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Transition between the relaxor and ferroelectric states for (1−x)Pb(Mg1∕3Nb2∕3)O3–xPbTiO3 with x=0.2 and 0.3 polycrystalline aggregates

Miguel Algueró、B. Jiménez、L. Pardo2005-08-16Applied Physics Letters

The transition between the relaxor and ferroelectric states for 0.8Pb(Mg1∕3Nb2∕3)O3–0.2PbTiO3 and 0.7Pb(Mg1∕3Nb2∕3)O3–0.3PbTiO3 polycrystalline aggregates has been studied by measurements of the dielectric and elastic properties as a function of temperature. The ferroelectric to relaxor transition seems to present a r…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

FT‐IR and FT‐Raman spectral studies of bis(L‐proline) hydrogen nitrate and bis(L‐proline) hydrogen perchlorate

S. Pandiarajan、M. Umadevi、V. Sasirekha 等 5 位作者2005-08-16Journal of Raman Spectroscopy

Abstract FT‐IR and FT‐Raman spectra were recorded for bis( L ‐proline) hydrogen nitrate and bis( L ‐proline) hydrogen perchlorate crystals. The wavenumber assignments have been made for the proline functional groups, viz. COOH, COO − , CNCCC ring, [NH 2 ] + , (CH 2 ), CCN and CH. In both crystals, two prolin…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Buckling instabilities in GaN nanotubes under uniaxial compression

Shang-Chao Hung、Yan‐Kuin Su、Te‐Hua Fang 等 7 位作者2005-08-16Nanotechnology

We report experimental observations of shell buckling instabilities in free-standing, vertically aligned GaN nanotubes subjected to uniaxial compression. Highly uniform arrays of the GaN nanotubes standing on a GaN template were fabricated and subjected to uniaxial compression using a nanoindenter. The buckling load w…

Carbon Nanotubes in CompositesGaN-based semiconductor devices and materialsBoron and Carbon Nanomaterials Research

Highly Efficient Direct Current Electrodeposition of Single‐Walled Carbon Nanotubes in Anhydrous Solvents

Yutaka ABE、Ryo Tomuro、Masahito Sano2005-08-16Advanced Materials

Uniform single-walled carbon nanotube films are fabricated by a DC electrodeposition technique from a dispersion solution of the nanotubes in dry organic solvents. Thick and shiny or thin and see-through, tightly bound films are formed on various substrates (see Figure). Highly efficient deposition is made possible by…

Carbon Nanotubes in CompositesConducting polymers and applicationsElectrochemical Analysis and Applications

Stochastic models of carrier dynamics in single-walled carbon nanotubes

A. V. Barzykin、M. Tachiya2005-08-16Physical Review B

Recent time-resolved measurements in optically excited individual semiconducting single-walled carbon nanotubes have revealed rapid electron-hole pair annihilation. A stochastic model of the carrier dynamics has been proposed that includes Auger interactions and discrete occupancy of the nanotubes by the carriers [F.…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Arrangement of multiple structural units in a [0001]Σ49tilt grain boundary in ZnO

Yukio Sato、Teruyasu Mizoguchi、Fumiyasu Oba 等 5 位作者2005-08-16Physical Review B

Arrangement of structural units in a ZnO [0001] $\ensuremath{\Sigma}=49$ symmetric tilt boundary was investigated using a combination of high-resolution electron microscopy and atomistic calculation in detail. The boundary is found to be described by the combination of two different dislocationlike structural units an…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Experimental Characterization Procedure for a Synchronous Machine Model With Saturation and Arbitrary Rotor Network Representation

Dionysios Aliprantis、Scott D. Sudhoff、Bernd Kuhn2005-08-16IEEE Transactions on Energy Conversion

This paper sets forth the experimental procedure for obtaining the parameter set of a synchronous machine model with saturation and arbitrary linear network representation for the rotor. The method utilizes a combination of magnetization curves and standstill frequency-response tests. A novel test procedure is propose…

Electric Motor Design and AnalysisSensorless Control of Electric MotorsMagnetic Properties and Applications

Direct Observation of Excitons and a Continuum of One-Dimensional Mott Insulators: A Reflection-Type Third-Harmonic-Generation Study of Ni-Halogen Chain Compounds

M. Ono、Hideo Kishida、Hiroshi Okamoto2005-08-16Physical Review Letters

The third-harmonic-generation (THG) spectrum was measured for a NiBr-chain compound, which is a one-dimensional Mott insulator, in a reflection configuration. A sharp peak and a shoulder structure in the THG spectrum are attributed to three-photon resonance to an exciton and a continuum, respectively. The band-edge en…

Advanced Chemical Physics StudiesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Radiation-induced site-specific damage of mercury derivatives: phasing and implications

U.A. Ramagopal、Zbigniew Dauter、Radhakannan Thirumuruhan 等 5 位作者2005-08-16Acta Crystallographica Section D Biological Crystallography

The behavior of mercury-derivatized triclinic crystals of a 60 kDa protein target from the New York Structural GenomiX Research Consortium provides novel insights into the mechanism of heavy-atom-specific radiation damage and its potential exploitation for de novo structure solution. Despite significant anomalous sign…

Protein Structure and DynamicsEnzyme Structure and FunctionIon-surface interactions and analysis

Nano-structured materials produced from simple metallic alloys by phase separation

D. Mukherji、Giancarlo Pigozzi、Fabian Schmitz 等 6 位作者2005-08-16Nanotechnology

A method which is able to produce different types of nano-structured materials, namely nano-particles, nano-structured surfaces and nano-porous membranes, from two-phase metallic alloys is reviewed. The new process first establishes nano-structures in the bulk alloy and then separates them by selective phase dissoluti…

Electrocatalysts for Energy ConversionAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Heat capacity and critical behavior of hexagonalYMnO3

Makoto Tachibana、J. Yamazaki、Hitoshi Kawaji 等 4 位作者2005-08-16Physical Review B

We report heat capacity $({C}_{p})$ measurements on high-quality single crystals of hexagonal $\mathrm{Y}\mathrm{Mn}{\mathrm{O}}_{3}$, a ferroelectric and frustrated triangular antiferromagnetic (AF) compound. The obtained values of the critical exponent $\ensuremath{\alpha}$ and amplitude ratio ${A}^{+}∕{A}^{\ensurem…

Physics of Superconductivity and MagnetismMultiferroics and related materialsAdvanced Condensed Matter Physics

Band-gap formation in(n,0)single-walled carbon nanotubes(n=9,12,15,18): A first-principles study

Takashi Miyake、Susumu Saito2005-08-16Physical Review B

We study the electronic structure of the carbon nanotube theoretically by the first-principles techniques using the local-density approximation (LDA) with the many-body correction in the GW approximation. We find that the (9,0) tube is gapful irrespective of naive expectation from the graphene band structure. All of t…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

Preparation and Biocompatibility of Novel UV-Curable Chitosan Derivatives

Eiko Renbutsu、Masaru Hirose、Yoshihiko Omura 等 9 位作者2005-08-16Biomacromolecules

UV-curable chitosans (UVCC-7-10) were synthesized using less-toxic agents. The UVCC-7 was completely cured by UV spot irradiation for 4 s. The UVCC-7 was implanted into murine subcutaneous tissues, and the response to the implantation was observed by histological examination at 7 days after implantation. In the histol…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsMarine Biology and Environmental Chemistry

Electron paramagnetic resonance ofZn1−xMnxOthin films and single crystals

Mariana Diaconu、Heidemarie Schmidt、Andreas Pöppl 等 10 位作者2005-08-16Physical Review B

$X$-band electron paramagnetic resonance spectra were recorded for ${\mathrm{Zn}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{O}$ films grown by pulsed laser deposition and a single crystal for comparison. For different Mn concentrations in ${\mathrm{Zn}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{O}$ films we performe…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

In Situ Polymerization of Poly(methyl methacrylate)/Clay Nanocomposites in Supercritical Carbon Dioxide

Qian Zhao、Edward T. Samulski2005-08-16Macromolecules

Poly(methyl methacrylate)/clay nanocomposites have been prepared using a pseudo-dispersion polymerization of MMA monomer in the presence of fluorinated surfactant-modified clay (10F-clay) in supercritical carbon dioxide. The nanocomposites are characterized by scanning electron microscopy, transmission electron micros…

Polymer Nanocomposites and PropertiesSilicone and Siloxane ChemistryPolymer Foaming and Composites

Fibrillar assembly and stability of collagen coating on titanium for improved osteoblast responses

Hae‐Won Kim、Hae‐Won Kim、Longhao Li 等 7 位作者2005-08-16Journal of Biomedical Materials Research Part A

Collagen, as a major constituent of human connective tissues, has been regarded as one of the most important biomaterials. As a coating moiety on Ti hard-tissue implants, the collagen has recently attracted a great deal of attention. This article reports the effects of fibrillar assembly and crosslinking of collagen o…

Bone Tissue Engineering MaterialsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Aligned Arrays of Nanotubes and Segmented Nanotubes on Substrates Fabricated by Electrodeposition onto Nanorods

Melissa Sander、Han Gao2005-08-16Journal of the American Chemical Society

We describe an electrochemical-based approach to create vertically aligned nanotube arrays on substrates. Initially, nanoporous anodic alumina films are used as templates to electrodeposit nanorods, and then the alumina templates are removed and nanotube arrays are electrodeposited using the nanorod arrays as template…

Nanowire Synthesis and ApplicationsSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Flexural and Shear Properties of Silica Particle Modified Glass Fiber Reinforced Epoxy Composite

Yong Cao、John H. Cameron2005-08-16Journal of Reinforced Plastics and Composites

The objective of this study is to develop a new method of manufacturing glass fiber reinforced epoxy composites and to quantitatively show that the properties of such a new material are superior to that of a conventional fiber reinforced polymer composite of the same material base composition. To achieve this objectiv…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Silver transport inGexSe1−x:Agmaterials:Ab initiosimulation of a solid electrolyte

De Nyago Tafen、D. A. Drabold、M. Mitkova2005-08-16Physical Review B

In this paper, we present models of $\mathrm{Ge}\text{\ensuremath{-}}\mathrm{Se}$ glasses heavily doped with Ag obtained from ab initio simulation and study the dynamics of the network with an emphasis on the motion of ${\mathrm{Ag}}^{+}$ ions. The models are analyzed with partial pair correlation functions, static st…

Quantum Dots Synthesis And PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Interpenetrating‐Lattice‐Structured Magnets Exhibiting Anomalous Magnetic Properties

Joel S. Miller、T.E. Vos、William W. Shum2005-08-16Advanced Materials

Abstract Cubic [Ru 2 (O 2 CMe) 4 ] 3 [Cr(CN) 6 ] prepared from water has two interpenetrating lattices and exhibits anomalous magnetic hysteresis, saturation magnetization, out‐of‐phase alternating current (AC) susceptibility, χ″( T ), and zero‐field‐cooled/field‐cooled temperature‐dependent magnetization data with re…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research