Materials Literature
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Cauliflower‐like Co 3 O 4 /three‐dimensional (3D) graphene nanocomposite material was synthesized by a facile two‐step synthesis route (heat reduction of graphite oxide (GO) and hydrothermal synthesis of Co 3 O 4 ). The phase composition, morphology, and structure of the as‐obtained products were characterized by scan…
meso-Pyrrolyl boron dipyrromethene (BODIPY) was prepared under simple reaction conditions by using commercially available chemicals. Prior to this work, the BODIPY compound was prepared in multiple steps by using precursors which were not readily available. The X-ray structure of BODIPY revealed that the meso-pyrrole…
Graphene oxide and reduced graphene oxide hybrids with spin crossover complexes show the coexistence of electron conduction and unique magnetic behaviors.
Aqueous foams were produced with partially hydrophobic SiO <sub>2</sub> nanoparticles and sodium dodecyl sulfate (SDS) dispersions.
Cu2ZnSnS4 (CZTS) nanoparticles were synthesized by the precursor injection method using oleylamine as a solvent. Preliminary characterization indicated that the synthesized nanoparticles belonged to the kesterite structure with a bulged sphere-like morphology. Reduced graphene oxide (rGO) was synthesized by an improve…
Three new Mn(III) complexes [Mn2L2(ClO4)2] (1), [Mn2L2(NCS)2] (2) and [Mn2L2N(CN)2]ClO4·CH3CN (3) have been synthesized from the Schiff base ligand H2L (where H2L = N,N′-bis(2-hydroxypropiophenone)-1,2- ethanediamine) and various anionic coligands e.g. perchlorate, thiocyanate and dicyanamide. X-ray crystal structure…
Organic coordinating ligands are ubiquitously used to solubilize, stabilize and functionalize colloidal nanoparticles. Aliphatic organic ligands are typically used to control size during the nanoparticle growth period and are used as a high boiling point solvent for solution-based synthesis procedures. However, these…
Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-sh…
Six isostructural new compounds (La <sub>3</sub> Fe <sub>0.5</sub> GeSe <sub>7</sub> , La <sub>3</sub> MnGaSe <sub>7</sub> , Ce <sub>3</sub> Fe <sub>0.5</sub> SiSe <sub>7</sub> , Ce <sub>3</sub> Mn <sub>0.5</sub> SiSe <sub>7</sub> , Sm <sub>3</sub> Fe <sub>0.5</sub> SiSe <sub>7</sub> and Sm <sub>3</sub> Mn <sub>0.5</s…
Kinked structure improves the photoresponse of nanowire both in photocurrent and response rate.
Fabrication of <italic>in situ</italic> forming and acid-labile prodrug-based supramolecular hydrogels with adjustable gelation time for injectable drug delivery carriers.
We report on Janus subcompartmentalized assemblies with enzyme loaded liposomes entrapped within a polymer carrier capsule - Janus subcompartmentalized microreactors. The concept is based on the use of Pickering emulsions and the subsequent deposition of interacting liposomes and polymer layers. We demonstrate the adj…
Lymphatic metastasis plays an important role in tumour recurrence. The applications of nanoparticles in the treatment of lymphatic metastatic tumours have been limited by targeting inefficiency and nonselective toxicity. Hence, in this report, we have developed lipid-coated ZnO nanoparticles (LZnO NPs) in an attempt t…
n-Alkylamines were grafted on the basal plane oxygen functionalities of graphene oxide (GO), yielding molecular pillar supported graphene oxide frameworks (GOFs) with tunable interlayer spacing. A major fraction of n-alkylamines was found to covalently interact with the basal plane epoxy groups via nucleophilic substi…
A combination of experimental and computational methods was applied to investigate the crystal structure and optoelectronic properties of the non-stoichiometric pyrochlore Bi <sub>2−x</sub> Ti <sub>2</sub> O <sub>7−1.5x</sub> .
Freestanding and flexible asymmetric supercapacitors with good cycling stability.
Heterojunctions composed of single p-type CdS nanoribbons (NRs) and n-type silicon (Si) were successfully fabricated and can be applied as fast-speed self-driven visible photodetectors.
The development of injectable calcium phosphate cements (ICPC) represents a promising approach for minimally invasive surgical techniques. However, the undesirable anti-washout property and slow setting time of ICPC greatly hinder its clinical application. Xanthan gum (XG) has strong hydrophilic, shape retention and r…
A new and simple kind of in-plane heterostructure is constructed by MoS <sub>2</sub> nanoribbons (MoS <sub>2</sub> NRs) and WS <sub>2</sub> nanoribbons (WS <sub>2</sub> NRs) arranged both perpendicularly and in parallel.
The dendrite-like NiCu alloys show outstanding microwave absorption properties with the features of thin-thickness, strong absorption and wide-band.