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Facile Synthesis of Fluorinated Microporous Polyaminals for Adsorption of Carbon Dioxide and Selectivities over Nitrogen and Methane

Guiyang Li、Biao Zhang、Zhonggang Wang2016-03-31Macromolecules

Monoaldehyde compounds, benzaldehyde, 4-methylbenzaldehyde, 4-fluorobenzaldehyde, and 4-trifluoromethylbenzaldehyde, were utilized to react with melamine respectively to yield four hyper-cross-linked microporous polyaminal networks, PAN-P, PAN-MP, PAN-FP, and PAN-FMP, via a facile “one-step” polycondensation without a…

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture TechnologiesCovalent Organic Framework Applications

Mineralization of Poly(lactic acid) (PLA), Poly(3-hydroxybutyrate-co-valerate) (PHBV) and PLA/PHBV Blend in Compost and Soil Environments

Sudhakar Muniyasamy、Osei Ofosu、Maya Jacob John 等 4 位作者2016-03-31JOURNAL OF RENEWABLE MATERIALS

The present study investigates the mineralization of poly(lactic acid) (PLA) and poly(3-hydroxybutyrate-covalerate) (PHBV), and PLA/PHBV blend in compost and soil burial environments. The mineralization was assayed on the bas... | Find, read and cite all the research you need on Tech Science Press

biodegradable polymer synthesis and properties

Tuning Photophysical Properties in Conjugated Microporous Polymers by Comonomer Doping Strategies

Baltasar Bonillo、Reiner Sebastian Sprick、Andrew I. Cooper2016-03-31Chemistry of Materials

High Resolution Image Download MS PowerPoint Slide The photophysical properties of conjugated microporous polymers (CMPs) are tuned using an acceptor doping strategy. This allows the fluorescence of a native polyphenylene network to be controlled by introducing low loadings (0.1–5 mol %) of an acceptor comonomer, such…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Diffusion in a Crowded, Rearranging Environment

Rohit Jain、K. L. Sebastian2016-03-31The Journal of Physical Chemistry B

It has been found in many experiments that the mean square displacement of a Brownian particle x(T) diffusing in a rearranging environment is strictly Fickian, obeying ⟨(x(T))(2)⟩ ∝ T, but the probability distribution function for the displacement is not Gaussian. An explanation of this is that the diffusivity of the…

Fractional Differential Equations SolutionsMaterial Dynamics and PropertiesDiffusion and Search Dynamics

Polysaccharides based nanomaterials for targeted anti-cancer drug delivery

Divya Dheer、Divya Arora、Sundeep Jaglan 等 5 位作者2016-03-31Journal of drug targeting

Polysaccharides, an important class of biological polymers, are effectively bioactive, nontoxic, hydrophilic, biodegradable and offer a wide diversity in structure and properties. These can be easily modified chemically and biochemically to enhance the bioadhesion with biological tissues, better stability and can impr…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsAdvanced Drug Delivery Systems

Self-healing, Reshaping, and Recycling of Vulcanized Chloroprene Rubber: A Case Study of Multitask Cyclic Utilization of Cross-linked Polymer

Hong Xiang、Min Zhi Rong、Ming Qiu Zhang2016-03-31ACS Sustainable Chemistry & Engineering

To develop a new technology for sustainable application of sulfur cross-linked rubbers, a novel latent catalyst, organic complex copper(II) methacrylate (MA-Cu), is explored to trigger disulfide metathesis at elevated temperature. When it is incorporated into vulcanized chloroprene rubber fabricated following industri…

Fuel Cells and Related MaterialsPolymer composites and self-healingSynthetic Organic Chemistry Methods

Design of Poly(l-lactide)–Poly(ethylene glycol) Copolymer with Light-Induced Shape-Memory Effect Triggered by Pendant Anthracene Groups

Hui Xie、Manjie He、Xiaoying Deng 等 7 位作者2016-03-31ACS Applied Materials & Interfaces

A novel light-induced shape-memory material based on poly(l-lactide)-poly(ethylene glycol) copolymer is developed successfully by dangling the photoresponsive anthracene group on the PEG soft segment selectively. For synthesis strategy, the preprepared photoresponsive monomer N,N-bis(2-hydroxyethyl)-9-anthracene-metha…

Polymer composites and self-healingPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

A comparative study on the capacity of a range of food-grade particles to form stable O/W and W/O Pickering emulsions

Laudina J. Duffus、J.E. Norton、Paul Smith 等 5 位作者2016-03-31Journal of Colloid and Interface Science

Whilst literature describing edible Pickering emulsions is becoming increasingly available, current understanding of these systems still suffers from a lack of consistency in terms of the (processing and formulation) conditions within which these structures have been studied. The current study aims to provide a compar…

Proteins in Food SystemsPickering emulsions and particle stabilization

Synthesis of Capsule-like Porous Hollow Nanonickel Cobalt Sulfides via Cation Exchange Based on the Kirkendall Effect for High-Performance Supercapacitors

Yongfu Tang、Shunji Chen、Shichun Mu 等 7 位作者2016-03-31ACS Applied Materials & Interfaces

To construct a suitable three-dimensional structure for ionic transport on the surface of the active materials for a supercapacitor, porous hollow nickel cobalt sulfides are successfully synthesized via a facile and efficient cation-exchange reaction in a hydrothermal process involving the Kirkendall effect with γ-MnS…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Transition-Metal Doped Ceria Microspheres with Nanoporous Structures for CO Oxidation

Lin Zhou、Xiaoxiao Li、Ze Yao 等 8 位作者2016-03-31Scientific Reports

Catalytic oxidation of carbon monoxide (CO) is of great importance in many different fields of industry. Until now it still remains challenging to use non-noble metal based catalysts to oxidize CO at low temperature. Herein, we report a new class of nanoporous, uniform, and transition metal-doped cerium (IV) oxide (ce…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Electrospun nanofibres in agriculture and the food industry: a review

Masumeh Noruzi2016-03-31Journal of the Science of Food and Agriculture

The interesting characteristics of electrospun nanofibres, such as high surface-to-volume ratio, nanoporosity, and high safety, make them suitable candidates for use in a variety of applications. In the recent decade, electrospun nanofibres have been applied to different potential fields such as filtration, wound dres…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer-Based Agricultural Enhancements

Chemical Vapor Deposition of High‐Quality Large‐Sized MoS2 Crystals on Silicon Dioxide Substrates

Jianyi Chen、Wei Tang、Bingbing Tian 等 13 位作者2016-03-31Advanced Science

Large-sized MoS2 crystals can be grown on SiO2/Si substrates via a two-stage chemical vapor deposition method. The maximum size of MoS2 crystals can be up to about 305 μm. The growth method can be used to grow other transition metal dichalcogenide crystals and lateral heterojunctions. The electron mobility of the MoS2…

2D Materials and ApplicationsNanowire Synthesis and ApplicationsMXene and MAX Phase Materials

Casp3/7-Instructed Intracellular Aggregation of Fe3O4 Nanoparticles Enhances T2 MR Imaging of Tumor Apoptosis

Yue Yuan、Zhanling Ding、Junchao Qian 等 12 位作者2016-03-31Nano Letters

Large magnetic nanoparticles or aggregates are advantageous in their magnetic resonance properties over ultrasmall superparamagnetic iron oxide (USPIO) nanoparticles (NPs), but the former are cleared faster from the blood pool. Therefore, the "smart" strategy of intracellular aggregation of USPIO NPs is required for e…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesNanoplatforms for cancer theranostics

Recent Advances in Nanostructured Conducting Polymers: from Synthesis to Practical Applications

Duong Nguyen Nguyen、Hyeonseok Yoon2016-03-31Polymers

Conducting polymers (CPs) have been widely studied to realize advanced technologies in various areas such as chemical and biosensors, catalysts, photovoltaic cells, batteries, supercapacitors, and others. In particular, hybridization of CPs with inorganic species has allowed the production of promising functional mate…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Controlled Exfoliation of MoS2 Crystals into Trilayer Nanosheets

Xiaobin Fan、Pengtao Xu、Yuguang Li 等 8 位作者2016-03-31Journal of the American Chemical Society

The controlled exfoliation of transition metal dichalcogenides (TMDs) into pristine single- or few-layer nanosheets remains a significant barrier to fundamental studies and device applications of TMDs. Here we report a novel strategy for exfoliating crystalline MoS2 into suspensions of nanosheets with retention of the…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

The application of halloysite tubule nanoclay in drug delivery

Yuri Lvov、M DEVILLIERS、Rawil Fakhrullin2016-03-31Expert Opinion on Drug Delivery

INTRODUCTION: Natural and biocompatible clay nanotubes are among the best inorganic materials for drug nanoformulations. These halloysite tubes with SiO2 on the outermost surface have diameter of ca. 50 nm, length around 1 micrometer and may be loaded with drugs at 10-30 wt. %. Narrow tube openings allow for controlla…

Drug Solubulity and Delivery SystemsClay minerals and soil interactionsTherapeutic Uses of Natural Elements

Diffraction gratings: from principles to applications in high-intensity lasers

Nicolas Bonod、Jérôme Néauport2016-03-31OpenAlex

Diffraction gratings were discovered during the 18th century, and they are now widely used in spectrometry analysis, with outstanding achievements spanning from the probing of single molecules in biological samples to the analysis of solar systems in astronomy. The fabrication of high-quality diffraction gratings requ…

Solid State Laser TechnologiesOptical Coatings and GratingsLaser Design and Applications

Supercell program: a combinatorial structure-generation approach for the local-level modeling of atomic substitutions and partial occupancies in crystals

Kirill Okhotnikov、Thibault Charpentier、Sylvian Cadars2016-03-31OpenAlex

BACKGROUND: Disordered compounds are crucially important for fundamental science and industrial applications. Yet most available methods to explore solid-state material properties require ideal periodicity, which, strictly speaking, does not exist in this type of materials. The supercell approximation is a way to impl…

Quasicrystal Structures and PropertiesMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

New Perspectives on the Charging Mechanisms of Supercapacitors

Alexander C. Forse、Céline Merlet、John M. Griffin 等 4 位作者2016-03-31OpenAlex

Supercapacitors (or electric double-layer capacitors) are high-power energy storage devices that store charge at the interface between porous carbon electrodes and an electrolyte solution. These devices are already employed in heavy electric vehicles and electronic devices, and can complement batteries in a more susta…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesAdvanced battery technologies research

Preparation of Porous PMMA/TiO2 Microspheres by Spray Drying Process

Dong‐Hyun Paik、Hyunsuk Lee、Rae-Hyoung Gang 等 6 位作者2016-03-30Journal of the Society of Cosmetic Scientists of Korea

본 연구에서는 분무 건조 공정을 이용하여 다공성 PMMA 입자 내부에 $TiO_2$ 나노입자가 고르게 함침된 유/무기 복합분체를 제조하여, $TiO_2$ 의 은폐력은 그대로 유지하면서도 다공성 구조체로 피지를 흡유하여 지속성을 증대시키는 메이크업 화장품 소재로서의 가능성을 확인하고자 하였다. 끓는점이 다른 두 가지 공용매(디클로로메탄 및 헥산올)의 비율과 고분자의 농도 조절을 통해 입자크기와 기공크기를 제어할 수 있었으며, $TiO_2$ 나노입자를 제조된 시료의 전체 무게 대비 74.6 wt%까지 함침 시킬 수 있었다. SEM 이미지 분석을 통하여 복합분체의 다공성…

biodegradable polymer synthesis and propertiesAerogels and thermal insulationSilicone and Siloxane Chemistry