Materials Literature
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Sequential copolymerizations of trimethylene carbonate (TMC) and l-lactide (LLA) were performed with 2,2-dibutyl-2-stanna-1,3-oxepane as a bifunctional cyclic initiator. The block lengths were varied via the monomer/initiator and via the TMC/l-lactide ratio. The cyclic triblock copolymers were transformed in situ into…
We have prepared Ni-V(2)O(5).nH(2)O core-shell nanocable arrays for Li(+) intercalation applications. Ni-V(2)O(5).nH(2)O nanocables were prepared via formation of Ni nanorod arrays through the template based electrochemical deposition, followed by coating of V(2)O(5).nH(2)O on Ni nanorods through electrophoretic depos…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSugar-Induced Disintegration of Layer-by-Layer Assemblies Composed of Concanavalin A and GlycogenKatsuhiko Sato, Yoko Imoto, Jun Sugama, Shunsuke Seki, Hiroyuki Inoue, Tsuyoshi Odagiri, Tomonori Hoshi, and Jun-ichi AnzaiView Author Information Graduate School of Pharmaceutical…
The Silkworm Knowledgebase (SilkDB) is a web-based repository for the curation, integration and study of silkworm genetic and genomic data. With the recent accomplishment of a approximately 6X draft genome sequence of the domestic silkworm (Bombyx mori), SilkDB provides an integrated representation of the large-scale,…
Benziporphyrins are synthetic porphyrin analogues, in which one of the pyrroles is replaced with a benzenoid ring. The arene can be incorporated into the macrocycle in several ways leading to molecules with distinct physical and chemical properties. By appropriately changing the structure of benziporphyrins, it is pos…
Enhancement of the relaxivities of Gd-based MRI contrast agents is achieved by placing the metal ion at the barycentre of the molecular complex in order to improve motional coupling.
The Macromolecular Structure Database (MSD) group ( http://www.ebi.ac.uk/msd/ ) continues to enhance the quality and consistency of macromolecular structure data in the worldwide Protein Data Bank (wwPDB) and to work towards the integration of various bioinformatics data resources. One of the major obstacles to the im…
ADVERTISEMENT RETURN TO ISSUEPREVNoteUltrathin Coatings and (Poly(glutamic acid)/Polyallylamine) Films Deposited by Continuous and Simultaneous SprayingC. H. Porcel, A. Izquierdo, V. Ball, G. Decher, J.-C. Voegel, and P. SchaafView Author Information Unité INSERM U595, 2, Rue Humann, 67000, Strasbourg, France, and Ins…
In this paper it is presented a detailed numerical investigation of acoustic emission signals obtained from test samples of fibreglass reinforced polymeric matrix composites, when subjected to tensile and flexural tests. Various fractal indices, characteristic of the signals emitted at the different structural failure…
A single-walled carbon nanotube was exploited for its semi-flexible pseudo-one-dimensional nanostructure as a unique scaffold to display multivalent carbohydrate ligands, with a specific demonstration showing that galactosylated carbon nanotubes were effective in the capturing of pathogenic Escherichia coli in solutio…
We study the effects of $n$-doping and $p$-doping on the structural and electronic properties of $\mathrm{Sr}\mathrm{Ti}{\mathrm{O}}_{3}$ using the ab initio pseudopotential density functional theory. Two types of electron doping and one type of hole doping are considered: introducing O vacancies, substituting V for T…
We model the magnetization of quasi two-dimensional systems with easy perpendicular (z-)axis anisotropy upon change of external magnetic field along z. The model is derived from the Landau-Lifshitz-Gilbert equation for magnetization evolution, written in closed form in terms of the z component of the magnetization onl…
We have studied a non volatile memory effect in the mixed valent compound La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ induced by magnetic field (H). In a previous work [R.S. Freitas et al., Phys. Rev. B 65 (2002) 104403], it has been shown that the response of this system upon application of H strongly depends on the temperature ra…
The surface diffusion of Cu adatoms in the presence of an adisland at FCC or HCP sites on Cu(111) is studied using the EAM potential derived by Mishin {\it et al.} [Phys. Rev. B {\bf 63} 224106 (2001)]. The diffusion rates along straight (with close-packed edges) steps with (100) and (111)-type microfacets (resp. step…
X-ray back diffraction from monolithic two silicon crystal plates of 25--150 um thick and a 40--150 um gap using synchrotron radiation of energy resolution deltaE=0.36 meV at 14.4388 keV shows clearly resonance fringes inside the energy gap and the total-reflection range for the (12 4 0) reflection. This cavity resona…
A first-principles-based scheme is developed to simulate properties of (001) PbO-terminated $\mathrm{Pb}({\mathrm{Zr}}_{1\ensuremath{-}x}{\mathrm{Ti}}_{x}){\mathrm{O}}_{3}$ thin films that are under stress-free and open-circuit boundary conditions. Their low-temperature spontaneous polarization never vanishes down to…
The mechanism for the ferromagnetic order of (Ga,Mn)As and (Ga,Mn)$\mathrm{N}$ is extensively studied over a vast range of Mn concentrations. We calculate the electronic structures of these materials using density functional theory in both the local spin density approximation (LSDA) and the local density approximation…
Using photoemission intensities and a detection system employed by many groups in the electron spectroscopy community as an example, we have quantitatively characterized and corrected detector non-linearity effects over the full dynamic range of the system. Non-linearity effects are found to be important whenever meas…
Mobile applications of hydrogen power have long demanded new solid hydride materials with large hydrogen storage capacities. We report synthesis of a new quaternary hydride having the approximate composition Li(3)BN(2)H(8) with 11.9 wt % theoretical hydrogen capacity. It forms by reacting LiNH(2) and LiBH(4) powders i…
Au and Ag nanoshells are investigated as substrates for surface-enhanced Raman scattering (SERS). We find that SERS enhancements on nanoshell films are dramatically different from those observed on colloidal aggregates, specifically that the Raman enhancement follows the plasmon resonance of the individual nanoparticl…