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Control of Polymorphism in Crystallization of Amino Acid

Mitsutaka Kitamura2003-01-01Developments in Chemical Engineering and Mineral Processing

Abstract The crystallization mechanism and the controlling factors in the crystallization of amino acid polymorphs were investigated. It was demonstrated that the effect of supersaturation (Ostwald's step rule) was not observed for systems of either L‐Glutamic acid (α, β) or L‐Histidine (A, B). The intensive effect of…

Crystallography and molecular interactionsEnzyme Structure and FunctionCrystallization and Solubility Studies

Analysis of Magnetic Properties of the Wound-core Type Three-phase Transformer

Kunihiro Shinya、Koichi Saitoh2003-01-01IEEJ Transactions on Industry Applications

This papaer describes the magnetic properties of wound-core type three-phasetransformer. In the analysis, magnetization characteristics are approximated by a Fourier-series, and it is assumed that the eddy current factor is proportional to the time-varying magnetic flux. Moreover harmonic balance method where the zero…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Interdiffusion in α Solid Solution of the Al-Cu-Mg-Ag System

Tomoshi Takahashi、Koji Hisayuki、Toshimi Yamane 等 5 位作者2003-01-01MATERIALS TRANSACTIONS

Quaternary and ternary interdiffusion experiments of Al-rich α Al-Cu-Mg-Ag alloys have been performed in the temperature range from 793 to 853 K. The concentration profiles indicate that the diffusion distance of Cu is shorter than those of Mg and Ag in the solid solutions. The direct and indirect interdiffusion coeff…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesMetallurgical and Alloy Processes

Influence of Compressive Stress on Electric Properties of Na 0.5 − x K x Bi 0.5 TiO 3 Solid Solutions (x ≤ 0.1)

J. Suchanicz、J.P. Mercurio、K. Konieczny 等 4 位作者2003-01-01Ferroelectrics

The dielectric, pyroelectric and hysteresis loops measurements of NBT-KBT ceramics for stress-free or under compressive stress (0-1500 bar) have been carried out. It was shown that compressive stress shifts of phase transition, reduction of thermal hysteresis and decrease of the polarization. These effects can be main…

Ferroelectric and Piezoelectric MaterialsSolid-state spectroscopy and crystallographyMaterial Science and Thermodynamics

PbTiO3 at Finite Temperature: An Ab-initio Molecular Dynamics Study

Varadharajan Srinivasan2003-01-01AIP conference proceedings

PbTiO3 is a prototypical ferroelectric material that exhibits a single structural phase transition (cubic to tetragonal): it is a soft mode driven, predominantly displacive, transition. In this paper, we study the behavior of PbTiO3 at finite temperature by ab‐initio molecular dynamics simulations. In this approach cl…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsSolid-state spectroscopy and crystallography

Structural Study of Phase Transition in Ferroelectric RbHSO 4

Kazuyuki Itoh、Chikako Moriyoshi2003-01-01Ferroelectrics

We determined the paraelectric and ferroelectric structures of RbHSO 4 by X-ray crystal structure analysis at nine temperatures. The ferroelectric structure is similar to one of two disordered arrangements of the paraelectric phase. Determined temperature dependence of the atomic mean-square thermal displacements is c…

Acoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Magnetic properties of thin α-p-nitrophenyl nitronyl nitroxide films

Sílvia Molas、C. Coulon、Jordi Fraxedas2003-01-01CrystEngComm

By stabilising the otherwise unstable α-phase of the p-nitrophenyl nitronyl nitroxide radical as thin films we experimentally observe that this phase nearly behaves as a Curie paramagnet, as evidenced by a small Weiss temperature (θ = −0.3 K), in agreement with recent measurements performed on a rather unique single c…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchElectron Spin Resonance Studies

REACTOR CHARACTERISTICS RELATED TO MODERATE OR INTENSE LOW-OXYGEN DILUTION FOR CLEAN/CLEANING COMBUSTION PLANTS

Mara de Joannon、Giuseppe Langella、F. Beretta 等 5 位作者2003-01-01Clean Air

Combustion processes evolving in mild conditions are correcterized by working temperature lower than the flame temperature of the traditional combustion systems, allowing for a drastic reduction of pollutant formation. Such operating conditions' need of specific plant configurations related to the recovery of flue gas…

Catalytic Processes in Materials Science

Investigation of 1-Deoxy-D-Xylulose 5-Phosphate Synthase and Transketolase of Bacillus subtilis in Relation to Vitamin B6 Biosynthesis

Akihiro Sakai、Natsumi Kinoshita、Makoto Kita 等 5 位作者2003-01-01Journal of Nutritional Science and Vitaminology

In Escherichia coli, 4-(phosphohydroxy)-L-threonine and 1-deoxy-D-xylulose 5-phosphate are believed to be direct precursors of vitamin B6 (B6), and 1-deoxy-D-xylulose 5-phosphate synthase (Dxs) and transketolase could catalyze the formation of each precursor. In this report, the possible involvement Dxs and transketol…

Microbial Metabolic Engineering and BioproductionEnzyme Structure and FunctionBiochemical and Molecular Research

Nematic ordering problem as the polymer problem of the excluded volume

A Yakunin2003-01-01Open Physics

Abstract Based on a solution of the polymer excluded volume problem, a technique is proposed to estimate some parameters at the isotropic-nematic liquid crystal phase transition (the product of the volume fraction of hard sticks and the ratio of the stick length, L, to its diameter, D; the maximum value of this ratio…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Study of thermal decomposition at a GC injector in an analysis of PBDDs/PBDFs by high-resolution GC/MS

Jun Onodera、Yoshihisa Ueda、Jaewon Choi 等 7 位作者2003-01-01BUNSEKI KAGAKU

今回著者らは高分解能ガスクロマトグラフィー/質量分析法(GC/MS)を用いた臭素化ダイオキシン類の測定におけるスプリットレス注入法による注入時の熱分解反応について検討した.その結果,臭素化ダイオキシン類の測定において,GC注入口における十分な気化効率保持のための全温度範囲で,臭素化ダイオキシン類の脱臭素化体化合物が検出された.これらは得られたマススペクトルやGC保持時間及びクロマトピーク波形等の情報から考えて,注入時の瞬間気化時の熱分解反応生成物と考えられる.しかし,この熱分解反応は,同一設定及び条件下での異なるシステム間でその反応挙動が異なることも確認された.このことから,注入口内の微妙な環境の相違が,臭素化ダイオキシン類の熱分…

Energetic Materials and CombustionAnalytical Chemistry and ChromatographyThermal and Kinetic Analysis

Amphiphilic porphyrins in reverse micelles: the influence of the molar ratio of water to surfactant and side-chain length on their triplet-state lifetimes. A case studyElectronic supplementary information (ESI) available: Further experimental details. See http://www.rsc.org/suppdata/cp/b3/b302607h/

Junhua Yu、Xuesong Wang、Baowen Zhang 等 7 位作者2003-01-01Physical Chemistry Chemical Physics

Using bis(2-ethylhexyl) sodium sulfosuccinate (AOT) as surfactant, a series of amphiphilic porphyrins terminated with imidazole were studied in AOT/isooctane/water reverse micelles, intending to mimic the relationship between microenvironments in organisms and the amphiphilic properties of porphyrins for photodynamic…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Localization of plastic deformations as a result of wave interaction

Adam Glema、Tomasz Łodygowski、P. Perzyna2003-01-01DOAJ (DOAJ: Directory of Open Access Journals)

The main objective of the paper is the investigation of the interaction and reflection of elastic-viscoplastic waves which can lead to localization phenomena in solids. The rate type constitutive structure for an elastic-viscoplastic material with thermomechanical coupling is used. An adiabatic inelastic flow process…

Engineering Technology and MethodologiesEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Promoted Ignition and Burning Tests of Stainless Steel in Flowing and Nonflowing Oxygen

ET Forsyth、Marc A. Maes、JM Stoltzfus 等 4 位作者2003-01-01OpenAlex

The Industry-Sponsored Metals Combustion Test Program 96-1 was coordinated through Wendell Hull & Associates, Inc., on behalf of several contributing companies, and all design and testing was performed at the NASA White Sands Test Facility. Phase I of this test program studied the threshold pressure for self-susta…

Fire effects on concrete materialsEngineering and Material Science Research

Trivalent passivation of plated zinc and zinc alloys—alternatives to hexavalent based systems

A.R. Gardner、J.E. Scharf2003-01-01Transactions of the IMF

SUMMARYHexavalent chrome passivates have been used for improving the corrosion resistance of sacrificial zinc and zinc alloy coatings on ferrous substrates for many years now. However, forthcoming legislation and corporate policies are beginning to curtail the use of hexavalent chrome compounds and replacements are ac…

Anodic Oxide Films and Nanostructures

Expanding fracture of steel cylinder shell by detonation driving

Tang Tie-gang2003-01-01Baozha yu chongji

The high-speed photography has been applied to observe the expanding fracture of the steel cylinder shells, drive which by detonation. The clear photos of expanding process of steel cylinder shells have been obtained. The fracture strain of the expanding steel shell becomes larger when the strain rate increase to arou…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsAdvanced Measurement and Detection Methods

Effects of load mode on mechanical properties of ZrO2 (2Y)/TRIP steel composites

Zhou Yu、郭英奎、李冬波 等 4 位作者2003-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

The ZrO 2 (2Y)/TRIP steel composites were prepared by vacuum hot pressing sintering. The room temperature static tensile and dynamic yield strength were tested using the static tensile and Split Hopkinson Pressure Bar methods, respectively. The effects of load mode on the static and dynamic mechanical behaviors were s…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Current situation of titanium alloy materials used for national aviation

QU Heng-lei2003-01-01Hangkong cailiao xuebao

The research on titanium alloy materials is paid great attention. This paper review the current situation of titanium alloys developed by the materials research units in recent years, including high temperature titanium alloys, titanium matrix composites, high strength and high toughness titanium alloys, fire resistan…

Titanium Alloys Microstructure and PropertiesMaterial Properties and ApplicationsMechanical Failure Analysis and Simulation

STUDY ON FACTORS AFFECTING ABLATIVE PERFORMANCE OF C/C COMPOSITES

Changle Chen2003-01-01Carbon

Based on material property, macro and micro factors affecting ablative performance of C/C composites for SRM nozzle throat are discussed. Their inter-influences are also analyzed.

Advanced ceramic materials synthesisHigh-Velocity Impact and Material BehaviorSilicone and Siloxane Chemistry

Concrete deterioration by golden mussels

Míriam Pérez2003-01-01OpenAlex

The International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM) was founded with the aim to promote scientific cooperation in the area of construction materials and structures worldwide. This mission is achieved through collaboration of leading experts in construction prac…

Surface Modification and Superhydrophobicity