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From Bubble to Skyrmion: Dynamic Transformation Mediated by a Strong Magnetic Tip

A. S. Kirakosyan、V. L. Pokrovsky2003-05-21arXiv

Skyrmions in thin metallic ferromagnetic films are stable due to competition between the RKKY interaction and uniaxial magnetic anisotropy. We mimic the RKKY interaction by the next-nearest-neighbors ferromagnetic and antiferromagnetic exchange interactions. We demonstrate analytically and numerically dissipative tran…

Materials Science

Effect of Surfactant Structure on the Orientation of Liquid Crystals at Aqueous−Liquid Crystal Interfaces

Jeffrey M. Brake、Andrew D. Mezera、Nicholas L. Abbott2003-05-21Langmuir

It is known that the orientations assumed by thermotropic liquid crystals (LCs) in contact with water are sensitive to the types and concentrations of surfactants and/or polymers present in the aqueous phase. This work expands upon these past observations by developing criteria for surfactants that give rise to a part…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Metal-Insulator Transition Induced by Short Range Magnetic Ordering in Mono-layered Manganite

E. O.2003-05-20Bulletin of the Korean Chemical Society

The structural, magnetic, and transport properties of a mono-layered manganite <TEX>$La_{0.7}Sr_{1.3}MnO_{4+{\delta}}$</TEX> were investigated using variable temperature neutron powder diffraction as well as magnetization and transport measurements. The compound adopts the tetragonal I4/mmm symmetry and exhibits no ma…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Photophysical Properties of a Supramolecular Interlocked Conjugate

Andrew C. Benniston、Morven Davies、Anthony Harriman 等 4 位作者2003-05-20The Journal of Physical Chemistry A

The binding behavior between a rigid, π-accepting aromatic polycycle (ADIQ·2PF 6 ) and an electron-donating crown ether (CE(10)) is reported in acetonitrile solution. In CH 3 CN at low concentration of crown ether, the binding data are consistent with formation of a 1:1 complex in which the ADIQ·2PF 6 residue is parti…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Study of the structural evolution of the 10 Å unstable hydrate of kaolinite during dehydration by XRD and SAXS

S. Naamen、Safa Jemai、H. Ben Rhaïem 等 4 位作者2003-05-20Journal of Applied Crystallography

This work deals with understanding the structural evolution of the dehydration of the 10 Å unstable hydrate of kaolinite. The method used to characterize this hydrate is based on a comparison between the experimental and the calculated X-ray diffraction profiles. The study was achieved in two steps: (i) the quantitati…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Quasi-Steady State Natural Convection in Laser Chemical Vapor Deposition With a Moving Laser Beam

Kun Zhang2003-05-20ASME Journal of Heat and Mass Transfer

Numerical analysis of laser chemical vapor deposition (LCVD) of titanium nitride by a moving laser beam is presented. The effect of natural convection due to temperature and concentration differences in the gaseous mixture is modeled and implemented into thermal model of LCVD by a moving laser beam. The problem is for…

Diamond and Carbon-based Materials ResearchHigh-Temperature Coating BehaviorsLaser Material Processing Techniques

Phase Transitions and Spin Relaxation in La0.95Sr0.05MnO3

B. I. Kochelaev、E. Shilova、J. Deisenhofer 等 7 位作者2003-05-20Modern Physics Letters B

We present a model calculation of the paramagnetic-resonance linewidth in La 0.95 Sr 0.05 MnO 3 . Both the temperature and the angular dependencies can be described by contributions from the crystal field due to the cooperative Jahn–Teller transition.

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Synthesis and characterization of multiblock copolymers based on L‐lactic acid, citric acid, and poly(ethylene glycol)

Fanglian Yao、Yun Bai、Yutao Zhou 等 6 位作者2003-05-20Journal of Polymer Science Part A Polymer Chemistry

Abstract Because poly( L ‐lactic acid) (PLLA) is a biodegradable polyester with low immunogenicity and good biocompatibility, it is used as a biomaterial. However, hydrophobic PLLA does not have any reactive groups. Thus, its application is limited. To increase the hydrophilicity of PLLA and accelerate its degradation…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Observation of Equilibrium, Nanometer-Sized Clusters of Silver Iodide in Aqueous Solutions

Ivana Mladenović、Willem K. Kegel、Paul H. H. Bomans 等 4 位作者2003-05-20The Journal of Physical Chemistry B

Thermodynamically stable clusters containing up to 10 or more silver iodide pairs have been observed in aqueous electrolyte solutions using ultracentrifugation and cryoelectron microscopy. These clusters are in equilibrium with an excess phase of solid AgI. We measured the size distribution of the clusters by their si…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Cationic disorder, microstructure and dielectric response of ferroelectric SBT ceramics

Christophe Müller、F Jacob、Y. Gagou 等 4 位作者2003-05-20Journal of Applied Crystallography

Polycrystalline samples of SrBi 2 Ta 2 O 9 (acronym SBT) have been prepared by means of solid-state reaction either using a classical route or by mechanochemical activation. For each compound, a structural analysis of the ferroelectric orthorhombic phase (space group A 2 1 am ) has been performed from the fitting of n…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisX-ray Diffraction in Crystallography

Optical properties of polycrystalline metallic films

Juan C. Sotelo、Jesper Ederth、Gunnar A. Niklasson2003-05-20Physical review. B, Condensed matter

We extend the Mayadas and Shatkes's approach [Phys. Rev. B $1,$ 1382 (1970)] to study the optical properties of polycrystalline metal thick films in the visible and far infrared range of the spectrum. We show that in this range grain boundary scattering can account for the experimentally observed lowering of the film…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Photogeneration of superparaelectric large polarons in dielectrics with soft anharmonicT1uphonons

Keiichirō Nasu2003-05-20Physical review. B, Condensed matter

In connection with the recent experiments on photoenhancements of the electronic conductivity and the quasistatic electric susceptibility of ${\mathrm{SrTiO}}_{3},$ we theoretically study global versus local parity violation of a photogenerated electron in this dielectric. The photogenerated electron, being quite itin…

Ferroelectric and Piezoelectric MaterialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

In-Situ Contacted Single-Walled Carbon Nanotubes and Contact Improvement by Electroless Deposition

Robert Seidel、M. Liebau、Georg S. Duesberg 等 8 位作者2003-05-20Nano Letters

This work presents a simple and versatile approach for the growth of in-situ contacted single-walled carbon nanotubes (SWCNTs) and subsequent improvement of the contacts using a self-aligned process. We investigated the conditions for the thermal CVD growth of SWCNTs and developed a variety of multilayered metal syste…

Carbon Nanotubes in CompositesGraphene research and applicationsSemiconductor materials and interfaces

200-mW-average power ultraviolet generation at 0193 μm in K_2Al_2B_2O_7

Nobuhiro Umemura、Miwako Ando、Kaori Suzuki 等 9 位作者2003-05-20Applied Optics

K2Al2B2O7 has been found to be phase matchable for type-1 sum-frequency generation (SFG) at 0.193 microm by mixing the Nd:YAG laser wavelength at 1.0642 microm and the SFG output of the RbTiOAsO4 optical parametric oscillator tuned at 0.2358 microm. An average power of 200 mW at 10 kHz was obtained in a 7-mm-long crys…

Crystal Structures and PropertiesPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Phase Diagram Constructed from the HPLC Fractions of a Polystyrene-b-polyisoprene Prepared by Anionic Polymerization

Soojin Park、Kyoon Kwon、Dong-Hyun Cho 等 6 位作者2003-05-20Macromolecules

Using 2D-LC, a mother PS-b-PI diblock copolymer prepared by anionic polymerization was fractionated into nine fractions differing in the PI and PS block lengths. In this way, PS-b-PIs of the similar molecular weight were obtained. The fractions show composition variation large enough to construct a detailed phase diag…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsBlock Copolymer Self-Assembly

A model for diffusion-controlled solidification of ternary alloys in mushy layers

Daniel Anderson2003-05-20Journal of Fluid Mechanics

We describe a model for non-convecting diffusion-controlled solidification of a ternary (three-component) alloy cooled from below at a planar boundary. The modelling extends previous theory for binary alloy solidification by including a conservation equation for the additional solute componentand coupling the conserva…

Solidification and crystal growth phenomenaMetallurgical Processes and Thermodynamicsnanoparticles nucleation surface interactions

PTFE−Polystyrene Core−Shell Nanospheres and Nanocomposites

Elena Giani、Katia Sparnacci、Michele Laus 等 6 位作者2003-05-20Macromolecules

PTFE latexes with particles in the submicrometer size range were employed as seeds in the emulsifier-free styrene emulsion polymerization to obtain PTFE−polystyrene (PS) core−shell nanospheres. Stable latexes were generally obtained. Neither residual PTFE nor secondary nucleation was observed, thus leading to PTFE−PS…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

SYMMODES: a software package for group-theoretical analysis of structural phase transitions

C. Capillas、E. Kroumova、M. I. Aroyo 等 6 位作者2003-05-20Journal of Applied Crystallography

Group-theoretical methods are widely used in the investigation of phase transitions in crystals. On the one hand, important structural aspects concerning the relation between the lowand the highsymmetry structures follows from the the group±subgroup relations of the space groups G > H describing the symmetry of the tw…

Solid-state spectroscopy and crystallographynanoparticles nucleation surface interactionsX-ray Diffraction in Crystallography

Preparation and Catalytic Evaluation of Macroporous Crystalline Sulfated Zirconium Dioxide Templated with Colloidal Crystals

Mohammed A. Al-Daous、Andreas Stein2003-05-20Chemistry of Materials

Colloidal crystal templates were used to synthesize three-dimensionally ordered macroporous sulfated zirconia catalysts with pore diameters of ∼300 nm and less. Ordered arrays of uniformly sized poly(methyl methacrylate) latex spheres were infiltrated with clear precursor solutions containing varying SO 4 /Zr molar ra…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Luminescence of Tiopronin Monolayer-Protected Silver Clusters Changes To That of Gold Clusters upon Galvanic Core Metal Exchange

Tao Huang、Royce W. Murray2003-05-20The Journal of Physical Chemistry B

Water-soluble tiopronin monolayer-protected silver clusters (Ag MPCs), with 1.6 nm average diameter cores, exhibit visible luminescence at 500 nm with a quantum yield estimated near 10 -4 when excited at 400 nm. The Ag MPCs become organic-soluble upon conversion to poly(ethylene glycol) quaternary ammonium salts of th…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresNanocluster Synthesis and Applications