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Ceramic foams from preceramic polymers

Paolo Colombo、John R. Hellmann2002-12-01Materials Research Innovations

The direct foaming of preceramic polymer mixtures, followed by high temperature pyrolysis in an inert atmosphere, can be employed to fabricate ceramic foams with impressive strength, stiffness, thermome-chanical and thermochemical durability, and electromagnetic properties. Flexural strength and stiffness were superio…

Advanced ceramic materials synthesisPolymer Foaming and CompositesAdvanced materials and composites

Stress-Induced Crystallization around a Crack Tip in Natural Rubber

Siwar Trabelsi、Pierre‐Antoine Albouy、J. Rault2002-12-01Macromolecules

Stress-induced crystallization, orientation, and crystallinity have been measured by X-ray diffraction around cracks in a cis- 1,4-polyisoprene sample drawn at low ratio, λ < 3.5. A zone of maximum crystallinity and a transition zone of varying crystallinity are observed; the dimensions of these semicrystalline zones…

Polymer Nanocomposites and PropertiesPolymer crystallization and propertiesRheology and Fluid Dynamics Studies

The influence of structural Fe, Al and Mg on the infrared OH bands in spectra of dioctahedral smectites

J. L. Bishop、Jana Madejová、Peter Komadel 等 4 位作者2002-12-01Clay Minerals

Abstract Visible to near-infrared (NIR) reflectance spectra and mid-IR transmittance spectra are presented here for a collection of dioctahedral smectites. Analysis of the structural OH vibrations is performed by comparing the NIR combination and overtone bands with fundamental stretching and bending absorption featur…

Geochemistry and Geologic MappingGeological and Geochemical AnalysisClay minerals and soil interactions

Mechanical properties of Al 2 O 3 /polymethylmethacrylate nanocomposites

Benjamin J. Ash、Diana F. Rogers、Christopher J. Wiegand 等 7 位作者2002-12-01Polymer Composites

Abstract Alumina/polymethylmethacrylate (PMMA) nanocomposites were produced by incorporating alumina nanoparticles, synthesized using the forced gas condensation method, into methylmethacrylate. The particles were dispersed using sonication and the composites were polymerized using free radical polymerization. At an o…

Material Dynamics and PropertiesPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Compaction dynamics of a granular medium under vertical tapping

Pierre Philippe、Daniel Bideau2002-12-01Europhysics Letters (EPL)

We report new experimental results on granular compaction under consecutive vertical taps. The evolution of the mean volume fraction and of the mean potential energy of a granular packing presents a slow densification until a final steady state, and is reminiscent of usual relaxation in glasses via a stretched exponen…

Theoretical and Computational PhysicsGranular flow and fluidized bedsMaterial Dynamics and Properties

Rare-earth-doped transparent glass ceramics

M. Clara Gonçalves、Luís F. Santos、Rui M. Almeida2002-12-01Comptes Rendus Chimie

Glass ceramics are a known class of polycrystalline ceramic materials, where, depending on the glass matrix and the particular crystalline phases, one can obtain materials with improved mechanical, thermal, electrical or optical properties. The characteristics and applications of optical glass ceramics are reviewed, w…

Glass properties and applicationsLuminescence Properties of Advanced Materials

Rare-earth-doped glasses for fiber amplifiers in broadband telecommunication

Setsuhisa Tanabe2002-12-01Comptes Rendus Chimie

Rare-earth-doped optical amplifiers have a great potential for broadband Wavelength-Division-Multiplexed (WDM) telecommunication by tailoring host glass compositions. In order to design the emission spectra of doped rare-earth ions, it is important to understand the relationship between the local ligand field and vari…

Material Science and ThermodynamicsSolid State Laser TechnologiesGlass properties and applications

Electromigration reliability issues in dual-damascene Cu interconnections

E.T. Ogawa、Ki‐Don Lee、V. Blaschke 等 4 位作者2002-12-01IEEE Transactions on Reliability

Electromigration studies on Cu interconnects are reviewed. Some history and more recent results are discussed along with a description of the present interpretations of the active mass transport mechanisms involved in Cu electromigration. The issue of the dual-damascene process and its potential effect on EM reliabili…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

The Influence of Surface Wettability on the Adhesion Strength of Settled Spores of the Green Alga Enteromorpha and the Diatom Amphora

John A. Finlay2002-12-01Integrative and Comparative Biology

In this paper we report on the effect of surface wettability on surface selection and adhesion properties of settled (adhered) spores of the biofouling marine alga Enteromorpha and cells of the diatom Amphora, through the use of patterned self-assembled monolayers (SAMs). The SAMs were formed from alkanethiols termina…

Diatoms and Algae ResearchMarine Biology and Ecology ResearchMarine Biology and Environmental Chemistry

Compatibilization of Polymer Blends

Leszek A. Utracki2002-12-01The Canadian Journal of Chemical Engineering

Abstract Most polymer blends are immiscible and need to be compatibilized. The compatibilization must accomplish: (i) optimization of the interfacial tension; (ii) stabilize the morphology against high stresses during forming; and (iii) enhance adhesion between the phases in the solid state. Compatibilization is accom…

Additive Manufacturing and 3D Printing TechnologiesPolymer crystallization and propertiesbiodegradable polymer synthesis and properties

Photoreactive Organic Thin Films

作者信息未提供2002-12-01OpenAlex

This volume concentrates on the use of spectroscopic microscopy in the measurement of electrical and optical properties of nanostructures.This is of increasing importance in advanced research and the development of fabrication technologies for semiconductor nanostructures.Chapters deal with electron beam probe spectro…

Photochromic and Fluorescence ChemistryLiquid Crystal Research AdvancementsPhotopolymerization techniques and applications

Cationic charge determines the distribution of liposomes between the vascular and extravascular compartments of tumors.

R. B. Campbell、Dai Fukumura、Edward B. Brown 等 8 位作者2002-12-01OpenAlex

Tumor vessels possess unique physiological features that might be exploited for improving drug delivery. In the present study, we investigate the possibility of modifying polyethylene glycol-ylated liposome cationic charge of polyethylene glycol coated liposomes to optimize delivery to tumor vessels using biodistribut…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsRNA Interference and Gene Delivery

Adhesion a la Moule

J. Herbert Waite2002-12-01OpenAlex

Mussels owe their sessile way of life in the turbulent intertidal zone to adaptive adjustments in the process and biochemistry of permanent attachment. These have understandably attracted scientific interest given that the attachment is rapid, versatile, tough and not subverted by the presence of water. The adhesive p…

Microbial metabolism and enzyme functionbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Macromolecular phasing with SHELXE

George M. Sheldrick2002-12-01OpenAlex

Abstract SHELXE was designed to provide a simple, fast and robust route from substructure sites found by the program SHELXD to an initial electron density map, if possible with an indication as to which heavy-atom enantiomorph is correct. This should be understood as a small contribution to high-throughput structural…

Enzyme Structure and FunctionRNA and protein synthesis mechanismsMass Spectrometry Techniques and Applications

Fluorination of Single-Wall Carbon Nanotubes and Subsequent Derivatization Reactions

Valéry N. Khabashesku、W. E. Billups、John L. Margrave2002-12-01OpenAlex

This Account focuses on the most recent and systematic efforts in the area of functionalization chemistry of the single-wall carbon nanotubes (SWNTs) which utilizes direct fluorination for the preparation of "fluoronanonotubes" and their subsequent derivatization. The results obtained prove that the addition of fluori…

Graphene research and applicationsFullerene Chemistry and ApplicationsCarbon Nanotubes in Composites

Microbial Cellulose Utilization: Fundamentals and Biotechnology

Lee R. Lynd、Paul J. Weimer、Willem H. van Zyl 等 4 位作者2002-12-01OpenAlex

column 1, line 14: "fuels and materials" should read "organic fuels and materials."Page 529, Table 4, line 10: "smithiti" should read "smithii."Page 530, column 2, line 5 from bottom: reference 651 should be deleted.Page 531, Table 5, Binding affinity: for CenA BMCC, "41" and "1.89" should read "8.6" and "0.40," respe…

Biofuel production and bioconversionEnzyme Production and CharacterizationAdvanced Cellulose Research Studies

Electrochemical Sensors Based on Carbon Nanotubes

Qiang Zhao、Zhenhai Gan、Qiankun Zhuang2002-12-01OpenAlex

Abstract Carbon nanotubes are attractive new materials. It has been about a decade since carbon nanotubes were discovered. Carbon nanotubes have many outstanding properties and have many practical or potential applications. In this short review we introduce recent advances in carbon nanotubes as potential material for…

Conducting polymers and applicationsElectrochemical sensors and biosensors

Planar negative refractive index media using periodically L-C loaded transmission lines

George V. Eleftheriades、Ashwin K. Iyer、P.C. Kremer2002-12-01OpenAlex

Recent demonstrations of negative refraction utilize three-dimensional collections of discrete periodic scatterers to synthesize artificial dielectrics with simultaneously negative permittivity and permeability. In this paper, we propose an alternate perspective on the design and function of such materials that exploi…

Metamaterials and Metasurfaces ApplicationsAntenna Design and AnalysisAdvanced Antenna and Metasurface Technologies

Tetrabutylammonium tetrakis(nitrato-κ2O,O′)[1,3,5-tris(pyrazolyl)methane-κ3N]cerate(III)

Shu-Jian Chen、Yi‐Zhi Li、Xue-Tai Chen 等 5 位作者2002-11-30Acta Crystallographica Section E Structure Reports Online

The title complex, (nBu4N)+[(HCPz3)Ce(NO3)4]− or (C16H36N)[Ce(NO3)4(C10H10N6)], which is the first lanthan­ide(III) complex of tris­(pyrazolyl)­methane (HCPz3), is 11-coordinate. The Ce—O and Ce—N bond lengths are in the ranges 2.514 (3)–2.685 (3) and 2.686 (4)–2.761 (4) Å, respectively.

Crystal structures of chemical compoundsMagnetism in coordination complexesLanthanide and Transition Metal Complexes