Materials Literature
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The anodic polarization of chromium and 18Cr-8Ni stainless steel has been investigated in 2 to 48 percent hydrofluoric acid, 40 percent sulfuric acid, and in a solution containing 5 percent hydrofluoric acid and 40 percent sulfuric acid. Chromium can be anodically protected in hydrofluoric acid. The corrosion rate of…
Abstract Polyfunctional monomers such as allyl methacrylate, allyl acrylate, and diallyl maleate have been found to greatly enhance the radiation crosslinking of polyethylene. The radiation dose for incipient gelation is decreased by a factor of approximately 25 by the presence of small amounts of these monomers. The…
The electrode potentials of the system Th, ThCl 4 (KCl, NaCl) were measured at various concentrations of thorium chloride, and at temperatures between 670 °C and 850 °C, using a silver – silver chloride reference electrode. It was shown by a direct gravimetric method that the reaction,Th (metal) + ThCl 4(melt) = 2ThCl…
NaBr.2H20 is monoclinic, P21/c, Z=4, with a=6.575, b=10.456,c=6-776 /~ and fl=113-38 °.The structure agrees very well with that determined independently by Culot, Piret & Van Meersche (1962); the differences are attributed chiefly to different absorption errors.
Dielectric, ferroelectric, and piezoelectric properties were investigated for compositions in the high‐lead hafnate region of the system PbHfO 3 ‐PbTiO 3 ‐PbSnO 3 ‐PbNO 2 O 6 . Phase diagrams were prepared that show the existence of a ferroelectric‐to‐antiferroelectric phase transition with increasing temperature. Fiv…
Three main types of crack formation in plastically deformed MgO crystals have been observed. They are all due to internal stresses of macroscopic character resulting from the difficulty of mutual penetration of perpendicular dislocation bands and the consequent geometrical incompatibilities of plastic deformation. The…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Structures of Nitrogen Oxide-Boron Trifluoride ComplexesJ. C. Evans, H. W. Rinn, S. J. Kuhn, and G. A. OlahCite this: Inorg. Chem. 1964, 3, 6, 857–861Publication Date (Print):June 1, 1964Publication History Published online1 May 2002Published inissue 1 June 1964https://p…
The six complex hexagonal and rhombohedral layer structures known as hexagonal ferrites can be derived by stacking three building-block types, S , R , and T , having 2, 3, and 4 anion layers, respectively. The anion framework of R and T contains stacking reversals after each layer; the stacking sequence of R is 1·1·1,…
ZnS platelets grown from the vapor phase, bounded by (2̄11), (011̄), and (111) faces, were used. The crystals showed birefringence bands perpendicular to the [111] axis. X-ray rotation, oscillation, and Laue photographs showed that the bands are due to changes in crystal structure (cubic, hexagonal, and polytypes) and…
A possible mechanism for uniaxial anisotropy in ferromagnetic films is the magnetoelastic energy Wλ which results from the constraint imposed on the film by the substrate. Below some temperature T′ at which the mobility of the film atoms on the substrate is sufficiently low, the constraint prevents the film from defor…
Regularly interstratified chlorite-vermiculite (1:1) is found as a weathering product of chlorite in a Highfield channery silt loam soil profile in Adams County, Pennsylvania. The parent rock is greenstone, a metamorphosed basalt, composed of chlorite, epidote, alibite and ilmenite. Greenstone fragments in the soil ar…
The relation between the concentration of intrinsic paramagnetic states (the E′ centers) of silica (silica glass) produced by irradiation and the concentration of OH− ions in the silica was investigated by introducing OH− ions into silica, initially free of these ions, in a controlled manner. Optical absorption and el…
The electronic ground state wave functions in FeCO 3 and FeTiO 3 are deduced from the nuclear quadrupole coupling data. With these wave functions, the contribution of the intra atomic magnetic dipolar interaction and that of the electron orbital current effect to the internal magnetic field are calculated. A similar a…
Synthetic single crystals of Fe${\mathrm{Al}}_{2}$${\mathrm{O}}_{4}$ have been grown from the melt. Measurements of the thermal conductivity $K$ and optical absorption coefficient $\ensuremath{\alpha}$ have been made on a combination of synthetic and natural single crystals of ${\mathrm{Mg}}_{1\ensuremath{-}x}{\mathrm…
Polarized crystal-absorption spectra in the near-infrared, visible, and ultraviolet regions are reported for Cs2CuCl4. The near-infrared bands are analyzed on the basis of the known structure of the CuCl4= ion with D2d symmetry. The positions and polarizations of the bands are accounted for and the minor effcets of sp…
Proceedings of the National Academy of Sciences (PNAS), a peer reviewed journal of the National Academy of Sciences (NAS) - an authoritative source of high-impact, original research that broadly spans the biological, physical, and social sciences.
Processes occurring on the surface of iron in contact with an aqueous solution of ammonium nitrate are extremely complex. They greatly depend on the electrode potential. Chemical composition, solubility, structure, thickness, adherence and compactness of solid corrosion products vary within a wide range. Intergranular…
The structure of an authigenic maximum microcline from the Pontiskalk limestone, Switzerland, has been refined to an R value of 8.5% by a full-matrix least-squares program using 797 observed and 207 unobserved reflections. The ordering of tetrahedral Si,Al atoms is nearly complete and there is no significant structura…
Observations have been made of the domain structures on (110) [001] surfaces of grains in 3% silicon-iron sheet when stresses were applied to the sheet. The changes produced by a tension in the [110] direction or a compression in the [001] direction are similar to those observed by Dijkstra and Martius, but a more det…
Homogeneous crystals of Bi-Sb solid solutions are difficult to grow, but are important for the basic understanding of the electron transport properties and band structure of these materials. The problems arise from (1) the low melting temperature (approximately 300°C) which makes it difficult to achieve a large therma…