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Dielectric responses of the layered cobalt oxysulfide Sr_2Cu_2CoO_2S_2 with CoO_2 square-planes

S. Okada、I. Terasaki、H. Ooyama 等 4 位作者2004-02-02arXiv

We have studied the dielectric responses of the layered cobalt oxysulfide Sr$_2$Cu$_2$CoO$_2$S$_2$ with the CoO$_2$ square-planes. With decreasing temperature below the Néel temperature, the resistivity increases like a semiconductor, and the thermopower decreases like a metal. The dielectric constant is highly depend…

Materials Science

Biodegradable polymers from organic acids by using activated sludge enriched by aerobic periodic feeding

Davide Dionisi、Mauro Majone、Viviana Papa 等 4 位作者2004-02-02Biotechnology and Bioengineering

This article describes a new process for the production of biopolymers (polyhydroxyalkanoates, PHAs) based on the aerobic enrichment of activated sludge to obtain mixed cultures able to store PHAs at high rates and yields. Enrichment was obtained through the selective pressure established by feeding the carbon source…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Production of an Ultra‐Long‐Lived Charge‐Separated State in a Zinc Chlorin–C60 Dyad by One‐Step Photoinduced Electron Transfer

Kei Ohkubo、Hiroaki Kotani、Jianguo Shao 等 11 位作者2004-02-02Angewandte Chemie International Edition

Long live the state! Photoexcitation of a zinc chlorin–fullerene dyad with a short linkage results in the formation of the ultra-long-lived charge-separated (CS) state by a one-step photoinduced electron transfer without loss of energy, which is inevitable for charge separation by multistep electron-transfer processes…

Porphyrin and Phthalocyanine ChemistryFullerene Chemistry and ApplicationsPhotochemistry and Electron Transfer Studies

2-Dimensional Holographic Grating Formation in Chalcogenide Thin Films

Jung‐Tae Lee、Choel-Ho Yeo、Hong-Bay Chung2004-02-01Transactions on Electrical and Electronic Materials

Amorphous chalcogenide thin films, especially a-(Se, S) based films, exhibit a number of photo-induced phenomena. In this study, we make the As<TEX>$\_$</TEX>40/Ge<TEX>$\_$</TEX>10/Se<TEX>$\_$</TEX>15/S<TEX>$\_$</TEX>35//Ag thin film and then we measure the holographic diffraction efficiency according to thickness of…

Liquid Crystal Research AdvancementsPhotorefractive and Nonlinear OpticsPhase-change materials and chalcogenides

Effect of electron radiation dose on wettability and free surface energy of poly(ethylene terephthalate) film

M. Żenkiewicz2004-02-01Polimery

Results of investigation of the effect of electron radiation dose (up to 500 kGy), generated in linear high voltage accelerator, on the contact angle and surface free energy of poly(ethylene terephthalate) (PET) film were presented. Water, glycerin, formamide, diiodomethane, alpha-bromonaphthalene as well as their two…

Surface Modification and SuperhydrophobicityPolymer crystallization and propertiesPolymer Nanocomposite Synthesis and Irradiation

A fourth-order parabolic equation with a logarithmic nonlinearlity

Ahmed Bonfoh2004-02-01Bulletin of the Australian Mathematical Society

We consider some generalisations of the Cahn—Hilliard equation based on constitutive equations derived by M. Gurtin in (1996) with a logarithmic free energy. Compared to the classical Cahn—Hilliard equation (see [4, 5]), these models take into account the work of internal microforces and the anisotropy of the material…

Solidification and crystal growth phenomenaStability and Controllability of Differential EquationsAdvanced Mathematical Modeling in Engineering

A comparative study of electroluminescence from Ge/SiO 2 and Si/SiO 2 films

MA Shu-yi、Chen Hui、Yong Xiao 等 5 位作者2004-02-01Chinese Physics

Ge/SiO 2 and Si/SiO 2 films were deposited using the two-target alternation magnetron sputtering technique. The Au/Ge/SiO 2 /p-Si and Au/Si/SiO 2 /p-Si structures were fabricated and their electroluminescence (EL) characteristics were comparatively studied. Both Au/Ge/SiO 2 /p-Si and Au/Si/SiO 2 /p-Si structures have…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

The development of high speed steel rolls by extrusion casting

Hanwei Fu、Qiang Xiao、Jianfeng Xing2004-02-01Ironmaking & Steelmaking Processes Products and Applications

Extrusion casting processes are developed for HSS rolls and the effects of the extrusion casting process on the properties of HSS rolls are investigated. It was found that pressure, pressing time and pressing speed are three important factors affecting the shrinkage cavity. At a pouring temperature of 1400–1450°C, a p…

Metallurgy and Material FormingMetal Alloys Wear and PropertiesPolymer Science and Applications

Photoisomerization of Arylstilbazolium Ligands in the Presence of DNA¶

Bernard Juskowiak、Malgorzata Chudak2004-02-01Photochemistry and Photobiology

ABSTRACT The ability of the DNA duplex to behave as an efficient organized medium for trans‐cis photoisomerization has been explored. The presence of DNA affected isomerization in a variety of ways depending on the aryl moiety properties of the ligand and its DNA‐binding mode. Contrary to intercalating ligands, 9‐[2‐(…

DNA and Nucleic Acid ChemistryRadical Photochemical ReactionsPhotochromic and Fluorescence Chemistry

Chemical composition distribution of multicomponent copolymer chains

Siripon Anantawaraskul、João B. P. Soares、Paula M. Wood‐Adams2004-02-01Macromolecular Symposia

Abstract Probability theory was used to model the microstructure of copolymer chains. Specifically, we derived analytical expressions to describe the chemical composition distribution of multicomponent random copolymers and the longest monomer sequence length distribution of binary copolymers. The results agree with S…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsMachine Learning in Materials Science

Instability of Eu2+/Eu3+ photoluminescence in X-irradiated CaSO4:Eu3+

D. Lapraz、H. Prévost、A. Lakshmanan2004-02-01physica status solidi (a)

The photoluminescence (PL) properties of a calcium sulphate doped only with trivalent europium are studied before and after X-irradiation. On X-irradiation, a high Eu2+ emission appears clearly, with a simultaneous decrease of the Eu3+ PL intensity. The Eu2+/ Eu3+ PL intensity ratio increases as a function of X-air ke…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesRadiation Effects and Dosimetry

Mixed Cationic‐nonionic Surfactants and pH Adjustment Route to Synthesize High‐quality MCM‐48

Shangru Zhai、Yanjun Gong、Ye Zhang 等 7 位作者2004-02-01Journal of the Chinese Chemical Society

Abstract Using the mixture of cetyltrimethylammonium bromide (CTAB) and p‐Octyl polyethylene glycol phenyl ether (OP‐10) as templates, siliceous MCM‐48 materials can be synthesized with low molar ratio of CTAB to silica (0.139:1) and low concentration of mixed surfactants ( ca .5%) and within a wide range of OP‐10/CTA…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Amino Acid Residues in RAG1 Responsible for the Interaction with RAG2 during the V(D)J Recombination Process

Jung Eun Ko、Choong Won Kim、Deok Ryong Kim2004-02-01Journal of Biological Chemistry

The V(D)J recombinase, a complex of RAG1 and RAG2, carries out a gene rearrangement process that is required for the achievement of diverse antigen receptor repertoires during the early developmental stage of lymphocytes. It recognizes a specific site spanning the coding DNA region of antigen receptor genes and produc…

DNA Repair MechanismsEnzyme Structure and FunctionBiochemical and Molecular Research

Thermal destruction of two-dimensional graphite islands on refractory metals (Ir, Re, Ni, and Pt)

N. R. Gall、N. P. Lavrovskaya、E. V. Rut’kov 等 4 位作者2004-02-01Technical Physics

Thermal destruction of two-dimensional graphite films on Ni(111), Re(10-10), Ir(111), and Pt(111) substrates is studied. It is shown that the detachment of an edge carbon atom from an island is a limiting process stage for all the cases. The activation energy of this process varies from 2.5 eV for nickel to 4.5 eV for…

Graphene research and applicationsFullerene Chemistry and ApplicationsGraphite, nuclear technology, radiation studies

Fine Count Yarn Spun with a High Draft Ratio

Ching‐Iuan Su、Jau-Yuan Jiang2004-02-01Textile Research Journal

We investigate the improvement of 5.90 tex cotton yarn spun with a high total draft ratio of 100 on a modified apron drafting system. For optimum drafting conditions of 5.90 tex spun yarn spinning, the application of drafting force has to be considered during roller drafting. We examine the influence of roller gauge a…

Textile materials and evaluationsResearch in Cotton Cultivation

The permittivity of a monatomic gas with spatial dispersion

V. P. Makarov、A. A. Rukhadze2004-02-01Journal of Experimental and Theoretical Physics

The longitudinal, ε l (ω, k ), and transverse, ε tr (ω, k ), permittivities of a monatomic gas were calculated. The frequency ranges in which the permittivity ε(ω) and permeability μ(ω) of a gas without spatial dispersion have a physical meaning were determined. The limiting magnetic susceptibility χ(ω) at ω=0 and the…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAcoustic Wave Phenomena Research

UHF Diagnostic Monitoring Techniques for Power Transformers

M.D. Judd、Yang Li、C.J. Bennoch 等 4 位作者2004-02-01Strathprints: The University of Strathclyde institutional repository (University of Strathclyde)

This paper initially gives an introduction to ultra-high frequency (UHF) partial discharge monitoring techniques and their application to gas insulated substations. Recent advances in the technique, covering its application to power transformers, are then discussed and illustrated by means of four site trials. Mountin…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Corrosion inhibition of mild steel in hydrochloric acid solutions by malonitrile compounds

S. Elayyoubi、B. Hammouti、S. Kertit 等 5 位作者2004-02-01Revue de Métallurgie

p-methoxy benzylidene malonitrile (MN1) and p-hydroxy benzylidene malonitrile (MN2) were synthesized and tested as inhibitors for the corrosion of mild steel in molar HCl. We have found that both of them inhibit the corrosion. The maximum inhibition efficiency reached 100% for MN1 at 10-4 M and for MN2 at 10-3 M. Curr…

Corrosion Behavior and InhibitionInorganic and Organometallic ChemistryConcrete Corrosion and Durability

Octasilsesquioxane Chemistry II. Hydrosilylation Reaction of Octa(hydrido)silsesquioxane with Unsaturated Substrates and Product Properties

Ling‐Kang Liu、Enock Olugbenga Dare2004-02-01Journal of the Chinese Chemical Society

Abstract The hydrosilylation reaction of octa(hydrido)silsesquioxane with ω‐halo‐1‐alkenes and other unsaturated substrates allows attachment of 8 long‐chain functionalized alkyls on the cubic Si 8 O 12 skeleton. Pt/C and H 2 PtCl 6 have been adopted as the catalysts, the yields being 74–98% for compounds 2–9 . For te…

Advanced ceramic materials synthesisSynthesis and characterization of novel inorganic/organometallic compoundsSilicone and Siloxane Chemistry

Heat resistance and thermomechanical behaviour of ultralow and zero cement castables

N.M. Khalil2004-02-01British Ceramic Transactions

Knowledge of relative heat resistance as well as thermo-mechanical behaviour of refractory castables is very important for their use as linings in high temperature furnaces and refining vessels in the metallurgical, cement, and petrochemical industries. The present work aims at studying these properties for different…

Advanced ceramic materials synthesisLayered Double Hydroxides Synthesis and ApplicationsAdvanced materials and composites