Materials Literature
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Structural and morphological studies were carried out on cerium- and gadolinium-doped sol−gel silica glasses intended for scintillator applications, to deepen the understanding of rare earth ion incorporation into the glass matrix. Several compositions, ranging from 0 to 5 mol % Ce and from 0 to 8 mol % Gd, were studi…
A new series of magnetoresistive oxides based on the ${\mathrm{CaCu}}_{3}{\mathrm{Mn}}_{4}{\mathrm{O}}_{12}$ perovskite has been investigated by x-ray absorption and neutron powder diffraction. The samples were either doped at $\mathrm{Cu}$ sites by $\mathrm{Mn}$ or by $\mathrm{La}$ at $\mathrm{Ca}$ sites. The x-ray a…
Abstract The thermodynamic interactions between poly(4‐ tert ‐butyl styrene) [P(4tBS)] and 1,4‐polyisoprene (PI; both hydrogenous) were obtained as functions of the temperature, PI molecular weight, and blend composition through the examination of miscible ternary blends of these two components with a common miscible…
Auseinander und wieder zusammen: Die Spaltung hochmolekularer linearer Koordinationspolymere aus Phosphan-telechelem Polytetrahydrofuran und Palladiumdichlorid in verdünnter Lösung ist reversibel (siehe Bild). 1 h Beschallung führte zu einer Abnahme des gewichtsgemittelten Molekulargewichts des Polymers von 1.7×105 au…
1.1 Bonding of Carbon Atoms 2 1.2 Defect-Free Nanotube 3 1.3 Defective Nanotubes 6 1.4 Electronic Properties 8 1.5 Optical and Optoelectronic Properties 12 1.6 Mechanical and Electromechanical Properties 14 1.7 Magnetic and Electromagnetic Properties 17 1.8 Chemical and Electrochemical Properties 18 Wetting and Fillin…
A micropatterned multilayer film, which was fabricated from layer-by-layer electrostatic self-assembly of nitrodiazoresin (NDR)/poly(acrylic acid) (PAA) followed by photolithography, was utilized as a structured template for the biomimetic mineralization of calcium carbonate. Micropatterned CaCO3 films consisting of r…
We study the slow dynamics of salol by varying both temperature and pressure using photon correlation spectroscopy and pressure-volume-temperature measurements, and compare the behavior of the structural relaxation time with equations derived within the Adam-Gibbs entropy theory and the Cohen-Grest free volume theory.…
During the last decade, a number of methodological and technical improvements in macromolecular crystallography (MC) led to the appearance of several protein structures at a level of resolution higher than 0.85 Å. This leads to the possibility of analysing the structure at a very fine level of detail: one can refine m…
13 C NMR has been used to investigate the segmental dynamics of isolated polyisoprene (PI) chains in host matrices of polybutadiene (PB), poly(vinylethylene) (PVE), and polystyrene (PS). In the dilute regime, where intermolecular concentration fluctuations are minimal, the segmental dynamics of isolated PI chains do n…
Abstract Poly(dimethyl)siloxanes of different viscosity have been synthesized by hydrolytic condensation of dimethyldichloro silane. Polysiloxane dispersed ferroelectric liquid crystal (PDFLC) composite films were prepared simultaneously by solvent induced and polymer induced phase separation techniques (SIPS and PIPS…
Abstract The structural and conformational changes in solid‐phase chlorinated polyethylene samples of different average molecular masses were studied with infrared spectroscopy. Characteristic absorption bands for both chlorinated polyethylene and chlorinated high‐molecular‐mass polyethylene, containing 1–56% Cl, were…
We have found that the simple introduction of Fe into a conventional NiCo catalyst enables the production of single-wall carbon nanotubes (SWNTs) with controlled diameter distributions by laser ablation. The diameter of as-grown SWNTs can be made larger by increasing the atomic percentage of Fe in the target without c…
Abstract Water‐based polyurethane–urea (WPUU) nanoparticles containing 4,4′‐methylenedi‐ p ‐phenyl diisocyanate (MDI) and isophorone diisocyanate (IPDI) were synthesized by a stepwise prepolymer mixing process, that is, the consecutive formation of hydroxyl‐terminated and isocyanate‐terminated polyurethane prepolymers…
The aim of this work is to study the merging of the main α and the secondary β relaxations in poly(butyl acrylate)- i -poly(methyl methacrylate) sequential interpenetrating networks in comparison to net -poly(butyl acrylate)- co -poly(methyl methacrylate) random copolymer networks. In both cases 10% of ethylene glycol…
A simple and efficient preparation of a number of PEG‐carboxylates is described. The syntheses are considerably more cost‐effective than existing procedures and allow for easier purifications.
The availability of multiporphyrin arrays with defined architectures and good solubility in organic solvents is essential for a wide variety of physical studies. Herein the synthesis of linear multiporphyrin arrays (triads, tetrad, pentad) bearing solubilizing 7-tridecyl (swallowtail) groups is presented. The rodlike…
Nitrogen adsorption isotherms on organized mesoporous aluminas prepared by several different synthesis procedures were analyzed by means of comparative plot method using Aluminiumoxid C (Degussa) and alpha-alumina as reference adsorbents. To secure the high-resolution ability of this method, all the adsorption measure…
Abstract Incoherent neutron scattering is presented as a powerful tool for interpreting changes in molecular dynamics as a function of film thickness for a range of polymers. Motions on approximately nanosecond and faster timescales are quantified in terms of a mean‐square atomic displacement (〈 u 2 〉) from the Debye–…
Abstract The effect of various doses of γ radiation on the structural properties of water‐soluble polymer blends based on poly(vinyl alcohol) (PVA) and poly(ethylene glycol) (PEG) has been investigated. Although the aqueous solutions of individual PVA and PEG homopolymers were homogeneous and clear, films transparent…
Hydrotalcites are receiving considerable attention as adsorbents, catalysts, and catalyst precursors. However, the use of hydrotalcites as an adsorbent material for carbon dioxide has only been considered recently. In this work, three commercial hydrotalcites, Puralox MG30, MG50, and MG70, were used for the removal of…