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Mechanical Degradation of Polymers

Colin Booth1965-07-01Rubber Chemistry and Technology

Abstract A sample of polyisoprene having a narrow molecular weight distribution has been degraded mechanically in several ways and molecular weight distributions of the degradation products have been determined. From these data we conclude that chain scission occurs at a point far removed from the ends, but not necess…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

On the Polymorphic Modifications of Phthalocyanines

Jacques M. Assour1965-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOn the Polymorphic Modifications of PhthalocyaninesJacques M. AssourCite this: J. Phys. Chem. 1965, 69, 7, 2295–2299Publication Date (Print):July 1, 1965Publication History Published online1 May 2002Published inissue 1 July 1965https://pubs.acs.org/doi/10.1021/j100891a026htt…

Porphyrin and Phthalocyanine ChemistryOrganic Chemistry Cycloaddition Reactions

Thermomagnetic effects in semiconductors and semimetals

R T Delves1965-07-01Reports on Progress in Physics

The principal thermomagnetic effects in semiconductors and semimetals are discussed, with emphasis on the physical processes which affect the transport coefficients. The Seebeck, Nernst, Righi-Leduc, Peltier, Ettingshausen and magnetothermal resistance coefficients are defined and the Kelvin-Onsager relations between…

Graphene research and applicationsThermal properties of materialsAdvanced Thermodynamics and Statistical Mechanics

Method for the Measurement of the Pyroelectric Coefficient, dc Dielectric Constant, and Volume Resistivity of a Polar Material

Sidney B. Lang、Frank Steckel1965-07-01Review of Scientific Instruments

A method is described for measuring the pyroelectric coefficient, dc dielectric constant, and volume resistivity of a polar material over a broad temperature range. The technique is based on the observation of the capacitive charging of a pyroelectric sample by the pyroelectric current generated during a continuous te…

Ferroelectric and Piezoelectric MaterialsStructural Health Monitoring TechniquesSolid-state spectroscopy and crystallography

The stacking-fault energy of F.C.C. metals

I. L. Dillamore、R.E. Smallman1965-07-01Philosophical magazine

The determination of stacking-fault energy from the dimensions of stacking-fault tetrahedra is critically examined and the results compared with those obtained by other methods. It is concluded that the dimensions of stacking-fault tetrahedra do not provide a reliable measure of stacking-fault energy. New values of th…

Microstructure and mechanical propertiesX-ray Diffraction in CrystallographySurface and Thin Film Phenomena

Crystallization kinetics and polymorphic transformations in polybutene-1

Joseph R. Powers、John Hoffman、James J. Weeks 等 4 位作者1965-07-01Journal of Research of the National Bureau of Standards Section A Physics and Chemistry

\ Vh e n s u bcooled fro m the m elt to any tempera t ure between abou t 90 t o lJ 0 C, polybu te l1!'-l tra nsform s at a r eadily m eas ura ble rate to a cr ys talline phase de noted "form 2," wh ich is t yp ically sphe ruli t ic. The kinetics of this process have bee n m eas ured by op t ical and d ihtometric t ech…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermal expansion of magnetic metals at low temperatures

G. K. White1965-07-01Proceedings of the Physical Society

Measurements have been made from 2 to 30 °K and 60 to 90 °K of the thermal expansion of iron, cobalt and nickel, which show that the Grüneisen parameter γ l for the lattice decreases slightly at low temperatures and that the electronic parameter γ e (calculated from the ratio of the electronic contributions to expansi…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Slip line and dislocation structures in fatigued copper

C Michael Roberts、A. P. Greenough1965-07-01Philosophical magazine

Large grained long life push-pull fatigue specimens of 99-999% purity copper have been examined at 10% and 50% of the expected life. Carbon replicas of slip striations were examined, interference microscopy was used to measure the displacement across the striations and dislocation structure was examined by transmissio…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFatigue and fracture mechanics

On the formation of interstitial loops in b.c.c. metals

B.L. Eyre、R. Bullough1965-07-01Philosophical magazine

Two types of interstitial loops with Burgers vector b = a/2<111> and b = a<100>, respectively, have been observed experimentally in irradiated b.c.c. metals. The present paper discusses how these loops can form from a common loop nucleus consisting of a single platelet of interstitials on a {110} plane. Such a loop co…

Microstructure and mechanical propertiesFusion materials and technologiesIon-surface interactions and analysis

Studies on melt spinning. I. Fundamental equations on the dynamics of melt spinning

Susumu Kase、Tatsuki Matsuo1965-07-01Journal of Polymer Science Part A General Papers

Abstract The dynamics of melt spinning was analyzed by deriving a set of simultaneous partial differential equations. Equation of heat balance: Equation of force balance: Equation of material balance: In the above equations, the distance x from the spinneret and time τ are the independent variables; temperature t , lo…

Textile materials and evaluations

Characteristic fluorescence corrections in electron-probe microanalysis

S. J. B. Reed1965-07-01British Journal of Applied Physics

A method has been developed for calculating characteristic fluorescence corrections in all cases involving K and L lines, based on the formula derived by Castaing for the case of one K line exciting another K line. A modification to the original formula is proposed, which takes into account more recent work on K line…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Infrared Spectra between 100 and 2500 Cm.-1 of Some Complex Metal Cyanates, Thiocyanates, and Selenocyanates

Antonio Sabatini、Ivano Bertini1965-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInfrared Spectra between 100 and 2500 Cm.-1 of Some Complex Metal Cyanates, Thiocyanates, and SelenocyanatesA. Sabatini and I. BertiniCite this: Inorg. Chem. 1965, 4, 7, 959–961Publication Date (Print):July 1, 1965Publication History Published online1 May 2002Published iniss…

Solid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Polymerization of adsorbed monolayers. II. Thermal degradation of the inserted polymer

A. Blumstein1965-07-01Journal of Polymer Science Part A General Papers

Abstract Monomolecular layers of methyl methacrylate inserted between the lamellae of montmorillonite clay were polymerized. Finely divided complexes of poly(methyl methacrylate)–montmorillonite were suspended in boiling hydrocarbons and subjected to thermal degradation at 215°C. and above, under air and nitrogen, wit…

Polymer Nanocomposites and PropertiesMolecular Junctions and NanostructuresSynthesis and properties of polymers

Principles of the Theory of Solids

George Saunders1965-07-01OpenAlex

J. M. Ziman London: Cambridge University Press. 1964. Pp. 360. Price 45s. This book is essentially an account of the consequences of the lattice periodicity in solids. Much of the ground was well tilled in the author's treatise Electrons and Phonons (Oxford: The Clarendon Press, 1962) but, as a textbook, the new work…

Metallurgical and Alloy Processes

Fabric and Mineral Analysis of Soils

ROY BREWER1965-07-01OpenAlex

Fabric and mineral analysis of soils , Fabric and mineral analysis of soils , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی

Textile materials and evaluationsSoil Mechanics and Vehicle DynamicsAeolian processes and effects

On the Temperature Dependence of Cooperative Relaxation Properties in Glass-Forming Liquids

Gerold Adam、Julian H. Gibbs1965-07-01OpenAlex

A molecular-kinetic theory, which explains the temperature dependence of relaxation behavior in glass-forming liquids in terms of the temperature variation of the size of the cooperatively rearranging region, is presented. The size of this cooperatively rearranging region is shown to be determined by configuration res…

Material Dynamics and PropertiesGlass properties and applicationsThermodynamic properties of mixtures

Copolymerization of phenyl isocyanate with ethylene oxide

Junji Furukawa、Shinzo Yamashita、Motokazu Maruhashi 等 4 位作者1965-06-30Die Makromolekulare Chemie

Abstract Copolymerization of phenyl isocyanate with ethylene oxide was investigated under several conditions. The polymers obtained with AlEt 3 alone or the AlEt 3 ‐H 2 O system as catalyst were found to be composed of two types, that is polyethylene oxide and alternate copolymer of phenyl isocyanate with ethylene oxi…

Silicone and Siloxane Chemistry

Temperature and molecular weight dependence of the melt viscosity of polyethylene oxide in bulk

Akio Teŕamoto、Hiroshi Fujita1965-06-30Die Makromolekulare Chemie

Abstract Isothermal viscosities η (at low shear rates) of polyethylene oxide fractions and blends were measured in the range from the monomer (glycol) to a molecular weight of about 10 5 and at a number of temperatures between 9 and 155°C. The fashion in which η varied with temperature was independent of molecular wei…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

COMBINED RESONANCE IN SEMICONDUCTORS

É. I. Rashba1965-06-30Soviet Physics Uspekhi

CONTENTS 1. Influence of Spin–orbit Interaction on Resonance Effects 823 2. Combined Resonance with Band Carriers (General Analysis) 824 3. Combined Resonance with Band Carriers in Crystals of Different Symmetry. Discussion of First Experimental Results 828 4. Combined Resonance with Bound Carriers (General Analysis)…

Semiconductor Quantum Structures and DevicesSolid-state spectroscopy and crystallographyMagneto-Optical Properties and Applications

Effect of thermal diffuse scattering on propagation of high energy electrons through crystals

C. R. Hall、P. B. Hirsch1965-06-22Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract A simple theory is developed for calculating the contribution from thermal diffuse scattering to the absorption of high energy electrons passing through crystals. The Einstein model for a vibrating crystal is used and the incident wave is assumed to be a Bloch wave, the thermally diffuse scattered wave to be…

Nuclear Physics and ApplicationsElectron and X-Ray Spectroscopy TechniquesCrystallography and Radiation Phenomena