N S SchneiderCite this: Macromolecules 1977, 10, 2, 452–458Publication Date (Print):March 1, 1977Publication History Published online1 May 2002Published inissue 1 March 1…

Corrosion Behavior and InhibitionPolymer composites and self-healingBuilding materials and conservation

ADSORPTION ON HYDROUS OXIDES: II. OXALATE, BENZOATE AND PHOSPHATE ON GIBBSITE

Rhys Parfitt、A. R. Fraser、James Russell 等 4 位作者1977-03-01Journal of Soil Science

Summary Adsorption isotherms, the infrared spectra of adsorbed species, and the amount of hydroxyl released when oxalate is adsorbed, all indicate that adsorption of oxalate, benzoate and phosphate at low solution concentrations occurs only on A1(OH)(H 2 O) sites exposed on edge faces of the platy gibbsite crystals st…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMine drainage and remediation techniques

Analysis of Adhesively Bonded Joints Between Panels of Composite Materials

W. J. Renton、Jack R. Vinson1977-03-01Journal of Applied Mechanics

A mathematical model is developed and methods of analysis are formulated for determining the structural response of the single-lap and symmetric-lap joints composed of generally orthotropic material systems. Analytical results are compared in both instances with experimental data and excellent correlation is seen to e…

Mechanical Behavior of CompositesStructural Analysis of Composite MaterialsMaterial Properties and Applications

Stable heptamethine pyrylium dyes that absorb in the infrared

G. A. Reynolds、K. H. Drexhage1977-03-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStable heptamethine pyrylium dyes that absorb in the infraredG. A. Reynolds and K. H. DrexhageCite this: J. Org. Chem. 1977, 42, 5, 885–888Publication Date (Print):March 1, 1977Publication History Published online1 May 2002Published inissue 1 March 1977https://pubs.acs.org/d…

Photochromic and Fluorescence Chemistry

Mechanical properties of mixtures of two compatible polymers

Albert F. Yee1977-03-01Polymer Engineering and Science

Abstract The properties of mixtures of poly(2, 6‐dimethyl p‐phenylene oxide) and poly(styrene) have been measured by DSC, density gradient, dynamic mechanical response, and tensile testing. The mixtures are found to have single glass trasitions that vary continuously with the composition. They also have small negative…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

On the crystal structure of nylon 6

James P. Parker、P. H. Lindenmeyer1977-03-01Journal of Applied Polymer Science

Abstract Nylon 6 can exist in either of two stable crystal structures, the α crystal with hydrogen bonds between antiparallel chains or the γ crystal with hydrogen bonds between parallel chains. Both structures have been observed in the same highly annealed fiber, suggesting that the polymer should not be regarded as…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Preparation, Characterization, and Properties of Dy‐Doped Small‐Grained BaTiO 3 Ceramics

Akihiko Yamaji、Yoichi Enomoto、Kyôichi Kinoshita 等 4 位作者1977-03-01Journal of the American Ceramic Society

The effects of Dy doping and sintering parameters on the properties of BaTiO 3 ceramics were studied. The average grain size decreases with increasing Dy content and is controlled at ∼1.5 μ m by 0.8 at.% Dy. The Curie temperature change, associated with ≤1.2 at.% Dy, is <3°C. The dielectric constant is ∼2600 for sp…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsDielectric materials and actuators

Photodegradation of cellulose acetate fibers

Nyok‐Sai Hon1977-03-01Journal of Polymer Science Polymer Chemistry Edition

Abstract The photodegradation of cellulose acetate fibers by ultraviolet light in vacuo at 77°K and at ambient temperature was studied. Three kinds of light sources with different wavelengths between 2353 and 6000 Å were employed. ESR studies at 77°K show that several kinds of free radicals are produced from cellulose…

Advanced Cellulose Research StudiesLignin and Wood ChemistryMaterial Properties and Processing

Impact Abrasion of Harder by Softer Materials

R. V. Dietrich1977-03-01The Journal of Geology

Fluorite, halite, periclase, and sylvite have been abraded in a wind tunnel by windblown dust from the "normal" air of the intake room plus or minus introduced silt-sized particles of calcite, barite, or snow. The results indicate that the effective kinetic energy of a projectile and the bond strength of the target-ra…

High-Velocity Impact and Material BehaviorParticle Dynamics in Fluid FlowsEngineering and Material Science Research