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Role of Hydrocarbon Radicals CHx (x=1, 2, 3) in Graphene Growth: A Theoretical Perspective

Chong Wang、Bo Xiao、Yi‐hong Ding2012-01-31ChemPhysChem

Many outstanding properties of graphene are blocked by the existence of structural defects. Herein, we propose an important healing mechanism for the growth of graphene, which is produced via plasma-enhanced chemical vapor decomposition (PECVD), that is, the healing of graphene with single vacancies by decomposed CH(4…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Effects of Nanosized Polystyrene and Polystyrene-Encapsulated Nanosilica on Physical Properties of Natural Rubber/Styrene Butadiene Rubber Nanocomposites

Anyaporn Boonmahitthisud、Saowaroj Chuayjuljit2012-01-31Polymer-Plastics Technology and Engineering

Natural rubber (NR)/styrene butadiene rubber (SBR) nanocomposites have been prepared with nanosized polystyrene (nPS) and polystyrene-encapsulated nanosilica (PS-nSiO2) through latex compounding. The nPS and PS-nSiO2 were synthesized by differential microemulsion polymerization. 80/20 NR/SBR blend was filled with vari…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

Facile mass production of thermally reduced graphene oxide

Seungjun Lee、Sungjin Park2012-01-31Carbon letters

Mass production of graphene-based materials, which have high specific surface area, is of importance for industrial applications. Herein, we report on a facile approach to produce thermally modified graphene oxide (TMG) in large quantities. We performed this experiment with a hot plate under environments that have rel…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

Modelling Dynamic Losses Under Rotational Magnetic Flux

Jean Vianei Leite、Mauricio Valência Ferreira da Luz、N. Sadowski 等 4 位作者2012-01-31IEEE Transactions on Magnetics

The flux density waveform in the stator of a rotational electrical machine or three-phase transformer is typically bidirectional in many regions of the core. However, rotational magnetic flux can be observed in some parts of their magnetic circuits. The iron core under rotational flux presents magnetic losses, usually…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Modifications of kenaf fibers with N‐methylol acrylamide for production of kenaf‐unsaturated polyester composites

Xueping Ren、Renhui Qiu、K. Li2012-01-31Journal of Applied Polymer Science

Abstract Kenaf fiber mats were modified with N ‐methylol acrylamide (NMA) solution with either sulfuric acid or p ‐toluenesulfonic acid (TsOH) as a catalyst. The (unmodified‐kenaf)‐UPE composites and (NMA‐modified‐kenaf)‐UPE composites were obtained by a compression molding process. Orthogonal experiments were used fo…

Natural Fiber Reinforced CompositesElectromagnetic wave absorption materialsMechanical Engineering and Vibrations Research

A New Look at Cavitation and the Applications of Its Liquid-Phase Effects in the Processing of Food and Fuel

Muthupandian Ashokkumar、Olga Krasulya、Sergey Shestakov 等 4 位作者2012-01-31Applied Physics Research

Ultrasound-induced acoustic cavitation has been studied in detail due to its chemical effects (sonochemistry) and light emission (sonoluminescence). However, the physical effects such as shear, shockwaves, etc., can also be used for useful applications despite their harmful effects, such as cavitation erosion. It has…

Microbial Inactivation MethodsUltrasound and Cavitation PhenomenaRadiation Effects and Dosimetry

Graphene field-effect transistor for radio-frequency applications : review

Jeong‐Sun Moon2012-01-31Carbon letters

Currently, graphene is a topic of very active research in fields from science to potential applications. For various radio-frequency (RF) circuit applications including low-noise amplifiers, the unique ambipolar nature of graphene field-effect transistors can be utilized for high-performance frequency multipliers, mix…

Graphene research and applications2D Materials and ApplicationsGraphene and Nanomaterials Applications

sp magnetism in clusters of gold thiolates

Ayuela, A.、Crespo del Arco, Patricia、Garcia, M.A. 等 5 位作者2012-01-31Docta Complutense (Universidad Complutense de Madrid)

Using first-principles calculations, we consider the bond between thiolate and small Au clusters, with particular emphasis on the resulting magnetic moment. The moment of pure gold clusters is 1 mu(B) for clusters with an odd number of Au atoms and zero for those with an even number. The addition of the thiolate, havi…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

New Catalysts for the Hydrogenation of Glucose to Sorbitol

Reinhard Geyer、Peter Kraak、Axel Pachulski 等 4 位作者2012-01-31Chemie Ingenieur Technik

Abstract Nickel catalysts supported on ZrO 2 , TiO 2 and ZrO 2 /TiO 2 mixtures performed more active, selective and stable than Ni/SiO 2 catalysts in the hydrogenation of glucose to sorbitol. This was shown by catalytic testing as well as by determination of Ni crystallite size before and after the test. The reason fo…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis for Biomass Conversion

Mechanochemistry: from Mechanical Degradation to Novel Materials Properties

V. Šepelák、K. D. Becker2012-01-31Journal of the Korean Ceramic Society

High-energy mechanical action applied to solid leads to destruction and diminution to the nanosize level. But on the other hand, it can induce structural changes at the nanoscale and at the atomic level which can result in novel materials properties. In this contribution, case studies will be presented concerned with…

High-pressure geophysics and materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

The Effect of Rice Husk Powder on Standard Malaysian Natural Rubber Grade L (SMR L) and Epoxidized Natural Rubber (ENR 50) Composites

Supalak Attharangsan、Hanafi Ismail、M. Abu Bakar 等 4 位作者2012-01-31Polymer-Plastics Technology and Engineering

The effects of rice husk powder (RHP) loading and two types of natural rubber matrix (SMR L and ENR 50) on curing characteristics and mechanical properties were studied. The scorch time and cure time decreased with increasing RHP loading whereas maximum torque showed an increasing trend. SMR L composites possessed lon…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesTribology and Wear Analysis

Cure and thermal stability of poly(amide‐amidic acid)—cured tetraglycidyl 4,4′‐diaminodiphenylmethane

Haiming Chen、Renguo Lü、Pei Li 等 7 位作者2012-01-31Journal of Applied Polymer Science

Abstract A novel curing agent, poly (amide‐amidic acid) (PAA), was used to cure tetraglycidyl 4,4′‐diaminodiphenylmethane (TGDDM). The initial cure and exothermic peak temperatures increased with increase in PAA content. The mechanism for the cure of TGDDM/PAA was proposed which involved, besides TGDDM cure, PAA imidi…

Epoxy Resin Curing ProcessesFlame retardant materials and propertiesSynthesis and properties of polymers

Effect of chemical blowing agent on the hygroscopic behavior of HDPE/rice husk flour composites

Behzad Kord2012-01-31Journal of Thermoplastic Composite Materials

The effect of chemical blowing agent on the cell morphology and long-term water absorption and thickness swelling of composites based on high-density polyethylene/rice husk flour were studied in this research. Composite materials containing high-density polyethylene, rice husk flour, chemical blowing agent and couplin…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Corrosion resistance of explosion cladding plate of carbon steel and 316L stainless steel

R. G. Paula、Carlos Roberto de Araújo、Vanessa de Freitas Cunha Lins 等 4 位作者2012-01-31Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The ASME AS-240TP-316L stainless steel in the form of a sheet 3 mm in thickness and the ASTM SA-516 grade 60N steel substrate are joined by explosion cladding. The objective of this paper is to evaluate the electrochemical behaviour of a cladding plate of carbon–manganese steel and stainless steel 316L when compared t…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Core Tester Iron Losses Segregation by Finite Element Modeling

J. P. Schlegel、N. Sadowski、Nelson Jhoe Batistela 等 6 位作者2012-01-31IEEE Transactions on Magnetics

A new designed core tester and its feeding and control devices are presented in this paper. With this workbench, mounted single phase induction motor stators can be magnetically fed with controlled induction waveforms in order to evaluate their quality in the industrial environment. As the measured data involves the m…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Poly(ϵ‐caprolactone) Decorated With One Room‐Temperature Red‐Emitting Ruthenium(II) Complex: Synthesis, Characterization, Thermal and Optical Properties

Marcus Schulze、Michael Jäger、Ulrich S. Schubert2012-01-31Macromolecular Rapid Communications

The incorporation of room-temperature red-emissive [Ru(II)(dqp)(dqp-CH(2) OH)](2+) (dqp is 2,6-di(quinolin-8-yl)pyridine) in poly(ε-caprolactone) (PCL) is explored following two routes. First, the ring-opening polymerization of ε-caprolactone is investigated using the free ligand and the complex as initiators. Alterna…

Advanced Polymer Synthesis and CharacterizationConducting polymers and applicationsbiodegradable polymer synthesis and properties

Using three-dimensional surface roughness parameters in analysis of atmospheric corrosion degradation of carbon steel

B.Y.R. Surnam、C.V. Oleti2012-01-31Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

When carbon steel is subjected to atmospheric corrosion, the surface texture of the base metal becomes rougher due to corrosion attack. In this study, three-dimensional surface roughness analysis of the base metal of carbon steel samples exposed outdoors was performed to investigate this aspect of atmospheric corrosio…

Corrosion Behavior and InhibitionWelding Techniques and Residual StressesNon-Destructive Testing Techniques

The role of the Pb2+ lone electron pair for bond valence sum analysis in mullite-type PbMBO4 (M = Al, Mn and Fe) compounds

M. Mangir Murshed、R. X. Fischer、Thorsten M. Gesing2012-01-31Zeitschrift für Kristallographie - Crystalline Materials

Abstract The bond valence sums (BVS) of the constituent atoms of three series of mullite-type compounds PbMn x Al 1– x BO 4 , PbFe x Al 1– x BO 4 and PbMn x Fe 1– x BO 4 ( x = 0 – 1) were analyzed with particular emphasis on lead. While the formal BVS of one bridging oxygen atom in the edge-sharing MO 6 octahedron was…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Superconductivity and structural variation of the electron-correlated layer systems Sr(Pd1−xTx)2Ge2(T=Co, Ni, Rh;0⩽x⩽1)

Jia-Wei Wang、I. A. Chen、Tsu‐Lien Hung 等 8 位作者2012-01-31Physical Review B

Superconductivity variations deduced from the x-ray diffraction and the magnetic and heat-capacity measurements in the pseudoternary Sr(Pd${}_{1\ensuremath{-}x}{T}_{x}$)${}_{2}$Ge${}_{2}$ layer system [Pd($4{d}^{8}$), $T$ $=$ Co($3{d}^{7}$), Ni($3{d}^{8}$), or Rh($4{d}^{7}$); $0\ensuremath{\leqslant}x\ensuremath{\leqs…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Photoinduced Electron Transfer in Zinc Naphthalocyanine–Naphthalenediimide Supramolecular Dyads

Mohamed E. El‐Khouly、Andrey G. Moiseev、Art van der Est 等 4 位作者2012-01-31ChemPhysChem

Photoinduced electron transfer was studied in self-assembled donor-acceptor dyads, formed by axial coordination of pyridine appended with naphthalenediimide (NDI) to zinc naphthalocyanine (ZnNc). The NDI-py:ZnNc (1) and NDI(CH(2))(2)-py:ZnNc (2) self-assembled dyads absorb light over a wide region of the UV/Vis/near i…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies