Materials Literature
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Electronic state calculations are performed self-consistently using the extended Hückel-type nonorthogonal tight-binding method for two different oxygen configurations (backbonded and double-bonded oxygen configurations) on the H-covered surface of spherical Si35H36, Si47H60, Si71H84, Si136H120, Si148H120, and Si172H1…
Temperature-dependent resistivity, thermoelectric power, and magnetoresistance (MR) are investigated in YBa2Cu3O7∕La0.7Sr0.3MnO3 (YBCO/LSMO) bilayers with the thickness of YBCO fixed at 150 nm and that of LSMO varying from t=0 to 50 nm. It is found that the onset temperature Tc of the superconducting transition retain…
Comparing the formability with each other, extrusion and various rolling experiments were carried out to make fine-grained AZ31 Mg sheets, and uni-axial tensile tests were carried out at different strain rates and temperatures to investigate the effect of different variables. A warm deep drawing tool setup with heatin…
Magnesium has a hexagonal close-packed crystal structure which makes it more difficult to deform than aluminum. Conventional strip production usually requires several process steps to reach the final strip thickness. Strip casting can reduce some of the process steps and make strip processing simpler and easier, espec…
The $4f$ photoemission spectra of atomically rough $\mathrm{Re}(12\overline{3}1)$ have been measured using synchrotron radiation. A surface core level shift of 0.17 eV towards higher binding energy than the bulk is obtained, and is supported by measurements at different photon energies and emission angles. This surfac…
Thixocasting is a new semi-solid processing route for magnesium alloys; it is claimed that finer microstructures can be produced and as a consequence, better corrosion resistance can be achieved. Therefore, it is of great interest to compare the corrosion properties of two Mg-Zn-RE alloys produced by standard squeeze…
Biologische Template: Diatomeenzellwände wurden mit Metallfilmen überzogen und anschließend aufgelöst, was nanostrukturierte Metallmikroschalen mit den Strukturmerkmalen der Diatomeentemplate lieferte. Wegen ihrer einzigartigen Nanostrukturdetails (siehe Bild) sind diese Mikroschalen nützliche Substrate für die oberfl…
Aluminum arc spray process was employed to form an aluminum coating on AZ31 magnesium alloy substrate. Anti-corrosion property of the Al-coated specimens was evaluated by salt immersion tests and electrochemical tests. There was no apparent inter-layer diffusion or compound layer formation between the aluminum coating…
A novel deep cryogenic treatment is presented to relieve residual stresses in 7050 aluminum alloy parts, in which the parts are submerged in liquid nitrogen and uphill quenched in proprietary QCW-01 quenchant. The optimum parameters of uphill quenching process were concluded in an attempt to combine maximum stress rel…
Neutron diffraction has been used to study the progress of deformation twinning and intergranular strain evolution in extruded magnesium during cyclic and monotonic loading at two temperatures. Differences in the intergranular strains generated during tensile and compressive tests are attributed to the operation of tw…
The electronic structure and the magnetic properties of ${\mathrm{Mn}}_{3}\mathrm{Ga}\mathrm{N}$ are studied as a function of lattice constant and are compared with those of ${\mathrm{Mn}}_{4}\mathrm{N}$. The local moments on the Mn atom in ${\mathrm{Mn}}_{3}\mathrm{Ga}\mathrm{N}$ and the face centered Mn atoms in ${\…
The effect of Jahn-Teller (JT) interactions on specific heat and magnetic properties was studied for the series of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ $(0.55\ensuremath{\leqslant}x\ensuremath{\leqslant}0.87)$ compounds by measurements of specific heat, ultrasonic velocity, an…
Epitaxial (110)(Bi4−xNdx)Ti3O12(x=0–0.73) films with a variety of neodymium content were grown by metal-organic chemical-vapor deposition, and the effects of neodymium content and site occupancy on spontaneous polarization along the a axis were systematically investigated. Raman spectra revealed that the neodymium is…
Integration of Ba1−xSrxTiO3- (BST) based thin films with affordable Si substrates has a potentially significant commercial impact as the demand for high-frequency tunable devices intensifies. Utilizing a coplanar device design we have monolithically integrated, optimized, and fabricated a high-performance composite bi…
Local symmetry breaking in PbxSr1−xTiO3 (PST) solid solutions was revealed by Raman spectroscopy below and above the ferroelectric phase-transition temperature. In the paraelectric phase, local symmetry breaking associated with the polar clusters localized mostly at grain boundaries in ceramic samples leads to the act…
Hot deformation and associated structural changes were studied in compression of a magnesium alloy AZ31 with initial grain sizes (D0) of 22 µm and 90 µm at a temperature of 573K. D0 influences significantly the flow curve and the kinetics of grain refinement during hot deformation. For D0 = 22 µm, grain fragmentation…
There is growing interest in magnesium alloys as structural materials for the automotive, aerospace and electronic industries. However, the corrosion performance of most magnesium alloys is not good enough for the increasingly diverse practical applications. The Cooperative Research Centre for Cast Metals Manufacturin…
Boron solids exhibit a fascinating geometric and electronic structure. The properties of alpha-rhombohedral boron can be significantly changed by the addition of other atomic constituents. It is found that Pauling's bond valence principle plays an important role in designing boron-rich semiconductors. We have designed…
Microwave tunable dielectric properties of strained (001) SrTiO3 thin films epitaxially deposited on (110) DyScO3 substrates were studied for in-plane film orientations ([100], [010], [110], and [−110]). A significant in-plane anisotropy in dielectric constant and tuning was observed in these SrTiO3 films. The highest…
In this study, the heterogeneous uptake of gaseous nitric acid on dolomite, CaMg(CO3)2, and calcite, CaCO3, particles under dry conditions at 296 K was investigated. A Knudsen cell reactor was used to measure heterogeneous uptake coefficients for these reactions. Several different experiments were performed including…