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A theoretical investigation of molecular core binding and relaxation energies in a series of oxygen‐containing organic molecules of interest in the study of surface oxidation of polymers

David Clark、Benjamin J. Cromarty、A. Dilks1978-12-01Journal of Polymer Science Polymer Chemistry Edition

Abstract Nonempirical LCAO MO SCF computations (in the ΔSCF formalism) have been carried out of binding energies and relaxation energies for an extensive series of oxygen‐containing organic systems encompassing most of the common functionalities. The molecules for which experimental data are available for comparison d…

Free Radicals and AntioxidantsNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Electron paramagnetic resonance of low-spin cobalt(II) complexes: effect of axial ligation upon the ground state

Abbas Pezeshk、Frederick T. Greenaway、Gershon Vincow1978-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron paramagnetic resonance of low-spin cobalt(II) complexes: effect of axial ligation upon the ground stateAbbas Pezeshk, Frederick T. Greenaway, and Gershon VincowCite this: Inorg. Chem. 1978, 17, 12, 3421–3425Publication Date (Print):December 1, 1978Publication Histor…

Magnetism in coordination complexesMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry

Effect of Alternating Current on Corrosion of Low Alloy and Carbon Steels

D. A. Jones1978-12-01CORROSION

The corrosion rates of low alloy steel and carbon steel in 0.1 N NaCl were accelerated by factors of 4 to 6 when an alternating current density of 30 mA/cm2 (60 cps) was applied in dilute salt solutions purged with nitrogen. Tests with low frequency alternating anodic and cathodic current showed that both steels polar…

Non-Destructive Testing TechniquesHydrogen embrittlement and corrosion behaviors in metalsCorrosion Behavior and Inhibition

Characterization of binuclear .mu.-peroxo and .mu.-superoxo cobalt(III) amine complexes from Raman spectroscopy

C. G. Barraclough、Geoffrey A. Lawrance、Peter A. Lay1978-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCharacterization of binuclear .mu.-peroxo and .mu.-superoxo cobalt(III) amine complexes from Raman spectroscopyColin G. Barraclough, Geoffrey A. Lawrance, and Peter A. LayCite this: Inorg. Chem. 1978, 17, 12, 3317–3322Publication Date (Print):December 1, 1978Publication Hist…

Electrochemical Analysis and ApplicationsCorrosion Behavior and InhibitionMetal complexes synthesis and properties

Activation of Carbon Dioxide by Tetraphenylporphinatoaluminium Methoxide. Reaction with Epoxide

Norikazu Takeda、Shohei Inoue1978-12-01Bulletin of the Chemical Society of Japan

Abstract α,β,γ,δ-Tetraphenylporphinatoaluminium methoxide reacts reversibly with carbon dioxide in the presence of 1-methylimidazole, and this carbon dioxide is activated to react with propylene oxide to produce propylene carbonate under atmospheric pressure and at room temperature.

Luminescence and Fluorescent MaterialsPorphyrin and Phthalocyanine ChemistryCovalent Organic Framework Applications

Magnetoferroelectricity in Cr2BeO4

Robert E. Newnham、John Kramer、Walter A. Schulze 等 4 位作者1978-12-01Journal of Applied Physics

Chromium chrysoberyl undergoes a phase transformation from a paramagnetic state to a complex antiferromagnetic state at 28 K. The spiral spin structure of the antiferromagnetic state violates all the crystallographic symmetry elements, making Cr2BeO4 potentially ferroelectric. Chynoweth experiments conducted at low te…

Glass properties and applicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Influence of manufacturing variables on the characteristics and effectiveness of chitosan products. I. Chemical composition, viscosity, and molecular‐weight distribution of chitosan products

Wayne A. Bough、W. L. Salter、A. C. M. Wu 等 4 位作者1978-12-01Biotechnology and Bioengineering

Abstract Ten chitosan products were manufactured from dry shrimp hulls under differing process conditions and compared to a commercially available product. Manufacturing variables tested were: alkali versus enzymatic deproteination; acid demineralization versus no treatment; air versus nitrogen atmosphere; 5 min vs. 1…

Aquaculture Nutrition and GrowthMicroplastics and Plastic PollutionNanocomposite Films for Food Packaging

Secondary electron emission from insulators

K. Kanaya、Susumu Ono、Fumiko Ishigaki1978-12-01Journal of Physics D Applied Physics

The high yield of secondary electron emission from insulators due to electron bombardment may be the result of an increase of the depth of escape. The free-electron scattering theory is applied to the high energy of the primary beam, but it cannot be applied to the low energy of the secondary escaping beam because of…

X-ray Spectroscopy and Fluorescence AnalysisPlasma Diagnostics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Flatband Potential of Cadmium Sulfide ( CdS ) Photoanodes and Its Dependence on Surface Ion Effects

David S. Ginley、M. A. Butler1978-12-01Journal of The Electrochemical Society

Results are presented which show that the flatband potential ( V fb ) of a semiconducting cadmium sulfide ( CdS ) photoanode can be predicted from atomic electronegativity of its constituent atoms. This procedure, previously applied only to metal oxides, now appears generally applicable to any semiconductor‐electrolyt…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsElectrochemical Analysis and Applications

Effect of Cracks on Thermal Conductivity

D. P. H. Hasselman1978-12-01Journal of Composite Materials

Expressions are derived for the effect of penny-shaped cracks of various orientations on the thermal conductivity of solid materials.

Advanced ceramic materials synthesisComposite Material MechanicsThermal properties of materials

Crystal structures of sodium sulfate decahydrate (Glauber's salt) and sodium tetraborate decahydrate (borax). Redetermination by neutron diffraction

H. A. Levy、George C. Lisensky1978-12-01Acta Crystallographica Section B

Single-crystal neutron-diffraction data with full-matrix least-squares refinements have yielded precise locations for all atoms (for the H atoms in particular), in both compounds. Hydrogen bonding with H atom sites disordered with equal occupancy, as previously postulated to be the source of zero-point entropy in the…

Solid-state spectroscopy and crystallographyCrystallography and molecular interactionsX-ray Diffraction in Crystallography

An improved method for calculating the contribution of solvent to the X-ray diffraction pattern of biological molecules

Russell Fraser、T.P. MacRae、E. Suzuki1978-12-01Journal of Applied Crystallography

Solvent makes a significant contribution to the diffracted intensity of crystals and fibres of large biological molecules. Allowance for this contribution must be made in the refinement of trial structures and an improved method is described for the calculation of solvent scattering.

X-ray Diffraction in CrystallographyEnzyme Structure and Function

Mehrstufige organische Redoxysteme — ein allgemeines Strukturprinzip

K. Deuchert、Siegfried Hünig1978-12-01Angewandte Chemie

Ein allgemeines Strukturprinzip für organische Verbindungen, die zur zweistufigen Elektronenübertragung befähigt sind, geht aus der folgenden Reaktionssequenz hervor: Dabei können ein oder beide X durch Y⊖ ersetzt sein. In diesen Systemen besitzt der radikalische Partner oft sehr große thermodynamische Stabilität. Wah…

Polyoxometalates: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchCoordination Chemistry and Organometallics

Pore Sizes of Solids

I. Halász、Kornél Martin1978-12-01Angewandte Chemie International Edition in English

Abstract A new, fast, and simple method based on size exclusion chromatography permits determination of the volumes of open and closed pores of rigid solids such as silica or porous glasses, together with the specific surface and the pore‐size distribution for pore diameters ranging from 10 to 4000Å. The results are i…

Material Dynamics and PropertiesMesoporous Materials and CatalysisGlass properties and applications

Electronic structure and redox properties of the clusters [Ru3O(CH3CO2)6L3]n+

John A. Baumann、Dennis J. Salmon、Stephen T. Wilson 等 5 位作者1978-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic structure and redox properties of the clusters [Ru3O(CH3CO2)6L3]n+John A. Baumann, Dennis J. Salmon, Stephen T. Wilson, Thomas J. Meyer, and William E. HatfieldCite this: Inorg. Chem. 1978, 17, 12, 3342–3350Publication Date (Print):December 1, 1978Publication Hist…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

Low-frequency dispersion in carrier-dominated dielectri

A.K. Jonscher1978-12-01Philosophical Magazine B

Some dielectric materials with large densities of low-mobility charge carriers show an anomalous low-frequency dispersion of the real and imaginary components of the complex dielectric permittivity, both varying as ω n−1 , with n close to or equal to zero. This behaviour is likely to be found in any dielectric materia…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsAcoustic Wave Resonator Technologies

Utilización de cenizas volantes en la fabricación de cementos

Luis Ulloa Fernández de Sanmamed1978-12-01Materiales de Construccion

La crisis de la energía, que tomó gran importancia a partir de 1973, ha originado la aceleración de estudios y posibilitado el desarrollo de otras fuentes alternativas del petróleo. El aprovechamiento de la energía latente que tienen algunos materiales volcánicos, o subproductos de procesos industriales (escorias side…

Bibliografía

Equipo Editorial1978-12-01Materiales de Construccion