Materials Literature
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We show that driven dislocation assemblies exhibit a set of dynamical phases remarkably similar to those of driven systems with quenched disorder such as vortices in superconductors, magnetic domain walls, and charge density wave materials. These phases include jammed, fluctuating, and dynamically ordered states, and…
Being a true two-dimensional crystal, graphene has special properties. In particular, a pointlike defect in graphene may induce perturbations in the long range. This characteristic questions the validity of using a supercell geometry in an attempt to explore the properties of an isolated defect. Still, this approach i…
This work explores the use of joint density-functional theory, a new form of density-functional theory for the ab initio description of electronic systems in thermodynamic equilibrium with a liquid environment, to describe electrochemical systems. After reviewing the physics of the underlying fundamental electrochemic…
Motivated to understand the nature of the strongly insulating ν=0 quantum Hall state in bilayer graphene, we develop the theory of the state in the framework of quantum Hall ferromagnetism. The generic phase diagram, obtained in the presence of the isospin anisotropy, perpendicular electric field, and Zeeman effect, c…
Here a recently observed weak first order transition in doped SrTiO3 is argued to be a consequence of the coupling between strain and order parameter fluctuations. Starting with a semi-microscopic action, and using renormalization group equations for vertices, we write the free energy of such a system. This fluctuatio…
Changing polystyrene nanoparticles from three-dimensional spherical shape to two-dimensional disk shape promotes their cell surface binding with significant reduction of cell uptake. As a result of lower cell uptake, nanodisks show very little perturbations on cell functions such as cellular ROS generation, apoptosis…
We report that electricity can be generated from limitless thermal motion of ions by two dimensional (2D) surface of silicon wafer at room temperature. A typical silicon device, on which asymmetric electrodes with Au and Ag thin films were fabricated, can generate a typical open-circuit voltage up to 0.40 V in 5 M CuC…
We present a systematic first-principles study of the phonon spectrum of hexagonal YMnO3 in ferroelectric (multiferroic) phase. We investigated in detail the low-energy phonon modes, their dispersion, symmetry, as well as the infrared optical properties of the crystal and determined the phonon density of states.
We discuss the nature of pressure induced phase transitions in standard Quantum Paraelectrics near quantum critical point. From a microscopic theory we first show that near the critical point the transition temperature $T_c(p)$ varies as $ (1-p/p_c)^ξ$ with $ξ={1/2}$. Within the Landau scheme, it is shown that for $ξ\…
We report results of inelastic-neutron-scattering measurements of low-energy spin-wave excitations in two structurally distinct families of iron-pnictide parent compounds: Na${}_{1\ensuremath{-}\ensuremath{\delta}}$FeAs and BaFe${}_{2}$As${}_{2}$. Despite their very different values of the ordered magnetic moment and…
We used gold nanoparticles (NPs) to investigate the length-scale-dependent dynamics in semidilute poly(ethylene glycol) (PEG)–water solutions. Fluctuation correlation spectroscopy was used to measure the diffusion coefficients ( D ) of the NPs as a function of their radius ( R 0 ), PEG volume fraction (ϕ), and molecul…
Soy protein isolate (SPI) and polyethylene oxide (PEO) were dissolved in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) and nonwoven nanofiber membranes were prepared from the solution by electrospinning. PEO functioned as a cospinning polymer in the process to improve the spinnability of SPI. The ratio of SPI to PEO was va…
This work investigates the surface and bulk properties of nanofibrillated cellulose (NFC) and bacterial cellulose (BC), as well as their reinforcing ability in polymer nanocomposites. BC possesses higher critical surface tension of 57 mN m(-1) compared to NFC (41 mN m(-1)). The thermal degradation temperature in both…
Abstract The synthesis and optical investigations of di(p‐methoxylphenyl)dibenzofulvene ( 1 ) and its analogues 2 , 3 , 4 , 5 , 6, and 7 with different lengths of alkoxyl chains are presented. All of these molecules exhibit emission in the solid state. The following interesting properties are reported for compound 1 :…
Several recent studies have attempted to impart [Au25(SR)18](-) with new properties by doping with foreign atoms. In this study, we studied the effect of copper doping on the electronic structure, geometric structure, and stability of [Au25(SR)18](-) with the aim of investigating the effect of foreign atom doping of […
BACKGROUND: This study aims to investigate the influence of different stirring times on antibacterial activity of silver nanoparticles in polyethylene glycol (PEG) suspension. The silver nanoparticles (Ag-NPs) were prepared by green synthesis method using green agents, polyethylene glycol (PEG) under moderate temperat…
We demonstrated giant optical activity using a chiral metamaterial composed of an array of conjugated bilayer metal structures. The chiral metamaterials were further integrated with photoactive inclusions to accomplish a wide tuning range of the optical activity through illumination with near-infrared light. The stron…
We present a novel, versatile, and simple solution-based routine to produce soft, nanosized Janus particles with tunable structural and physical properties at high volume yield. This process is based on the cross-linking of compartments within precisely defined multicompartment micelles (MCMs), which are themselves fo…
Large-scale soil application of biochar may enhance soil fertility, increasing crop production for the growing human population, while also sequestering atmospheric carbon. But reaching these beneficial outcomes requires an understanding of the relationships among biochar's structure, stability, and contribution to so…
Halloysite clay tubes have 50 nm diameter and chemically different inner and outer walls (inner surface of aluminum oxide and outer surface of silica). Due to this different chemistry, the selective etching of alumina from inside the tube was realized, while preserving their external diameter (lumen diameter changed f…