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Corrosion Resistance of Titanium-Ruthenium Alloys

A. J. Sedriks1975-02-01CORROSION

The corrosion resistance of various Ti-Ru alloys (0.07 to 0.55 Wt% Ru) has been evaluated and compared with published data on Ti-Pd alloys. The results show that Ti-Ru alloys (1) are comparable with Ti-Pd alloys in terms of corrosion resistance in dilute (0 to 10%) boiling H2SO4 solutions, and are only slightly inferi…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Clebsch−Gordan coefficients for crystal space groups

Rhoda Berenson、Joseph L. Birman1975-02-01Journal of Mathematical Physics

A practical method for calculating Clebsch−Gordan coefficients for crystal space groups is presented. It is based on properties of the space group irreducible representations as induced from ray representations of subgroups. Using this method, we obtain all Clebsch−Gordan coefficients for a family of representations i…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Negative-ion/molecule reactions in sulphur hexafluoride

J P McGeehan、Brian C. O’Neill、J D Craggs1975-02-01Journal of Physics D Applied Physics

Using a double Townsend (uniform field) ionization chamber, the authors studied the ion conversion reactions involving SF 6 - and SF 5 - in SF 6 by observing, with mass spectrometer sampling, the processes occurring when these ions were injected separately from the source region into that where collisional detachment…

Diamond and Carbon-based Materials ResearchPlasma Diagnostics and ApplicationsVacuum and Plasma Arcs

Comparative Studies on the Properties of Tryptophanase and Tyrosine Phenol‐lyase Immobilized Directly on Sepharose or by Use of Sepharose‐Bound Pyridoxal 5′‐Phosphate

Saburo Fukui、Seiichiro Ikeda、Motoki Fujimura 等 5 位作者1975-02-01European Journal of Biochemistry

Tryptophanase from Escherichia coli B/qt 7-A and tyrosine phenol-lyase (beta-tyrosinase) from Escherichia intermedia were immobilized on Sepharose 4B by several direct coupling reactions or through pyridoxal 5'-phosphate previously bound to Sepharose. The most active preparation of immobilized tryptophanase was obtain…

Enzyme Structure and FunctionPolyamine Metabolism and ApplicationsAmino Acid Enzymes and Metabolism

Magnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. IV. Octachlorodimolybdate(n-) with n = 3 and 4 and tetrabutyratodimolybdate(n+) with n = 0 and 1

F. Albert Cotton、Erik B. Pedersen1975-02-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. IV. Octachlorodimolybdate(n-) with n = 3 and 4 and tetrabutyratodimolybdate(n+) with n = 0 and 1F. Albert Cotton and Erik PedersenCite this: Inorg. Chem. 1975, 14, 2, 39…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Lattice Thermal Conductivity of Crystals Containing Dislocations

Yoshiaki Kogure、Y. Hiki1975-02-01Journal of the Physical Society of Japan

General method to treat the scattering of lattice waves by static strain fields in anisotropic solids was applied to the calculation of thermal conductivity of crystals containing dislocations. The scattering cross widths for edge and screw dislocations in cubic crystals with {111} <110> and {110} <110> slip systems w…

Thermal properties of materialsThermography and Photoacoustic TechniquesFire effects on concrete materials

Phase transition in a polymer chain in dilute solution

A.R. Massih、M A Moore1975-02-01Journal of Physics A Mathematical and General

The order of the phase transition within a long polymer molecule in dilute solution brought about by the intramolecular forces is investigated within the context of a lattice model. It is found that the entropy is continuous at the transition but that the density changes discontinuously, implying that the transition h…

Lipid Membrane Structure and BehaviorMaterial Dynamics and PropertiesElectrostatics and Colloid Interactions

Short−range order fluctuations in the isotropic phase of a liquid crystal MBBA

Erdoḡan Gülari、B. Chu1975-02-01The Journal of Chemical Physics

We have measured the polarized (I∥) and the depolarized (I⊥) scattered light intensities by fluctuations of the orientational order parameter as a function of two scattering angles over a range of temperatures close to and above the isotropic−nematic phase transition of para−methoxybenzylidine para−n−butylaniline (MBB…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

The thermal conductivity of nickel and copper dispersed in poly(vinyl chloride)

Robert P. Kusy、Roger Corneliussen1975-02-01Polymer Engineering and Science

Abstract The thermal conductivity of segregated distributions of poly (vinyl chloride)/nickel (PVC/Ni) and poly(vinyl chloride)/copper (PVC/Cu) was measured for volume fractions ranging from 0 to 0.15. The thermal conductivities increased from 0.15 Btu/hr ft °F for unmodified PVC to 2.79 Btu/hr ft °F for PVC/15 percen…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Chemical modification of yeast 3-phosphoglycerate kinase.

Francis S. Markland、A.D.E. Bacharach、Bernhard H. F. Weber 等 6 位作者1975-02-01Journal of Biological Chemistry

Sulfhydryl reagents, as well as mild hydrogen peroxide oxidation, do not inhibit the activity of yeast phosphoglycerate kinase, indicating that the single thiol group and 3 methionine residues present in the enzyme are not essential for activity. Nitration of phosphoglycerate kinase by tetranitromethane inhibits the e…

Cancer, Hypoxia, and MetabolismEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Crystal and molecular structures of ion radical molecular complexes of cis-bis(trifluoromethylethylene-1,2-dithiolato)nickel with phenothiazine and phenoxazine. Effects of donor-acceptor separation on the molecular properties

Anami. Singhabhandhu、Paul D. Robinson、J. H. Fang 等 4 位作者1975-02-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structures of ion radical molecular complexes of cis-bis(trifluoromethylethylene-1,2-dithiolato)nickel with phenothiazine and phenoxazine. Effects of donor-acceptor separation on the molecular propertiesAnami. Singhabhandhu, P. D. Robinson, J. H. Fang,…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchPhenothiazines and Benzothiazines Synthesis and Activities

Deformational, swelling, and potentiometric behavior of ionized poly(methacrylic acid) gels. II. Experimental results

J. Hasa、M. Ilavský1975-02-01Journal of Polymer Science Polymer Physics Edition

Abstract The deformational, swelling, and potentiometric behavior of poly(methacrylic acid) gels was measured as a function of the degree of crosslinking, ionic strength, and degree of ionization. The comparison of the stress–strain behavior with theoretical relations derived in the preceding part has shown that the r…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Science and PVC

Effect of pressure on the zone-center phonons of PbTiO3and on the ferroelectric-paraelectric phase transition

F. Cerdeira、W. B. Holzapfel、D. Bäuerle1975-02-01Physical review. B, Solid state

The first-order Raman spectrum of single-crystalline PhTi${\mathrm{O}}_{3}$ in the teatragonal ferroelectric phase was studied at room temperature as a function of hydrostatic pressure up to 80 kbar. Mode Gr\"uneisen parameters, as well as higher-order coefficients in the expansion of phonon frequency vs pressure are…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsUltrasonics and Acoustic Wave Propagation

Comparative Electron-Microscope Studies on Type-III and Type-I Collagens

Hanna Wiedemann、Tadahiko Fujii、Klaus Kühn 等 5 位作者1975-02-01European Journal of Biochemistry

Long-spacing-segment crystallites prepared from type III collagen with the chain composition [alpha1(III)]3 and type I collagen with the chain composition [alpha(I)]i12alpha2 have been compared in the electron microscope after positive. staining with phosphotungstic acid and uranyl acetate. The comparison revealed sev…

Enzyme Production and CharacterizationCollagen: Extraction and Characterization

An Analysis of the Impedance of Polycrystalline Beta‐Alumina

R. W. Powers、S. P. Mitoff1975-02-01Journal of The Electrochemical Society

A procedure is described in this paper for distinguishing in the measured electrical properties of polycrystalline β‐alumina, the separate contributions of the grain boundaries and of the crystal, i.e. , the grain interiors. This separation is brought about through the use of a model for these properties. Certain quan…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Physical adsorption of patchwise heterogeneous surfaces. I. Heterogeneity, two-dimensional phase transitions, and spreading pressure of the krypton-graphitized carbon black system near 100.deg.K

Frederick A. Putnam、Tomlinson Fort1975-02-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhysical adsorption of patchwise heterogeneous surfaces. I. Heterogeneity, two-dimensional phase transitions, and spreading pressure of the krypton-graphitized carbon black system near 100.deg.KFrederick A. Putnam and Tomlinson Fort Jr.Cite this: J. Phys. Chem. 1975, 79, 5,…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchNanopore and Nanochannel Transport Studies

Effective conductivity of two−phase material with cylindrical phase boundaries

Kenneth S. Mendelson1975-02-01Journal of Applied Physics

A two−phase material in which the phase boundaries are cylindrical surfaces is considered. The generators of the phase boundaries are parallel to the z axis and the x and y axes are the principal axes of the effective conductivity tensor. If the two phases have conductivities σ1 and σ2, then the effective conductivity…

Material Dynamics and Properties

Blue dextran-sepharose: an affinity column for the dinucleotide fold in proteins.

Sioe Thung Thompson、Kathleen Heelan Cass、Earle Stellwagen1975-02-01Proceedings of the National Academy of Sciences

A procedure is described to utilize blue dextran-Sepharose as an affinity chromatographic column specific for the super-secondary structure called the dinucleotide fold, which forms the binding sites for substrates and effectors on a wide range of proteins. The procedure can be used to identify proteins, either purifi…

Chemical Synthesis and AnalysisEnzyme Structure and FunctionBiochemical and Molecular Research

Chemical shift in the X-ray K absorption edge of strontium

M. K. Das Gupta1975-02-01Journal of Physics F Metal Physics

It has been observed here that the K edge of strontium is shifted towards the high energy side in all its compounds with respect to strontium metal. These shifts have been correlated, qualitatively with the interatomic distances and the per cent ionic character of the bonds in simple compounds. A graph of observed shi…

Nonlinear Optical Materials ResearchBoron and Carbon Nanomaterials ResearchX-ray Diffraction in Crystallography