Materials Literature
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Using a rigorous coupled-wave analysis, a (2 /spl times/ 2) matrix method in homogenous layered media is generalized for a grating-embedded multilayer structure with (2M /spl times/ 2M) dynamic and propagation matrices in both transverse-electric and transverse-magnetic polarizations, where M is the number of harmonic…
Ternary carbide Ti3 SiC2 was first synthesised through a pulse discharge sintering (PDS) technique from mixtures of Ti, SiC, and C with different molar ratios. Sintering processes were conducted at 1200 – 1400°C for 15 – 60 min at a pressure of 50 MPa. The phase constituents and microstructures of the synthesised samp…
The objective of this work is to find a suitable correlation that best fits the specific heat of metals, metal oxides and metal fluorides as a function of temperature. It was found that a multilinear regression model of the form CP = aT b e cT e d/T has the lowest deviation from experimental data compared to other cor…
Abstract Melamine is widely used as a blowing agent in intumescent flame‐retardant systems. However, when it was blended into the epoxy resin cured with hyperbranched (3‐hydroxyphenyl) phosphate (HHPP), neither greater expansion nor improved limiting oxygen index (LOI) was obtained during combustion compared with that…
Pb(Zr,Ti)O 3 –Pb(Mn 1/3 Nb 2/3 )O 3 (PZT–PMnN) system has been studied for high‐power piezoelectric applications. This study investigates this system to find out the composition with high‐power density piezoelectric characteristics and low tem‐perature coefficient of resonance frequency (TCF). It was found that the co…
The well-known fact that a phase change is normally accompanied by a relatively large change in internal energy is explored and is used to develop an innovative method of achieving refrigerative effects in solid state metal alloys. Applying a cyclic mechanical stress in certain materials can induce crystalline structu…
Abstract Malonate oligomers were synthesized as plasticizers for poly(lactic acid) (PLA). Esterification reactions were performed between diethyl bishydroxymethyl malonate (DBM) and either adipoyl dichloride or succinyl dichloride. Two molar masses were obtained within each series. Blending was carried out with PLA an…
Abstract We have studied the photoinduced charge separation in a double layer consisting of a 50 nm thick, discotic antenna layer, i.e., free‐base tetra‐ para ‐octylphenyl porphyrin (H 2 TOPP), spin‐coated onto a smooth layer of anatase TiO 2 using the electrodeless “flash‐photolysis time‐resolved microwave conductivi…
Carbon nanotubes (CNTs) have attracted great attention as electron emitters. These field emission cathodes operate at room temperature without a heater, in contrast to thermionic emitters that often require considerable heater power for proper operation. Furthermore, CNTs have the advantage of large aspect ratios, all…
An approximate analytical model was developed that links the fringing-field broadening of the phase profile of a liquid-crystal (LC) beam-steering device, and the resulting diffraction efficiency, to the physical parameters of the device including the cell thickness as well as the dielectric, optical, and geometrical…
Abstract In this paper a synthetic Poly(L‐lactic‐co‐ϵ‐caprolactone) [P(LLA‐CL)] (75:25) copolymer has been fabricated into a nanofibrous structure by electrospinning. The polymer crystal structure has been investigated by DSC and x‐ray diffraction method. During electrospinning at room temperature, a crystallization o…
Electrochemical impedance spectroscopy, corrosion potential measurements, and surface analysis by scanning electron microscopy/energy-dispersive x-ray spectroscopy (SEM/EDX) and Raman spectroscopy were used to investigate the localized dissolution of millscale-covered pipeline steel surfaces. The porous millscale orig…
Abstract An efficient method for preparation of semiconductor quantum rod films for robust lasing in a cylindrical microcavity is reported. A capillary tube, serving as the laser cavity, is filled with a solution of nanocrystals and irradiated with a series of intense nanosecond laser pulses to produce a nanocrystal f…
The affinity of Mg/Fe hydrotalcite‐like‐compound (HTlc) for the removal of Cr (VI) from aqueous medium was studied as a function of pH, contact time, temperature, HTlc dose and Cr (VI) concentration. The fraction of Cr (VI) removal decreases with increase in pH of 3 to 10. The reaction kinetic study was undertaken by…
The relaxation processes in pure and copper-doped potassium tantalate niobate (KTN) were investigated by dielectric spectroscopy over a wide frequency and temperature range. In the copper-doped KTN above the ferroelectric phase transition temperature, a relaxation process was observed to behave according to the Vogel-…
In recent years, scientific and industrial interest has been focused on the preparation of organic/inorganic nanocomposites because of their unique hybrid properties correlated with the enormous interfacial adhesion region that is a characteristic of nanoparticles. The objective of the whole research was to improve po…
Abstract In this contribution we report on an XPS study of microporous and mesoporous titanosilicates, in particular microporous titanium silicalite TS‐1, ordered mesoporous Ti‐MCM‐41 and [Ti]‐MCM‐41 and amorphous mesoporous silica–titania (MST) catalysts. Our aim was to obtain both photoemission and x‐ray‐excited Aug…
Species of cyanobacteria in the genera Synechococcus and Synechocystis are known to be the catalysts of a phenomenon called "whitings", which is the formation and precipitation of fine-grained CaCO3 particles. Whitings occur when the cyanobacteria fix atmospheric CO2 through the formation of CaCO3 on their cell surfac…
Superelasticity is a property used in orthodontics to initiate tooth movement in the first stage of orthodontic treatment. It is the aim of all clinicians to accomplish biological tooth movement, which implies the use of low, continuous force and requires archwire with low stiffness. In this study, 15 nickel-titanium…
Abstract The molecular cluster model for homogeneous bubble nucleation was extended to predict the bubble nucleation events in elastomers, polymers and polymer solutions. For nucleation in elastomers and polymers, the strain energy overcome by a critical bubble during growth period was also considered. The calculation…