Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhosphazene high polymers with bioactive substituent groups: prospective anesthetic aminophosphazenesHarry R. Allcock, Paul E. Austin, and Thomas X. NeenanCite this: Macromolecules 1982, 15, 3, 689–693Publication Date (Print):May 1, 1982Publication History Published online1…
The primary steps involved in a heterogeneously catalyzed reaction are illustrated schematically by Figure 1. These include adsorption and desorption steps of the particles involved as well as surface migration and reactive and nonreactive interactions. Thus a reaction path may be offered to the overall chemical trans…
This is the first of a series of papers dealing with work on the surface structure of yarns, which formed the basis for the development of the Sirospun process. The paper explains that untreated single yarns are generally unsuitable for use as warp yarn in weaving, mainly because the surface fibres are not adequately…
Theoretical and practical advances in the field of ferroelectcitricity stimulate search for, as well as preparation and investigation of, novel ferroelectrics exhibiting high pyroelectric, electric, optical and mechanical characteristics. This situation necessitates systimatization in analysis of available experimenta…
The Limulus lysate gelatin activity of several simple polysaccharides including yeast mannans and bacterial dextrans was investigated. The mannans from Saccharomyces cerevisiae wild and mutant strains possessing dense branches showed positive gelatin activity at concentrations of 1 microgram/ml or more regardless of d…
Pyridinoline, a cross-linking amino acid of collagen, was degraded by irradiation of ultraviolet light. The decomposition rate varied with pH of the solution and wavelength of irradiation light. The maximum of the degradation rate at individual pH coincides with the ultraviolet absorption maximum. Namely, it was maxim…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrical properties of sodium copper sulfide (Na3Cu4S4), a mixed-valence one-dimensional metalZbigniew Peplinski, David B. Brown, Timothy Watt, William E. Hatfield, and Peter DayCite this: Inorg. Chem. 1982, 21, 5, 1752–1755Publication Date (Print):May 1, 1982Publication H…
The behaviour of a ⅓〈1 123〉{1122} edge dislocation under the effect of an external shear stress applied on {1122} planes has been studied by computer calculation. Before the application of the external stress, the dislocation has either of two typos of core configuration; one spreads as two twin faults on {1121} and {…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of tantalum .mu.-dinitrogen complexes from molecular nitrogen and reduced tantalum complexesScott M. Rocklage, Howard W. Turner, Jere D. Fellmann, and Richard R. SchrockCite this: Organometallics 1982, 1, 5, 703–707Publication Date (Print):May 1, 1982Publication…
Collagen catabolism has been measured in skins of streptozotocin-induced diabetic rats. For measuring catabolism of collagen synthesized de novo during the diabetic state, we measured the amounts of [3H]hydroxyproline-containing degradation products in skins of diabetic rats, killed 4 h after [3H]proline injection (pr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemical properties of water-soluble porphyrins. 2. The reaction of iron(III) tetrakis(4-N-methylpyridyl)porphyrin with the superoxide radical dioxygen coupleD. Solomon, P. Peretz, and M. FaraggiCite this: J. Phys. Chem. 1982, 86, 10, 1842–1849Publication Date (Print):May 1,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluorine-19 NMR chemical shifts and the microstructure of fluoro polymersAlan E. Tonelli, F. C. Schilling, and Rudolf E. CaisCite this: Macromolecules 1982, 15, 3, 849–853Publication Date (Print):May 1, 1982Publication History Published online1 May 2002Published inissue 1 Ma…
A study has been commenced to determine the exact nature of marine iron corrosion products. Due to differences in micro-environments and corrosion products it is necessary to consider at least four distinct stages in the history of marine iron artifacts. These stages are (1) initial immersion, (2) concreted with resid…
A statistical theory of lyotropic cholesteric phase in the system of long coiled rod molecules is presented. Effects of molecular exclusion and of attractive intermolecular force are both taken into consideration. On the basis of the theoretical results, experiments on the cholesteric solutions of polypeptide are inve…
Metrizamide was employed in six patients who, during angiography, had had severe anaphylactoid reactions to conventional ionic contrast media. Five of these patients had received corticoid premedication before injection of both conventional contrast medium and metrizamide; anaphylaxis occurred only after administratio…
A mechanical lithotripter of simple and robust design is described. With the aid of this device it proves possible to crush common bile duct and intrahepatic calculi that are otherwise too large to pass out spontaneously after papillotomy, or are inaccessible to other means of treatment. To date it has been used with…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotolysis of organopolysilanes. Photochemical behavior of phenylethynyldisilanesMitsuo Ishikawa, Hiroshi Sugisawa, Takamasa Fuchikami, Makoto Kumada, Tokio Yamabe, Hiroshi Kawakami, Kenichi Fukui, Yutaka Ueki, and Haruo ShizukaCite this: J. Am. Chem. Soc. 1982, 104, 10, 287…
Examination of the isothermal crystallization and the effect of melting conditions on samples of isotactic polypropylene and its composite with talc, combined with electron-microscopic observation, has shown two types of heterogeneous nuclei effective in the crystallization process: (1) metastable nuclei, representing…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermotropic liquid-crystalline behavior of some single- and double-chained pyridinium amphiphilesErnst J. R. Sudholter, Jan B. F. N. Engberts, and Wim H. De JeuCite this: J. Phys. Chem. 1982, 86, 10, 1908–1913Publication Date (Print):May 1, 1982Publication History Published…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structures of bis(4,4',6,6'-tetramethyl-2,2'-bipyridyl)copper(I) perchlorate, bis(4,4',6,6'-tetramethyl-2,2'-bipyridyl)copper(II) diperchlorate, and bis(4,4',6,6'-tetramethyl-2,2'-bipyridyl)copper(II) diperchlorate dihydrate. A search for copper(II) and…