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Cluster Approximations for Order-Disorder-Type Hydrogen-Bonded Ferroelectrics. II. Application to KH2PO4

R. Blinc、S. Svetina1966-07-15Physical Review

A four-particle cluster approximation is worked out for the free energy of ferroelectric K${\mathrm{H}}_{2}$P${\mathrm{O}}_{4}$, taking into account the overlap of the protonic wave functions between the two sites in a hydrogen bond as well as short-range and long-range forces and a part of the proton-lattice interact…

Crystallography and molecular interactionsSolid-state spectroscopy and crystallographyMolecular Spectroscopy and Structure

Faraday Effect of Charge-Transfer Transitions in Fe(CN)63−, MnO4−, and CrO42−

P. N. Schatz、Anthony J. McCaffery、W. Suëtaka 等 6 位作者1966-07-15The Journal of Chemical Physics

Measurements of the magneto-optical rotatory dispersion (MORD) and magnetic circular dichroism (MCD) through the accessible charge-transfer bands of Fe(CN)63−, MnO4−, and CrO42− in the visible and ultraviolet are described and interpreted. The apparatus employed combines a superconducting solenoid furnishing maximum f…

Magnetism in coordination complexesElectron Spin Resonance StudiesMolecular spectroscopy and chirality

Spin-Density Oscillations in Ferromagnetic Alloys. I. "Localized" Solute Atoms: Al, Si, Mn, V, and Cr in Fe

Mary Beth Stearns1966-07-15Physical Review

The internal magnetic fields and isomer shifts of ${\mathrm{Fe}}^{57}$ nuclei in a number of iron-rich bcc binary alloy systems were measured by the M\"ossbauer technique. The added solute atoms Al, Si, Mn, Cr, or V give structure to the individual lines of the spectra indicating that their effects are quite localized…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Lowest4f→5dTransition of Trivalent Rare-Earth Ions in CaF2Crystals

Eugene Loh1966-07-08Physical Review

The lowest $4f\ensuremath{\rightarrow}5d$ ultraviolet absorption band of eleven (Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb) of the fourteen trivalent rare-earth (RE) ions in host Ca${\mathrm{F}}_{2}$ crystals has been measured. The room temperature absorption cross section [${\mathrm{cm}}^{2}$] and half-width [${…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsInorganic Fluorides and Related Compounds

Relaxation of Disulfide and Tetrasulfide Polymers

A. V. Tobolsky、W. J. MacKnight、Masato Takahashi1966-07-01Rubber Chemistry and Technology

Abstract The chemorheology of crosslinked polyethylene disulfide, polyethylene tetrasulfide, and mixtures of these polymers with elemental sulfur is investigated. It is shown that stress decay in the disulfide polymer occurs by scission of the small quantities of higher polysulfide linkages present in the network. It…

Structural mechanics and materialsMaterial Properties and Failure MechanismsPolymer Science and Applications

Microtexture and Composition of Reaction Products in the System Kaolin–Lime–Water

W C Ormsby、L. H. Bolz1966-07-01Journal of the American Ceramic Society

Textural and compositional features of reaction products in the system kaolin–lime–water were examined by electron microscopy and electron diffraction. Electron micrographs of replicas of fracture surfaces of compacted mixtures and transmission electron micrographs of powdered compacts showed considerable attack of ka…

Hydrocarbon exploration and reservoir analysisSoil and Unsaturated FlowClay minerals and soil interactions

Dynamic Penetration of Selected Projectiles into Particulate Media

Louis J. Thompson1966-07-01Defense Technical Information Center (DTIC)

This is an overall study of the whole process of projectile penetration into soil. The governing differential equations for the soil target medium are developed using the equations of motion and the continuity condition. Constitutive relationships are derived from Mohr-Coulomb theory for a rigid plastic material and f…

High-Velocity Impact and Material BehaviorSports Dynamics and BiomechanicsGeotechnical and Geomechanical Engineering

Exchange-coupled F-centre pairs in magnesium oxide

B. Henderson1966-07-01British Journal of Applied Physics

Exchange-coupled F-centre pairs have been observed in neutron-irradiated magnesium oxide by paramagnetic resonance. Studies of the temperature dependence of the signal intensity indicate that the exchange energy J/k = 80 ± 10°K. The measured spin-Hamiltonian parameters are consistent with the pair of F centres being i…

High-pressure geophysics and materialsSolid-state spectroscopy and crystallographyNuclear materials and radiation effects

ANOMALOUS IMAGES IN ELECTRON MICROSCOPY

K. G. McIntyre、L. M. Brown1966-07-01Le Journal de Physique Colloques

Calculations of the diffraction contrast to be expected from spherical precipitates and prismatic dislocation loops are reported. If these defects lie close to a foil surface, the effect of the free surface on the image is important. In each case, there exists a certain critical strength of the defect, such that if th…

Electron and X-Ray Spectroscopy Techniques

Kristalline Korrosionsschichten und Korrosionsschutzschichten auf Metallen und ihre Beziehung zur Epitaxie

A. Neuhaus、M. Gebhardt1966-07-01Materials and Corrosion

Abstract Auf Grund vielfach eigener Untersuchungen wird berichtet über: Bildungsbedingungen, Phasenbestände und Epitaxie‐Topotaxie‐Beziehungen von Schichten der atmosphärischen Korrosion, des Angriffs durch Industrieluft mit ihren vielfältigen Reagenzien, des Salzwasser‐, Heißwasser‐ und Heißdampfangriffs und der Hoch…

Corrosion Behavior and Inhibition

Thermal Conductivity of SnTe between 100° and 500°K

D. H. Damon1966-07-01Journal of Applied Physics

The thermal conductivity, electrical conductivity, and Seebeck coefficient of several specimens of SnTe have been measured between 100° and 500°K. The thermal conductivity is weakly dependent on both temperature and hole concentration. The total thermal conductivity is separated into an electronic and a lattice therma…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity

The measurement of orientation distribution and its application to quantitative X-ray diffraction analysis

R. M. Taylor、K. Norrish1966-07-01Clay Minerals

Abstract Using X-ray techniques, the orientation distributions of crystal planes in laboratory prepared and naturally occurring aggregates were measured. A small specimen was mounted on the axis of a goniometer and the diffracted intensity measured as the specimen was rotated. Mo radiation was used to reduce the absor…

Concrete and Cement Materials ResearchClay minerals and soil interactionsX-ray Diffraction in Crystallography

Über eine Reihe isotyper Erdalkaliboratphosphate und ‐arsenate vom Typus 2MeO · X2O5 · B2O3. II. Die Verbindungen 2BaO · P2O5 · B2O3 und 2BaO · As2 O5 · B2O3

H. Bauer1966-07-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die thermische Darstellung der Verbindungen 2BaO · P 2 O 5 · B 2 O 3 und 2BaO · As 2 O 5 · B 2 O 3 wird beschrieben. Sie sind isotyp mit den früher beschriebenen analogen Calcium‐ und Strontiumverbindungen und schmelzen wie diese inkongruent. Die röntgekristallographischen Daten der nunmehr bekannten 6 Verbin…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

The Amino Acid Composition of Algal Cell Walls

Thomas Punnett、E. C. Derrenbacker1966-07-01Journal of General Microbiology

Summary: The cell walls of six different species of algae were prepared in highly purified form and their amino acid and amino sugar contents determined qualitatively. A limited number of ninhydrin-positive components was found, implying that the walls contain peptide rather than protein. In five of the algal walls, t…

Marine and coastal ecosystemsAlgal biology and biofuel productionDiatoms and Algae Research

Electron Paramagnetic Resonance and Optical Zeeman Spectra of Type II CaF2:Er3+

C. W. Rector、Bipin C. Pandey、H. W. Moos1966-07-01The Journal of Chemical Physics

A study was made of the EPR and optical spectra of trivalent erbium in Type II crystals of calcium fluoride. The EPR spectrum disclosed the existence of cubic, tetragonal, and trigonal sites in the approximate ratios 15:20:1. The splitting values agreed with those of Ranon and Low. The optical spectrum consisted predo…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsGlass properties and applications

Trigonal Bipyramidal Complexes of Bivalent Manganese, Iron, and Zinc with Tris (2-dimethylaminoethyl)amine

Mario Ciampolini、N. NARDI1966-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTrigonal Bipyramidal Complexes of Bivalent Manganese, Iron, and Zinc with Tris (2-dimethylaminoethyl)amineM. Ciampolini and N. NardiCite this: Inorg. Chem. 1966, 5, 7, 1150–1154Publication Date (Print):July 1, 1966Publication History Published online1 May 2002Published iniss…

Magnetism in coordination complexesLanthanide and Transition Metal Complexes

SNAP 8 reactor and shield designs and operating experience.

C. E. Johnson、Donna Mason1966-07-01Journal of Spacecraft and Rockets

Covers advancements in spacecraft and tactical and strategic missile systems, including subsystem design and application, mission design and analysis, materials and structures, developments in space sciences, space processing and manufacturing, space operations, and applications of space technologies to other fields.

Planetary Science and ExplorationGraphite, nuclear technology, radiation studies

Elongation at Break as a Measure of Cross-Link Density in Vulcanized Elastomers

E. DiGiulio、G. Bellini、G. V. Giandinoto1966-07-01Rubber Chemistry and Technology

Abstract After recalling the reaction mechanism suggested for the crosslinking of ethylene propylene copolymers with organic peroxides, the authors consider the relation between concentration of curing agent and crosslink density. It is experimentally found that, as a first approximation, the elongation ratio at break…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSilicone and Siloxane Chemistry

THE EFFECT OF DISLOCATIONS ON THE MAGNETIZATION CURVESOF FERROMAGNETIC CRYSTALS

A. Seeger1966-07-01Le Journal de Physique Colloques

The principal interaction between dislocations and the direction of magnetization in ferromagnets is due to the magnetoelastic (magnetostrictive) effect. After a brief historical survey, the following subjects are considered : I. The approach to ferromagnetic saturation. Susceptibility measurements in this range const…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

The Promotion of a Nickel Catalyst by Electronic Interaction with Germanium Supports

Raymond F. Baddour、Max C. Deibert1966-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Promotion of a Nickel Catalyst by Electronic Interaction with Germanium SupportsRaymond F. Baddour and Max C. DeibertCite this: J. Phys. Chem. 1966, 70, 7, 2173–2181Publication Date (Print):July 1, 1966Publication History Published online1 May 2002Published inissue 1 Jul…

Catalytic Processes in Materials Sciencenanoparticles nucleation surface interactionsAdvanced Materials Characterization Techniques