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Magnetic Susceptibility and Crystal Structure of (Pyridine N-Oxide)-Copper(II) Chloride

Helmut Schäfer、J. C. Morrow、H. M. Smith1965-01-15The Journal of Chemical Physics

Magnetic susceptibility of (pyridine N-oxide)-copper(II) chloride, C5H5NOCuCl2, has been measured by the Faraday method from 90° to 300°K. The magnetic moment decreases rapidly with temperature; the dimeric structure proposed on the basis of magnetic behavior has been confirmed by the results of crystal structure dete…

Metal complexes synthesis and propertiesMagnetism in coordination complexesFree Radicals and Antioxidants

Excitation of Methane, Ethane, Ethylene, Propylene, Acetylene, Propyne, and 1-Butyne by Low-Energy Electron Beams

C. R. Bowman、W. D. Miller1965-01-15The Journal of Chemical Physics

Low-energy inelastic collisions between electrons and hydrocarbon molecules are studied by means of a trapped-electron technique. Excitation spectra are obtained over the subionization energy range for methane, ethane, ethylene, propylene, acetylene, propyne, and 1-butyne. Molecular excitation potentials are measured,…

Advanced Chemical Physics StudiesMass Spectrometry Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Anomalous Thermoluminescent Kinetics of Irradiated Alkali Halides

J. A. Partridge、C. E. May1965-01-15The Journal of Chemical Physics

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation J. A. Partridge, C. E. May; Anomalous Thermoluminescent Kinetics of Irradiated Alkali Halides. J.…

Luminescence Properties of Advanced MaterialsGlass properties and applications

Kinetics of the calcite ⇌ aragonite transformation

Briant L. Davis、L. H. Adams1965-01-15Journal of Geophysical Research Atmospheres

A beryllium pressure vessel mounted in an X-ray diffractometer has been used to study the rates of the transformation calcite ⇌ aragonite at temperatures to 500°C and pressures to 15 kb. The rates of transformation are shown to be both temperature and pressure dependent. It is proposed that the tail-off shown by all r…

High-pressure geophysics and materialsCalcium Carbonate Crystallization and InhibitionThermal and Kinetic Analysis

Kinetic Secondary Electron Ejection from Molybdenum by Cesium Ions

Samuel H. Bosch1965-01-04Physical Review

Secondary electron emission yields have been measured for cesium ions on clean molybdenum as a function of ion kinetic energy for two angles of incidence. For the two incidence angles measured 0 and 40\ifmmode^\circ\else\textdegree\fi{}, the energy threshold was the same, approximately 2 keV. From this threshold there…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Giant Oscillations in the Magnetoacoustic Attenuation of Bismuth

A. M. Toxen、Sabih Tansal1965-01-04Physical Review

Measurements of the magnetoacoustic attenuation of bismuth at temperatures of 1.4-1.8\ifmmode^\circ\else\textdegree\fi{}K in transverse magnetic fields up to 17 kG are reported. For shear waves of frequency 8-40 Mc/sec, propagated in the bisectrix direction, with the magnetic field in the binary direction, oscillation…

High-pressure geophysics and materialsSolid-state spectroscopy and crystallographyThermodynamic and Structural Properties of Metals and Alloys

Spectroscopy of MnO43−in Calcium Halophosphates

J. D. Kingsley、J. S. Prener、B. Segall1965-01-04Physical Review

A study has been made of the optical absorption and fluorescence of the compounds ${\mathrm{Ca}}_{2}$P${\mathrm{O}}_{4}$Cl (spodiosite) and ${\mathrm{Ca}}_{5}$${(\mathrm{P}{\mathrm{O}}_{4})}_{3}$Cl (apatite) doped with ${\mathrm{Mn}}^{5+}$. The ${\mathrm{Mn}}^{5+}$ ion has the electronic configuration $3{d}^{2}$ and i…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Internal Field in General Dipole Lattices

F. W. de Wette、G. E. Schacher1965-01-04Physical Review

The calculation of the internal field in dipole lattices necessitates summing the contributions due to all dipoles in the crystal. These dipole sums are conditionally convergent, which means that they depend on the order of summation (i.e., the shape of the crystal). Rapidly converging expressions for these sums are o…

Electrochemical Analysis and ApplicationsInorganic and Organometallic ChemistrySolid-state spectroscopy and crystallography

Spin-Wave Analysis of the Sublattice Magnetization Behavior of Antiferromagnetic and Ferromagnetic CrCl3

Albert Narath、H. L. Davis1965-01-04Physical Review

The temperature and magnetic-field dependences of the sublattice magnetization in the hexagonal layertype compound Cr${\mathrm{Cl}}_{3}$ (${T}_{N}=16.8\ifmmode^\circ\else\textdegree\fi{}$K) have been deduced from the $^{53}\mathrm{Cr}$ nuclear magnetic resonance (NMR) for $0.4\ensuremath{\le}T\ensuremath{\le}8.1\ifmmo…

Magnetic and transport properties of perovskites and related materialsMagnetism in coordination complexesAdvanced Condensed Matter Physics

Transitional phenomena in α‐polyolefin melts

David L. Beck、A. A. Hiltz1965-01-01Polymer Engineering and Science

Abstract A first order transition was observed in the temperature range of about 210°C by dilatometric studies on both isotactic and atactic polypropylene and for isotactic poly (butene‐1) and poly (pentene‐1). No such transition was observed for polyethylene. It was found that the transition is not due to the measure…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Studies on Atmospheric Corrosion of Steels Related with Meteorological Factors in Japan (2nd Report)

Kazuhiko Oma、Teruz ocirc Sugano、Y ocirc ichi Hirai1965-01-01Corrosion engineering digest

The atmospheric corrosion rates of steel were measured in an industrial district (Kôtô-ku) of Tokyo, Japan.Analyzing correlations between the corrosion rates and meteorological factors and/or atmospheric pollution substance factors by means of statistical analysis method, a corrosion regression was obtained to describ…

Corrosion Behavior and InhibitionInfrastructure Maintenance and MonitoringConcrete Corrosion and Durability

Diffusion-Controlled Attack of Glass Surfaces by Molten Hydroxides

R. F. Bartholomew1965-01-01Journal of The Electrochemical Society

The attack of soda‐lime‐silica, alkali borosilicate, zirconia‐silica and alumina‐silica glasses by sodium hydroxide and potassium hydroxide melts at temperatures just above their melting points has been studied. Sodium hydroxide attack resulted in a frosty layer bound to the surface; potassium hydroxide left a clear s…

Glass properties and applicationsPigment Synthesis and PropertiesMaterial Science and Thermodynamics

The Cellulose/Water Relationship

P. K. Christensen、H. W. Giertz1965-01-01OpenAlex

This paper is a condensed survey of the interactions between water and cellulose materials. It is introduced by some general remarks about the interaction of water with solids, with special attention to hydrogen bonds, solutions and gels, then about the chemical and physical properties of cellulose fibres. The main di…

Advanced Cellulose Research Studies

Raman spectrum of ZnO

S. S. Mitra、James I. Bryant1965-01-01Journal de physique

The Raman spectrum of ZnO single crystals has been studied at room and low temperatures. About fifteen Raman peaks have been observed between 50 and 1 200 cm-1. The infrared reflection and transmission [1] measurements have also been made in the region 250 cm-1 to 1 500 cm-1 . The wurtzite (C46υ) structure has nine op…

Nonlinear Optical Materials ResearchSpectroscopy and Laser ApplicationsOptical Polarization and Ellipsometry

Electrical Resistivity and Thermoelectric Power of Stacking Faults in Gold

Jaroslav Polák1965-01-01physica status solidi (b)

Abstract Pure gold wires are quenched from high temperatures into iced brine and the changes of electrical resistivity and thermoelectric power are measured simultaneously during isochronal annealing. Two recovery stages are found: the first one (at 50 °C) corresponds to vacancy clustering with the formation of stacki…

Electronic Packaging and Soldering TechnologiesThermal properties of materialsnanoparticles nucleation surface interactions

Fission-Product Release from Monogranular UC2 Particles

L.R. Zumwalt、P. E. Gethard、Elmer E. Anderson1965-01-01Nuclear Science and Engineering

The fission-product release of spherical monogranular UC2 particles is studied by postirradiation annealing of neutron-activated samples and by exposing samples to a steady rate of photofission. The release of the several fission products studied appears to follow the kinetics and temperature-dependence of an activate…

Rare-earth and actinide compoundsRadioactive element chemistry and processingNuclear Materials and Properties

On the structure and water content of copper(II) tricyanomethanide

C. Biondi、M. Bonamico、L. Torelli 等 4 位作者1965-01-01Chemical Communications (London)

C. Biondi, M. Bonamico, L. Torelli and A. Vaciago, Chem. Commun. (London), 1965, 191 DOI: 10.1039/C19650000191

Molecular Sensors and Ion DetectionMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry