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Spatial and Temporal Oscillation at Si(111) Electrodes in Aqueous Fluoride-Containing Solution

H. J. Lewerenz1997-04-01The Journal of Physical Chemistry B

The oscillatory behavior of single crystalline n-Si(111) in dilute ammonium and sodium fluoride solutions is investigated. Simultaneous in-situ Fourier transform infrared analyses performed in the multiple internal reflection (FTIR-MIR) mode and photocurrent measurements show a pronounced variation in the integrated S…

Force Microscopy Techniques and ApplicationsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

CP/MAS 13C NMR Spectra of Frozen Solutions of Poly(vinyl alcohol) with Different Tacticities

Fumitaka Horii、Kenji Masuda、Hironori Kaji1997-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTCP/MAS 13C NMR Spectra of Frozen Solutions of Poly(vinyl alcohol) with Different TacticitiesFumitaka Horii, Kenji Masuda, and Hironori KajiView Author Information Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Ja…

Conducting polymers and applicationsLanthanide and Transition Metal ComplexesNMR spectroscopy and applications

Thermal and Photodegradation of Photochromic Spiroindolinenaphthooxazines and -pyrans: Reaction with Nucleophiles. Trapping of the Merocyanine Zwitterionic Form

V. Malatesta、C. Neri、M. L. Wis 等 5 位作者1997-04-01Journal of the American Chemical Society

Adducts of the zwitterionic (ZW) form of merocyanine (MC) of five photochromic spirooxazines (SO) and spiropyrans (SP) have, for the first time, been prepared photochemically or thermally through a trapping reaction of metastable MC with trimethylsilyl cyanide (TMSCN) in dichloromethane. The adducts (ZWAs) form easily…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryOrganic Chemistry Cycloaddition Reactions

Surfacevs. Bulk Chemistry of Pyrolytic Carbon Blacks by SIMS and Raman Spectroscopy

Hans Darmstadt、L. Sümmchen、Ulf Roland 等 6 位作者1997-04-01Surface and Interface Analysis

The chemical nature, especially with respect to the surface, of carbon blacks obtained by pyrolysis of used tyres (CBP) is very important for their use as reinforcing filler in rubbers. Both SIMS and Raman spectroscopy were used to investigate the surface and bulk chemistry of CBP obtained by vacuum pyrolysis of used…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Metamagnetic Behavior of the Novel Bimetallic Ferromagnetic Chain Compound MnNi(NO2)4(en)2 (en = Ethylenediamine)

Olivier Kahn、Evangelos G. Bakalbassis、Corine Mathonière 等 6 位作者1997-04-01Inorganic Chemistry

The self-assembling of the [Ni(NO2)2(en)2], Mn(II), and NO2- constituents affords the bimetallic chain compound MnNi(NO2)4(en)2. The Mn(II)−Ni(II) intrachain interaction is ferromagnetic, and the compound is a metamagnet with a critical field 1.2 kOe. The magnetic properties were interpreted quantitatively, using a cl…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Orientation Anisotropy of the Mechanical α Relaxation of High-Density Polyethylene Films Having a Well-Defined Stacked Lamellar Morphology

Hongyi Zhou、Garth L. Wilkes1997-04-01Macromolecules

Dynamic mechanical experiments were conducted on melt-extruded uniaxially oriented high- density polyethylene films having a well-defined stacked lamellar morphology. Samples were cut at different angles with respect to the original machine direction (MD) and tested by increasing the temperature from 20 to 130 °C at a…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Augmentation of skull bone using a bioresorbable barrier supported by autologous bone grafts. An intra‐individual study in the rabbit.

AnnaKarin Lundgren、Jens Lundgren、Lars Sennerby 等 6 位作者1997-04-01Clinical Oral Implants Research

The aim of this experimental investigation was to compare the effect of using autologous particulate bone grafts with and without a bioresorbable barrier covering for augmentation of the rabbit skull bone. For this purpose, bilateral, circular, 8 mm wide and 1 mm deep skull bone defects were prepared and overfilled wi…

Dental Implant Techniques and OutcomesElectrospun Nanofibers in Biomedical ApplicationsPeriodontal Regeneration and Treatments

Combined Type Liquid Crystalline Polymers Composed of Poly(p-phenylene terephthalate) Main Chain and Azobenzene Mesogenic Side Groups Attached through Polymethylene Spacers

Xiang Lin Piao、Jongseong Kim、Yong‐Kuk Yun 等 5 位作者1997-04-01Macromolecules

A series of combined main chain−side group thermotropic polyesters having varying lengths of oxypolymethyleneoxy spacers between the aromatic polyester main chain and the side azobenzene mesogenic unit have been synthesized and their liquid crystalline properties have been investigated. The thermal and liquid crystall…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsSynthesis and properties of polymers

High‐Temperature Environmental Stability of the Compounds in the Al 2 O 3 –Y 2 O 3 System

T. Mah、Kristin A. Keller、Sankar Sambasivan 等 4 位作者1997-04-01Journal of the American Ceramic Society

Heat treatments in several environments were performed on a series of compounds in the Al 2 O 3 and Y 2 O 3 system: Al 2 O 3 Y 3 Al 5 O 12 eutectic, Y 3 Al 5 O 12 , YAlO 3 , Y 4 Al 2 O 9 , and Y 2 O 3 . The yttrium aluminates were found to be stable at high temperatures under vacuum and in air. However, when they were…

Advanced ceramic materials synthesisHigh-Temperature Coating BehaviorsNuclear materials and radiation effects

Simulating the Mechanical Properties of a Yarn Based on the Properties and Arrangement of its Fibers Part I: The Finite Element Model

Lieva Van Langenhove1997-04-01Textile Research Journal

A theoretical model is established to predict stress-strain and torque-tensile strain curves of a yarn. The yarn is described by its properties and the arrangement of its fibers, which have a finite length. The yarn is transformed into finite elements. Equilibrium is expressed by virtual work, and is calculated iterat…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Generalized Landau–de Gennes theory of uniaxial and biaxial nematic liquid crystals

M. C. J. M. Vissenberg、Sjoerd Stallinga、G. Vertogen1997-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The generalized Landau--de Gennes theory for uniaxial and biaxial nematic liquid crystals is analyzed using tensor analysis. In this way all terms allowed by symmetry appear in the free-energy expression. This improves the quantitative shortcomings of the commonly used theory. It appears that uniaxial nematic liquid c…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Materials and Mechanics

Study of copper precipitates in α-iron by computer simulation

Yu.N. Osetsky、A. Serra1997-04-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

The evolution of a copper precipitate with a diameter of 3·5 nm containing up to 2·0 at.% of vacancies at different temperatures has been studied by molecular dynamics. The diffusion coefficients were calculated for a single vacancy and vacancy concentrations inside the precipitate of 0·5, 1·0 and 2·0 at.%. The diffus…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgical Processes and Thermodynamics

Analysis of the intrinsic magnetic properties ofR2Fe17single crystals (R=Y,nDy,nHo,nEr)

B. Garcı́a-Landa、P. A. Algarabel、M. R. Ibarra 等 5 位作者1997-04-01Physical review. B, Condensed matter

The magnetic behavior of some ${\mathrm{R}}_{2}$${\mathrm{Fe}}_{17}$ single crystals have been analyzed quantitatively in a wide temperature range, using a two-sublattice approximation for the magnetic structure and taking into account isotropic exchange and single-ion crystal-field interactions. The 3d sublattice beh…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Preparation of WNx Films and Their Diffusion Barrier Properties in Cu/Si Contact Systems

Mayumi Takeyama Mayumi Takeyama、Atsushi Noya1997-04-01Japanese Journal of Applied Physics

We prepared thin WN x films with various compositions by reactive sputtering and examined their characterizations and barrier properties applied to Cu/WN x /Si contact systems. The results indicate that the W 65 N 35 barrier, which is in the W 2 N phase with preferred orientation in the (111) plane, shows excellent ba…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Protein-tyrosine phosphorylation in the Archaea

S C Smith、Peter J. Kennelly、Malcolm Potts1997-04-01Journal of Bacteriology

Sulfolobus sulfataricus ATCC 35091, Haloferax volcanii, and Methanosarcina thermophila TM-1, representing the Euryarchaeota and Crenarchaeota subdomains of the Archaea, contain proteins which are phosphorylated on tyrosine. These data raise fundamental questions as to the origin and evolution of tyrosine phosphorylati…

RNA and protein synthesis mechanismsGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Misfit accommodation mechanisms at moving reaction fronts during topotaxial spinel-forming thin-film solid-state reactions: A high-resolution transmission electron microscopy study of five spinels of different misfits

H. Sieber、D. Heß、P. Werner1997-04-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Thin films of five different spinels MgAl2O4, MgCr2O4, MgIn2O4, TiMg2O4 and MgFe2O4 were grown by topotaxial solid state reactions on MgO(001) substrates. The spinels widely differed in their lattice parameter resulting in a variation in sign and amount of lattice misfit to the substrate. The films were characterized…

Advanced ceramic materials synthesisMagnetic Properties and Synthesis of FerritesMicrowave Dielectric Ceramics Synthesis

Synthesis of Aromatic Polyisophthalamides by in Situ Silylation of Aromatic Diamines

Ángel E. Lozano、Javier de Abajo、José G. de la Campa1997-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSynthesis of Aromatic Polyisophthalamides by in Situ Silylation of Aromatic Diamines†Angel E. Lozano, Javier de Abajo, and José G. de la CampaView Author Information Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Juan de la Cierva 3, 28006 Madrid, SpainCite this: Macr…

Synthesis and characterization of novel inorganic/organometallic compoundsSynthesis and properties of polymersCoordination Chemistry and Organometallics

Broadband high-reflection multilayer coatings at oblique angles of incidence

К. В. Попов、J. A. Dobrowolski、Alexander V. Tikhonravov 等 4 位作者1997-04-01Applied Optics

The angular properties of various wideband high reflectors are investigated. The theory is developed for the design of high reflectors based on contiguous quarter-wave stacks for use at one oblique angle or for a range of angles of incidence. Numerical results are presented for several high reflectors designed to have…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

The Promoter of the Gene Encoding the C 4 Form of Phosphoenolpyruvate Carboxylase Directs Mesophyll-Specific Expression in Transgenic C 4 Flaveria spp

Jörg Stockhaus、Ute Schlue、Maria Koczor 等 6 位作者1997-04-01The Plant Cell

, Ute Schlue, Maria Koczor, Julie A. Chitty, William C. Taylor, Peter Westhoff, The Promoter of the Gene Encoding the C₄ Form of Phosphoenolpyruvate Carboxylase Directs Mesophyll-Specific Expression in Transgenic C₄ Flaveria spp, The Plant Cell, Vol. 9, No. 4 (Apr., 1997), pp. 479-489

Calcium Carbonate Crystallization and Inhibition

Dynamics of domain walls in an incommensurate phase near the lock-in transition:One-dimensional crystal model

Vladimir Dmitriev、Takeshi Shigenari、A. A. Vasiliev 等 4 位作者1997-04-01Physical review. B, Condensed matter

A phase transition from a high-symmetry to a low-symmetry commensurate phase through an incommensurate phase was studied in the framework of the one-dimensional elastically hinged molecule model which includes only a fourth-order anharmonic potential. The phase diagram with respect to the harmonic-potential coefficien…

High-pressure geophysics and materialsSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure