Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal Structure of the Rhombohedral MO3.3R2O3 Compounds (M = U, W, or Mo) and Their Relation to Ordered R7O12 PhasesS. F. BartramCite this: Inorg. Chem. 1966, 5, 5, 749–754Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1…
Proceedings of the National Academy of Sciences (PNAS), a peer reviewed journal of the National Academy of Sciences (NAS) - an authoritative source of high-impact, original research that broadly spans the biological, physical, and social sciences.
The indices of refraction of ADP, KDP, and deuterated KDP were measured at temperatures between the Curie point and room temperature. The estimated accuracy of the data is ±0.0001. The empirical equation Δn = (n2+an+b)c(298 − T) where n is the index at room temperature, Δn is the change in index, and T is the temperat…
Single-crystal specimens or polycrystalline sinters of cubic NaCl, KCl, KBr, KI, MgO, CaO, NiO, UC, CaF 2 , BaF 2 , UO 2 , and ThO 2 as well as anisotropic TiO 2 , Al 2 O 3 , and U 3 O 8 were bombarded with 40-keV xenon or krypton ions to give integrated ion doses of up to 2 × 10 16 ions/cm 2 . The specimens were exam…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic Structures of Metal PentacyanonitrosylsP. T. Manoharan and Harry B. GrayCite this: Inorg. Chem. 1966, 5, 5, 823–839Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1 May 1966https://pubs.acs.org/doi/10.1021/ic5003…
Abstract Increased time of mixing carbon black-rubber vulcanizates reduces dynamic modulus and dynamic viscosity as well as phase angle at moderate amplitudes of oscillation. Changes in dynamic properties with mixing time are shown to be associated with dispersion of carbon black.
The electrical resistivity, Hall coefficient and thermoelectric power of tungsten-ditelluride WTe 2 have been determined in the temperature range 4.2 to 600° K using single crystal specimens. The Hall coefficient is of n -type in the whole temperature range, while the thermoelectric power is of p -type below 60° K and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA New Hydrogen-Abstracting Reaction with Diethyl AzodicarboxylateFumio Yoneda, Kunio Suzuki, and Yoshihiro NittaCite this: J. Am. Chem. Soc. 1966, 88, 10, 2328–2329Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1 May 1966h…
Abstract Aus Mn, Al und B wurde eine ternäre Phase der Zusammensetzung Mn 2 AlB 2 erhalten. Diese kristallisiert aus geschmolzenem Überschüssigem Aluminium in silberglänzenden Nadeln, zusammen mit den schon bekannten Verbindungen AlB 2 und Al 6 Mn. Mn 2 AlB 2 hat eine rhombisch‐basisflächenzentrierte Elementarzelle mi…
Abstract Glycidol has been shown to be easily polymerized at room temperature in the presence of triethylamine, pyridine, lithium hydroxide, potassium hydroxide, sodium hydroxide, sodium methoxide, sodium amide, and other catalysts. Its reactivity with these catalysts is vastly greater than that of propylene oxide. Ev…
Modes of deformation involved in shearing of plain weave fabrics are analyzed in terms of the mechanical properties of yarn and the geometrical parameters of the fabric. The effective contact lengths at the intersecting points in the fabric are determined from , the initial modulus of shearing. The hysteresis produced…
The infrared lattice spectra from 700 to 50 cm−1 of eight cubic rare earth oxides are reported. It is evident from these data that the crystal structure determines the frequency position, and clearly shows the effect of the lanthanide contraction in this series of compounds.
The development of scale cells in insects has been studied from the appearance of the first cytoplasmic projection which forms the scale rudiment. This rudiment contains numerous longitudinally oriented microtubules throughout. Immediately under its outer surface lie a series of adjacent but distinct bundles of longit…
The aim of this paper is to give a qualitative account of the electrical properties of liquid divalent metals for which the density of states falls below the free electron value at the Fermi surface. It is argued that if this happens in the crystalline state it will also happen in the liquid, that this is so in mercur…
The electrical conductivity, the magnetoresistance, the Hall coefficient and the thermoelectric power of single crystal graphite are theoretically calculated as functions of the temperature and magnetic field intensity in the region where lattice scattering is dominant. The values of the electron-phonon coupling const…
Experimentally measured effective vacuum thermionic electron work functions are reported for well outgassed polycrystalline surfaces of beryllium (3.67 eV), titanium (3.6 to 4.3 eV), chromium (3.90 eV), iron (4.47 eV), nickel (4.41 eV), copper (4.42 eV), platinum (5.6 to 5.8 eV), strongly (210) oriented, and 304 stain…
The parameters in the crystal structure of α-GeTe were determined by least-squares analysis of intensity data obtained with an automatic x-ray powder diffractometer. The rhombohedral cell containing 4 Ge and 4 Te atoms has a=5.996±0.001 Å, α=88.18°, and the single atom-position parameter x=0.237±0.002. The displacemen…
Fluorescence quenching effects caused by multipolar energy-transfer interactions between rare-earth ions are examined. Transfer between remote ions by way of transitions that are matched in energy appears to be essentially dependent upon concentration alone (e.g., Sm3+ self-quenching) while transfer by non-resonant me…
Abstract Using synthetic near-ideal graphite obtained by hot-pressing and annealing pyrolytic material, we have prepared graphite nitrates from the first to the fourth sequence, under controlled conditions. For the first sequence compound, present determinations on form I (room temperature) agree with previous publica…
The infrared spectrum of hydrogen bonded HN3 dimers in solid nitrogen has been determined. A dimer band at 387 cm−1, assigned to the torsional distortion of the hydrogen bond, indicates the dimer has an open, not a cyclic structure. The hydrogen bond bending force constant is 0.09 mdyn/Å. The hydrogen bond frequency s…